IP Library Granted Patent US 9,458,255
Granted Patent B2
US 9,458,255 · App. 13/260,907 · Granted Oct 4, 2016

Method for producing stabilized fluoropolymer

Inventors: Tomohiro Isogai (Settsu, JP); Tatsuo Suzuki (Settsu, JP); Tadashi Ino (Settsu, JP); Masahiro Kondo (Settsu, JP)
Assignee: DAIKIN INDUSTRIES, LTD.
C08F8/20C08F8/22
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Quick Facts
Patent No.
US 9,458,255
App. No.
13/260,907
Granted
Oct 4, 2016
Kind
B2
Abstract

The present invention is aimed to provide a highly-productive method for producing a stabilized fluoropolymer. The present invention relates to a method for producing a stabilized fluoropolymer, comprising the step of bringing a fluoropolymer to be treated into contact with a fluorinating agent to produce a stabilized fluoropolymer, while maintaining the concentration of hydrogen fluoride present in a reaction vessel at not higher than 1.0% by volume.

Claims (13)

1. A method for producing a stabilized fluoropolymer, comprising the step of

bringing a fluoropolymer to be treated into contact with a fluorinating agent in a stationary reactor to produce a stabilized fluoropolymer, while maintaining the concentration of hydrogen fluoride present in a reaction vessel at not higher than 1.0% by volume,

wherein the contacting step is carried out at a temperature of 50° C. or higher and 185° C. or lower, and

the fluoropolymer to be treated is in the form of a resin powder, a pellet, or a membrane obtained through molding, and

the fluoropolymer to be treated is constituted by 50 to 100 mol % of an ethylenic fluoromonomer unit and 0 to 50 mol % of a fluorinated alkyl vinyl ether unit, and

the fluoropolymer to be treated has an unstable group and

the unstable group is at least one group selected from the group consisting of —CF 2 COF, —CF 2 COOH, —CF 2 CH 2 OH, —CF 2 COOCH 3 , and —COOCO—, wherein —CF 2 COF —CF 2 COOH, —CF 2 CH 2 OH and —CF 2 COOCH 3 are terminal groups and wherein —COOCO— represents a group formed by bonding two —CF 2 COOH terminal groups.

2. The method for producing a stabilized fluoropolymer according to claim 1 ,

wherein the fluorinating agent is at least one substance selected from the group consisting of F 2 , NF 3 , SF 4 , ClF, ClF 3 , BrF 3 , and IF 5 .

3. The method for producing a stabilized fluoropolymer according to claim 1 ,

wherein the fluorinating agent is F 2 .

4. The method for producing a stabilized fluoropolymer according to claim 1 ,

wherein the contacting step is carried out at a temperature of 50° or higher and 120° or lower.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 28, 2011
From: ISOGAI, TOMOHIRO; SUZUKI, TATSUO; INO, TADASHI; KONDO, MASAHIRO
To: DAIKIN INDUSTRIES, LTD.
Reel/Frame 026986/0226 →
Priority Claims (1)
JP 2009-088264 · Mar 31, 2009 · national
Continuity (1)
Related Publication 20120035329A1 · Feb 9, 2012