IP Library Granted Patent US 9,108,850
Granted Patent B2
US 9,108,850 · App. 13/299,875 · Granted Aug 18, 2015

Preparing nanoparticles and carbon nanotubes

Inventors: Stephen O'Brien (New York, NY); Limin Huang (Jersey City, NJ); Brian Edward White (Walton, NY); Samuel Jonas Wind (White Plains, NY)
Assignee: The Trustees of Columbia University in the City of New York
C01B31/0233B82Y30/00B82Y40/00C01B2202/02C01B2202/34C01B2202/36Y10T428/24802
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Quick Facts
Patent No.
US 9,108,850
App. No.
13/299,875
Granted
Aug 18, 2015
Kind
B2
Abstract

Apparatus and methods for forming the apparatus include nanoparticles, catalyst nanoparticles, carbon nanotubes generated from catalyst nanoparticles, and methods of fabrication of such nanoparticles and carbon nanotubes.

Claims (17)

1. A method for forming catalyst nanoparticles, the method comprising:

selecting a film thickness of a film of a catalyst material to control for a predetermined effective nanoparticle diameter of the catalyst nanoparticles;

depositing the film of the catalyst material having the selected film thickness in a pattern on and contacting a substrate wherein the catalyst material is capable of being used for forming non-amorphous carbon nanotubes; and

heating the deposited catalyst material causing the deposited catalyst material to disperse forming separated catalyst nanoparticles from the deposited material on and contacting the substrate within the pattern, wherein heating the deposited catalyst material causes the formation of the catalyst nanoparticles with substantially uniform dispersity of the effective nanoparticle diameter.

2. The method of claim 1 , wherein depositing the catalyst material includes depositing a metal film, in which the metal is selected from one or any alloy or other combination of nickel, iron, cobalt, alloy of cobalt and platinum, alloy of iron and platinum, alloy of cobalt and molybdenum, alloy of iron and molybdenum, alloy of nickel and molybdenum, copper, and gold.

3. The method of claim 1 , wherein the predetermined effective nanoparticle diameter of the catalyst nanoparticles in a range from 0.1 nanometers to 100 nanometers.

4. The method of claim 1 , wherein depositing the film of the catalyst material includes depositing the film of the catalyst material on and in contact with a dielectric layer of the substrate.

5. The method of claim 1 , wherein depositing the film of the catalyst material includes depositing the film of the catalyst material on a substrate that includes one or more of silicon, sapphire, quartz, alumina, a silicate, a nitride, GaN, InN, AlN or Si 3 N 4 , germanium, tin, GaAs, InP, SiC, or ZnSe.

6. The method of claim 1 , wherein heating the deposited catalyst material comprises heating the catalyst material in a furnace while feeding a gas comprising an inert gas to the furnace at a flow rate of from about 40 sccm to about 800 sccm.

7. The method of claim 1 , wherein heating the deposited catalyst material comprises heating the catalyst material for a period of from about 10 minutes to about 1 hour and to a temperature of from about 500° C. to about 950° C. to form the separated catalyst nanoparticles.

8. The method of claim 1 , wherein heating the deposited catalyst material comprises heating the catalyst material to a temperature of from about 700° C. to about 900° C. to form the separated catalyst nanoparticles.

9. The method of claim 1 , wherein the film of the catalyst material has a thickness of about 1 nanometer or less.

10. The method of claim 1 , wherein the predetermined effective nanoparticle diameter of the catalyst nanoparticles is from about 1 nm to about 20 nm.

11. The method of claim 1 , wherein depositing the film of the catalyst material comprises depositing the film along only one side of the substrate proximate an edge of the substrate.

12. The method of claim 1 , wherein the substrate comprises a material that is stable at temperatures of from about 500° C. to about 950° C.

13. The method of claim 1 , further comprising selecting the predetermined effective nanoparticle diameter of the catalyst nanoparticles to control for a predetermined nanotube diameter of the carbon nanotubes to be formed on the catalyst nanoparticles.

14. The method of claim 1 , further comprising forming the non-amorphous carbon nanotubes having the predetermined nanotube diameter of from about 0.3 nanometers to about 4 nanometers.

Assignments (4)
CONFIRMATORY LICENSE Recorded Oct 3, 2017
From: COLUMBIA UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 044119/0720 →
CONFIRMATORY LICENSE Recorded Jun 3, 2013
From: COLUMBIA UNIVERSITY; NEW YORK MORNINGSIDE
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 030591/0821 →
CONFIRMATORY LICENSE Recorded Apr 4, 2013
From: COLUMBIA UNIVERSITY NEW YORK MORNINGSIDE
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 030160/0301 →
CONFIRMATORY LICENSE Recorded Jul 10, 2012
From: COLUMBIA UNIVERSITY NEW YORK MORNINGSIDE
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 028521/0115 →
Continuity (4)
Continuation 12246758
Continuation In Part PCTUS2007008389 · Apr 5, 2007
Provisional Application 60790385 · Apr 7, 2006
Related Publication 20120126199A1 · May 24, 2012