IP Library Granted Patent US 9,200,302
Granted Patent B2
US 9,200,302 · App. 13/260,281 · Granted Dec 1, 2015

Process for the rapid hydrolysis of high solids biomass

Inventors: Marco Cotti Comettini (Trivero, IT); Paolo Torre (Arenzano, IT); Francesco Cherchi (Campobasso, IT); Alberto Riva (Arquata Scrivia, IT); Simone Ferrero (Tortona, IT); Piero Ottonello (Genoa, IT); Mirko Garbero (Turin, IT)
Assignee: Beta Renewables S.p.A.
C12P19/02C13K1/02C12P2201/00
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Quick Facts
Patent No.
US 9,200,302
App. No.
13/260,281
Granted
Dec 1, 2015
Kind
B2
Abstract

The process for the hydrolysis of ligno-cellulosic biomass comprises the steps of A) Contacting a ligno-cellulosic feedstock, the feedstock comprised of biomass having a dry content and water with at least a portion of a solvent, the solvent comprised of water soluble hydrolyzed species; wherein at least some of the water soluble hydrolyzed species are the same as the water soluble hydrolyzed species obtainable from the hydrolysis of the biomass in the feedstock; B) maintaining the contact between the feedstock of the feedstock stream and the solvent at a temperature in the range of 20° C. to 200° C. for a time in the range of 5 minutes to 72 hours to create a hydrolyzed product from the biomass in the feedstock.

Claims (14)

1. A process for the hydrolysis of ligno-cellulosic biomass comprising the steps of

A) contacting a ligno-cellulosic feedstock of a feedstock stream, the ligno-cellulosic feedstock comprised of a ligno-cellulosic biomass having a dry content and water, with at least a portion of a solvent, wherein the dry content comprises cellulose, hemicellulose, and the weight percent of the cellulose in the dry content is greater than 5 weight percent of the dry content, the solvent comprises water soluble hydrolyzed species; wherein at least some of the water soluble hydrolyzed species are the same as the water soluble hydrolyzed species obtainable from the hydrolysis of the cellulose in the feedstock;

B) maintaining the contact between the feedstock of the feedstock stream and the solvent in the presence of a catalyst composition for the hydrolysis of the cellulose comprising at least one cellulase enzyme, at a temperature in the range of 20° C. to 100° C. for a time in the range of 5 minutes to 72 hours to create a hydrolyzed product from the biomass in the feedstock

wherein the process is conducted without adding inorganic acid.

2. The process of claim 1 , wherein the ratio of the weight of the solvent contacted with the feedstock to the weight of the feedstock is in the range of 40:60 to 90:10.

3. The process of claim 2 , wherein the ratio of the weight of the solvent contacted with the feedstock to the weight of the feedstock is greater than 0.8:1.

4. The process of claim 1 , wherein the ratio of the weight of the cellulose plus hydrolysis products of cellulose in the solvent to the weight of the cellulose in the ligno-cellulosic feedstock is greater than the ratio of 1:1.

5. The process of claim 2 , wherein at least a portion of the catalyst composition is contacted with the feedstock before contacting the feedstock with at least a portion of the solvent.

6. The process of claim 4 , wherein at least a portion of the catalyst composition is contacted with the feedstock before contacting the feedstock with at least a portion of the solvent.

7. The process of claim 2 , wherein at least a portion of the catalyst composition is contacted with the feedstock after contacting the feedstock with at least a portion of the solvent.

8. The process of claim 4 , wherein at least a portion of the catalyst composition is contacted with the feedstock after contacting the feedstock with at least a portion of the solvent.

9. The process of claim 2 , wherein at least a portion of the catalyst composition is contacted with the feedstock simultaneously with contacting the feedstock with at least a portion of the solvent.

10. The process of claim 4 , wherein at least a portion of the catalyst composition is contacted with the feedstock simultaneously with contacting the feedstock with at least a portion of the solvent.

11. The process of claim 2 , wherein the ratio of the biomass to water of the feedstock is greater than the ratio of 1:0.9.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 9, 2019
From: BETA RENEWABLES S.P.A.
To: VERSALIS S.P.A.
Reel/Frame 049124/0309 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 7, 2011
From: COTTI COMETTINI, MARCO; TORRE, PAOLO; CHERCHI, FRANCESCO; RIVA, ALBERTO; FERRERO, SIMONE; OTTONELLO, PIERO; GARBERO, MIRKO
To: CHEMTEX ITALIA S.R.L.
Reel/Frame 027030/0944 →
Priority Claims (4)
WO PCT/IT2009/000124 · Mar 31, 2009 · international
WO PCT/IT2009/000127 · Mar 31, 2009 · international
WO PCT/IB2009/055736 · Dec 14, 2009 · international
WO PCT/IB2009/055737 · Dec 14, 2009 · international
Continuity (1)
Related Publication 20120055466A1 · Mar 8, 2012