One-step synthesis of mesoporous pentasil zeolite with single-unit-cell lamellar structural features
A method for making a pentasil zeolite material includes forming an aqueous solution that includes a structure directing agent and a silica precursor; and heating the solution at a sufficient temperature and for sufficient time to form a pentasil zeolite material from the silica precursor, wherein the structure directing agent includes a quaternary phosphonium ion.
1. A material, comprising:
a plurality of zeolite particles each having a unit-cell structure that is lamellar and has a single unit-cell thickness in at least one dimension,
wherein the zeolite particles are intergrown to define pores that extend between the intergrown zeolite particles and so that the lamellar unit cells intersect perpendicular to one another, and
wherein the plurality of zeolite particles are either MFI zeolite particles or pentasil zeolite particles.
2. The material of claim 1 , wherein the pores have at least one dimension of 10 nm or less.
3. The material of claim 1 , wherein the lamellar single-unit-cell structure has a dimension of 2 nm or less.
4. The material of claim 1 , wherein the material has an X-ray diffraction pattern corresponding to the traces shown in FIG. 1( c ).
5. A composite material, comprising the material of claim 1 , wherein the composite material is a film or a coating.