Production of high purity lithium compounds directly from lithium containing brines
A process for reducing the amount of magnesium in a lithium-containing brine by adding an aqueous solution of KCl to the brine to precipitate at least some of the magnesium as carnallite salt is disclosed. Lithium salts prepared using this magnesium removal process are also disclosed.
1. A process for reducing an amount of magnesium in a lithium-containing brine comprising
adjusting the brine to a lithium content of from 4.5 to 6.9 wt % to precipitate a first amount of magnesium as bischofite;
concentrating the brine by adding a sufficient amount of a solution of KCl to the adjusted brine to precipitate an additional amount of magnesium as carnallite, and
concentrating the brine further to precipitate another additional amount of magnesium as additional carnallite;
wherein the lithium-containing brine does not contain KCl as carnallite.
2. The method of claim 1 , whereby the brine has an Mg/Li weight ratio, and the Mg/Li weight ratio of the brine is adjusted to a range of from 0.1 to 0.22 at a concentration of at least 5.7 wt % Li to 6.9 wt % Li.
3. The method of claim 2 , wherein the Mg/Li weight ratio is decreased in at least one evaporation pond.
4. The method of claim 2 , wherein the Mg/Li weight ratio is decreased in a container or pipe.
5. The method of claim 2 , wherein some lithium may be precipitated as lithium carnallite.
6. The method of claim 2 , further comprising the step of removing magnesium as carbonate or hydroxide salt.
7. The method of claim 6 , wherein some lithium may be lost due to entrainment within muds that result from precipitated magnesium salts as the carbonate or hydroxide salts.