Additives for transmission oils
The subject of the disclosure concerns microcapsules including a core containing one or more alkali metal borates, optionally hydrated, dispersed in one or more lubricating base oils of mineral, synthetic or natural origin, and a polymer shell. Another subject of the disclosure is a lubricating oil including microcapsules. A further subject of the disclosure is the use of microcapsules according to the disclosure as anti-wear and/or extreme pressure additive for lubricant compositions. A further subject of the disclosure is a method for preparing microcapsules by interface polymerization.
1. Microcapsules comprising:
a core containing one or more borates of alkali metals, dispersed in one or more mineral, synthetic or natural lubricant base oils; and
a polymer shell;
the borates being nanospheres,
the microcapsules being free of water.
2. The microcapsules according to claim 1 , in which the borates of alkali metals are compounds of general formula:
MO 1/2 .m BO 3/2 .n H 2 O (I)
where M is an alkali metal, m is a number between 2.5 and 4.5, and n is a number between 0.50 and 2.40, the monomer repeat unit of formula (I) possibly being repeated several times.
3. The microcapsules according to claim 1 , wherein the polymer is chosen from among the polyesters, polyurethanes, polyamides, polyureas, or the copolymers thereof, polyacrylonitriles, vinyl resins or aminoplast resins.
4. The microcapsules according to claim 1 , having a diameter of between 0.1 μm and 50 μm.
5. The microcapsules according to claim 1 , wherein the borates are nanospheres of diameter between 1 and 300 nm.
6. A lubricating oil comprising a microcapsule, the microcapsule comprising:
a core containing one or more borates of alkali metals, dispersed in at least one oil taken from the group of: mineral, synthetic or natural lubricant base oils; and
a polymer shell;
the borates being nanospheres,
the microcapsules being free of water.
7. The lubricating oil according to claim 6 , having a weight content of boron element, measured as per standard NFT 60-106, of between 500 and 5000 ppm.
8. The lubricating oil according to claim 7 , further comprising at least one of:
one or more anti-wear and extreme-pressure additives; and
one or more friction modifiers, chosen from among monoesters of polyols and fatty acids.
9. The lubricating oil according to claim 7 , being a transmission lubricant.
10. The microcapsules according to claim 1 , being at least one of an anti-wear and extreme- pressure additive for lubricating compositions.
11. The microcapsules according to claim 1 , prepared by an interface polymerization method comprising:
dispersing a hydrophobic phase denoted S1, containing a first monomer denoted M1 and one or more additives, in a continuous phase formed of a non-aqueous organic solvent denoted S2, the continuous phase being non-miscible with the hydrophobic phase and containing either an initiator allowing the chain polymerization of M1, or a monomer M2 leading to a polycondensation reaction with M1, to form polymers or copolymers that are the constituents of the polymer shell of the microcapsules,
wherein the one or more additives include the one or more borates of alkali metals.