IP Library › Granted Patent US 9,595,443
Granted Patent B2
US 9,595,443 · App. 13/277,642 · Granted Mar 14, 2017

Metal gate structure of a semiconductor device

Inventors: Ming Zhu (Singapore, SG); Hui-Wen Lin (Taiping, TW); Harry-Hak-Lay Chuang (Singapore, SG); Bao-Ru Young (Zhubei, TW); Yuan-Sheng Huang (Taichung, TW); Ryan Chia-Jen Chen (Chiayi, TW); Chao-Cheng Chen (Shin-Chu, TW); Kuo-Cheng Ching (Zhubei, TW); Ting-Hua Hsieh (Hsinchu, TW); Carlos H. Diaz (Mountain View, CA)
Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
H01L21/28088H01L21/82345H01L21/823481H01L29/4966H01L29/66545H01L21/823475H01L29/42376
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,595,443
App. No.
13/277,642
Granted
Mar 14, 2017
Kind
B2
Abstract

The invention relates to integrated circuit fabrication, and more particularly to a metal gate structure. An exemplary structure for a CMOS semiconductor device comprises a substrate comprising an isolation region surrounding and separating a P-active region and an N-active region; a P-metal gate electrode over the P-active region and extending over the isolation region, wherein the P-metal gate electrode comprises a P-work function metal and an oxygen-containing TiN layer between the P-work function metal and substrate; and an N-metal gate electrode over the N-active region and extending over the isolation region, wherein the N-metal gate electrode comprises an N-work function metal and a nitrogen-rich TiN layer between the N-work function metal and substrate, wherein the nitrogen-rich TiN layer connects to the oxygen-containing TiN layer over the isolation region.

Claims (31)

1. A complementary metal-oxide-semiconductor (CMOS) semiconductor device comprising:

a substrate comprising an isolation region adjacent to and separating a P-active region and an N-active region;

a P-metal gate electrode over the P-active region and extending over the isolation region, wherein the P-metal gate electrode comprises a P-work function metal and an oxygen-containing TiN layer between the P-work function metal and substrate; and

an N-metal gate electrode over the N-active region and extending over the isolation region, wherein the N-metal gate electrode comprises an N-work function metal and a nitrogen-rich TiN layer between the N-work function metal and substrate, wherein the nitrogen-rich TiN layer connects to the oxygen-containing TiN layer over the isolation region.

2. The CMOS semiconductor device of claim 1 further comprising an oxygen-containing TaN layer between the oxygen-containing TiN layer and the P-work function metal.

3. The CMOS semiconductor device of claim 1 further comprising a nitrogen-rich TaN layer between the nitrogen-rich TiN layer and the N-work function metal.

4. The CMOS semiconductor device of claim 1 further comprising a nitrogen-containing gate dielectric layer between the nitrogen-rich TiN layer and substrate.

5. The CMOS semiconductor device of claim 1 , wherein the N-metal gate electrode has a recess and P-metal gate electrode has a protrusion extending into the recess.

6. The CMOS semiconductor device of claim 1 , wherein a ratio of a maximum width of the P-metal gate electrode to a minimum width of the N-metal gate electrode is from about 1.05 to 1.2.

7. The CMOS semiconductor device of claim 1 further comprising an oxygen-containing TaN layer between the N-work function metal and the P-work function metal.

8. The CMOS semiconductor device of claim 1 further comprising a nitrogen-rich TaN layer between the N-work function metal and the P-work function metal.

9. The CMOS semiconductor device of claim 1 , wherein the N-work-function metal comprises a metal selected from a group of Ti, Ag, Al, TiAl, TiAlN, TaC, TaCN, TaSiN, Mn, and Zr.

10. The CMOS semiconductor device of claim 1 , wherein the P-work-function metal comprises a metal selected from a group of TiN, WN, TaN, and Ru.

11. A complementary metal-oxide-semiconductor (CMOS) semiconductor device comprising:

a substrate comprising an isolation region separating a P-active region and an N-active region;

a P-metal gate electrode over the P-active region and extending over the isolation region, wherein the P-metal gate electrode comprises a P-work function metal and a doped TiN layer between the P-work function metal and substrate; and

an N-metal gate electrode over the N-active region and extending over the isolation region, wherein the N-metal gate electrode comprises an N-work function metal and a nitrogen-rich TiN layer between the N-work function metal and substrate, wherein the nitrogen-rich TiN layer contacts the doped TiN layer over the isolation region.

12. The CMOS semiconductor device of claim 11 , wherein the doped TiN layer comprises an oxygen-containing TiN layer or a fluorine-containing TiN layer.

13. The CMOS semiconductor device of claim 11 , wherein a ratio of a width of the P-metal gate to a width of the N-metal gate ranges from about 0.8 to about 1.2.

14. The CMOS semiconductor device of claim 11 , wherein the P-metal gate comprises a signal metal over the P-work function metal.

15. The CMOS semiconductor device of claim 11 , wherein the N-metal gate comprises a signal metal over the N-work function metal.

16. The CMOS semiconductor device of claim 11 , further comprising a high-k dielectric layer between the doped TiN layer and the substrate and between the nitrogen-rich TiN layer and the substrate.

17. The CMOS semiconductor device of claim 11 , wherein the P-metal gate comprises a P-barrier layer between the P-work function metal and the doped TiN layer.

18. The CMOS semiconductor device of claim 11 , wherein the N-metal gate comprises an N-barrier layer between the N-work function metal and the nitrogen-rich TiN layer.

19. A complementary metal-oxide-semiconductor (CMOS) semiconductor device comprising:

a substrate comprising an isolation region separating a P-active region and an N-active region; and

a gate structure over the substrate, the gate structure comprises:

a P-metal gate electrode extending over the isolation region, wherein the P-metal gate electrode comprises a P-work function metal and a doped TiN layer between the P-work function metal and substrate;

an N-metal gate electrode extending over the isolation region, wherein the N-metal gate electrode comprises an N-work function metal and a nitrogen-rich TiN layer between the N-work function metal and substrate, wherein the nitrogen-rich TiN layer contacts the doped TiN layer over the isolation region; and

a TaN layer between the P-metal gate electrode and the N-metal gate electrode.

20. The CMOS semiconductor device of claim 19 , wherein the TaN layer comprises a nitrogen-rich TaN layer, an oxygen-containing TaN layer or a fluorine-containing TaN layer.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2012
From: CHING, KUO-CHENG; HSIEN, TING-HUA; DIAZ, CARLOS H.
To: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
Reel/Frame 028190/0959 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 3, 2012
From: ZHU, MING; LIN, HUI-WEN; CHUANG, HARRY-HAK-LAY; YOUNG, BAO-RU; HUANG, YUAN-SHENG; CHEN, RYAN CHIA-JEN; CHEN, CHAO-CHENG
To: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
Reel/Frame 027468/0689 →
Continuity (1)
Related Publication 20130099323A1 · Apr 25, 2013