Magnesium-based absorbable implants
A bioabsorbable implant including an elongated metallic element having an alloy including more than about 70% by weight magnesium and about 2-20% by weight lithium, and being substantially free of rare earth metals, the elongated metallic element defining at least a portion of the bioabsorbable implant, wherein the alloy defines a columnar microstructure including grains having an average grain length of at least about 1 mm, and an average grain diameter of less than about 3 mm.
1. A bioabsorbable implant comprising:
an elongated metallic element comprising an alloy including more than about 70% by weight magnesium and about 2-20% by weight lithium, and being substantially free of rare earth metals, the elongated metallic element defining at least a portion of the bioabsorbable implant;
wherein the alloy defines a columnar microstructure including grains having an average grain length of at least about 1 mm, and an average grain diameter of less than about 3 mm.
2. The bioabsorbable implant of claim 1 , wherein the alloy comprises about 2.0 to about 5.0% by weight lithium.
3. The bioabsorbable implant of claim 1 , wherein the alloy comprises about 5.0 to 10.5% by weight lithium.
4. The bioabsorbable implant of claim 1 , wherein the alloy comprises 10.5 to 20% by weight lithium.
5. The bioabsorbable implant of claim 1 , wherein the alloy comprises up to 80% magnesium.
6. The bioabsorbable implant of claim 1 , wherein the alloy further comprises at least one of strontium, iron, zinc, calcium and manganese.
7. The bioabsorbable implant of claim 1 , wherein an average grain diameter of the alloy is less than 5 microns in diameter.
8. The bioabsorbable implant of claim 7 , wherein an average grain diameter of the alloy is less than 1 micron in diameter.
9. The bioabsorbable implant of claim 1 , wherein the average grain diameter is less than about 0.2 mm.
10. The bioabsorbable implant of claim 1 , wherein the average grain length is at least about 10 mm.
11. The bioabsorbable implant of claim 1 , wherein the columnar microstructure includes grains having an aspect ratio of grain length to grain diameter of at least 10:1.
12. The bioabsorbable implant of claim 1 , wherein the elongated metallic element comprises at least one of a wire, rod, and a hollow tube.
13. The bioabsorbable implant of claim 12 , wherein the elongated metallic element comprises a wire having a diameter of less than about 0.2 mm.
14. The bioabsorbable implant of claim 1 , wherein the bioabsorbable implant is selected from the group consisting of an intraluminal device, a ligating clip, a ligating clip component, a bone fixation device, and a bone-to-soft-tissue fixation device.
15. The bioabsorbable implant of claim 14 , wherein the bioabsorbable implant is a bone fixation device selected from the group consisting of a plate, a pin, and a screw.
16. The bioabsorbable implant of claim 14 , wherein the bioabsorbable implant is a bone-to-soft-tissue fixation device selected from the group consisting of a suture anchor, an interference screw, and a cross pin.