Tube and medical device using same
Provided are a tube which has good transparency, flexibility, and solvent adhesion, and also has excellent clamp resistance, anti-conglutination property, and kink resistance, and a medical device using the tube. Specifically provided are a tube produced by forming a resin composition into a tube shape, which contains a styrene-based thermoplastic elastomer (a) and a polypropylene-based resin (b) and does not contain a softening agent, in which: the elastomer (a) is a product prepared by hydrogenating a block copolymer including at least a polymer block (A) formed of an aromatic vinyl compound and a polymer block (B) formed of isoprene and/or 1,3-butadiene; the content of the polymer block (A) is 5 to 40 mass % before hydrogenation, the polymer block (B) has a hydrogenation ratio of 70% or more, and the polymer block (B) includes a 1,2-bond and a 3,4-bond at a content of 30 to 85 mol %; the mass ratio of the styrene-based thermoplastic elastomer (a) to the polypropylene-based resin (b) [(a)/(b)] is 90/10 to 40/60; and the tube has a ratio of a diffraction peak intensity [I(14)] at a scattering angle of 14° to a diffraction peak intensity [I(15)] at a scattering angle of 15° [I(14)/I(15)] of 1.4 or more in X-ray diffraction, and a medical device including the tube.
1. A tube composed of a resin composition comprising:
a styrene thermoplastic elastomer (a) and
a polypropylene resin (b) that has a melt flow rate of 15 to 50 g/10 minutes at a temperature of 230° C. and at a load of 21.2 N,
wherein a mass ratio (a)/(b) of the styrene thermoplastic elastomer (a) to the polypropylene resin (b) is 90/10 to 40/60;
wherein the styrene thermoplastic elastomer (a) is a hydrogenated block copolymer prepared by hydrogenating a block copolymer comprising polymer block(s) (A), wherein in polymerized form polymer block(s) (A) comprises at least an aromatic vinyl unit, and wherein a total content of polymer block(s) (A) in the styrene thermoplastic elastomer (a) before hydrogenation is 5 to 40 mass % with respect to a total amount of the styrene thermoplastic elastomer (a); and a polymer block (B) that has a hydrogenation ratio of 70% or more, that comprises a 1,2-bond and a 3,4-bond at a content of 30 to 85 mol %, and that in polymerized form comprises at least one unit selected from the group consisting of isoprene and 1,3-butadiene;
wherein said resin does not contain a softening agent; and
wherein the tube has a ratio I(14)/I(15) of a diffraction peak intensity [I(14)] at a scattering angle (2θ) of 14° to a diffraction peak intensity [I(15)] at a scattering angle (20) of 15° of 1.7 or more in wide-angle X-ray diffraction.
2. The tube of claim 1 , wherein the content of aromatic vinyl unit in polymer block(s) (A) is 80% by mass or more with respect to the mass of polymer block(s) (A).
3. The tube of claim 1 , wherein the content of aromatic vinyl unit in polymer block(s) (A) is 90% by mass or more with respect to the mass of polymer block(s) (A).
4. The tube of claim 1 , wherein the content of aromatic vinyl unit in polymer block(s) (A) is 100% by mass or more with respect to the mass of polymer block(s) (A).
5. The tube of claim 1 , wherein the content of an isoprene unit and/or 1,3-butadiene unit in polymer block (B) is 80% by mass or more with respect to the mass of polymer block (B).
6. The tube of claim 1 , wherein the content of an isoprene unit and/or 1,3-butadiene unit in polymer block (B) is 90% by mass or more with respect to the mass of polymer block (B).
7. The tube of claim 1 , wherein the content of an isoprene unit and/or 1,3-butadiene unit in polymer block (B) is 100% by mass or more with respect to the mass of polymer block (B).
8. The tube of claim 1 , wherein the hydrogenation ratio in polymer block (B) is 80% or more.
9. The tube of claim 1 , wherein the hydrogenation ratio in polymer block (B) is 85% or more.
10. The tube of claim 1 , wherein the glass transition temperature of polymer block (B) ranges from −50 to 30° C.
11. The tube of claim 1 , wherein the glass transition temperature of polymer block (B) ranges from −45 to 10° C.
12. The tube of claim 1 , wherein the glass transition temperature of polymer block (B) ranges from −40 to 0° C.
13. The tube of claim 1 , wherein bonding between polymer block(s) (A) and polymer block (B) is linear, branched, radial, or a combination thereof.
14. The tube of claim 1 , wherein the content of polymer block(s) (A) in styrene-based thermoplastic elastomer (a) before hydrogenation ranges from 5 to 30% by mass.
15. The tube of claim 1 , wherein the content of polymer block(s) (A) in styrene-based thermoplastic elastomer (a) before hydrogenation ranges from 5 to 20% by mass.
16. The tube of claim 1 , wherein the content of polymer block(s) (A) in styrene-based thermoplastic elastomer (a) before hydrogenation ranges from 5 to 10% by mass.
17. The tube of claim 1 , wherein the weight average molecular weight of styrene-based thermoplastic elastomer (a) ranges from 4,000 to 500,000.
18. The tube of claim 1 , wherein the weight average molecular weight of styrene-based thermoplastic elastomer (a) ranges from 30,000 to 300,000.
19. The tube of claim 1 , wherein the weight average molecular weight of styrene-based thermoplastic elastomer (a) ranges from 50,000 to 250,000.
20. The tube of claim 1 , wherein the polypropylene resin (b) has a melt flow rate of 20 to 50 g/10 minutes at a temperature of 230° C. and at a load of 21.2 N.
21. The tube of claim 1 that has a crystallization temperature of 95° C. or more at a cooling speed of 10° C./minute when the crystallization temperature is measured with a differential scanning calorimeter.
22. The tube of claim 1 , wherein content of the 1,2-bond and the 3,4-bond in the polymer block (B) is in a range of 45 to 80 mol % with respect to a structural unit derived from the at least one compound in the polymer block (B).
23. The tube of claim 1 , wherein content of the 1,2-bond and the 3,4-bond in the polymer block (B) is, with respect to a structural unit derived from the at least one compound in the polymer block (B), in a range of 55 to 70 mol %.
24. The tube of claim 1 that has a ratio I(4)/I(15) of diffraction peak intensity [I(14)] at a scattering angle (2θ) of 14° to a diffraction peak intensity [I(15)] at a scattering angle (2θ) of 15° of 2.25 or more in wide-angle X-ray diffraction.
25. The tube of claim 1 , wherein a mass ratio (a)/(b) of the styrene thermoplastic elastomer (a) to the polypropylene resin (b) is 80/20 to 45/55.
26. The tube of claim 1 , wherein a mass ratio (a)/(b) of the styrene thermoplastic elastomer (a) to the polypropylene resin (b) is 70/30 to 50/50.
27. The tube of claim 1 , wherein said resin contains at least one of a tackifying resin, an inorganic filler or a lubricant.
28. The tube of claim 1 that is formed by melting said resin, forming the molten composition into a product having a tube shape through a die, followed by water cooling or air cooling, thereby yielding a tube.
29. The tube of claim 1 made by forming said resin composition into a tube directly with an extruder at the time of producing the resin composition.
30. The tube of claim 1 that has a crystallinity ranging from 14.0 to 22.4.
31. The tube of claim 1 that has a transparency ranging from 81 to 91% transmittance.
32. The tube of claim 1 that has a flexibility ranging from 14.8 to 22.8 MPa.
33. The tube of claim 1 that has a kink resistance ranging from 16 to 25 mm.
34. The tube of claim 1 that has a clamp resistance ranging from 1 to 40 secs.
35. The tube of claim 1 that exhibits no conglutination after being stacking and fixed with tape, being placed in a hot air drier at 100° C. for 30 mins, and being cooled at room temperature.
36. The tube of claim 1 that has a solvent adhesion ranging from 21 N to 45 N.
37. The tube of claim 1 that has a cross-section that has a circular shape or an elliptical shape.
38. The tube of claim 1 that has an outer diameter ranging from 1 to 50 mm.
39. The tube of claim 1 that has a thickness ranging from 0.3 to 30 mm.
40. The tube of claim 1 that is a multilayered tube.
41. A medical device comprising the tube of claim 1 .
42. An infusion device, a blood transfusion device, a peritoneal dialysis device, a catheter, a tube for an infusion bag, a tube for a blood bag, a blood vessel prosthesis, a blood circuit, a syringe, a hemodialyzer, a blood component separator or an oxygenator comprising the tube of claim 1 .