Self-pumping membraneless fuel cell
The present invention is directed to a device, and method of operation, for a fuel cell which uses bubble-based pumping to self-pump the fuel to the anode, and a single, common channel separating the anode from the cathode through which a mixed fuel and electrolyte flow. The fuel cell includes a single channel having two of its sides formed by the anode and the cathode, each having a suitable catalyst. A bubble generating region is formed in the anode and cathode reaction area of the channel. A one-way valve is located upstream of the bubble generating region. A vent for venting bubbles is disposed over a portion of the channel downstream of the bubble generating region. The fuel cell may be advantageously used to build miniature fuel cells for miniature electronic devices, or scaled to build larger fuel cells for larger electronic devices.
1. A fuel cell device comprising:
a channel having a first side and a second side, an inlet coupled to a solution comprising a mixture of a fuel and an electrolyte, an outlet downstream of the inlet, and a bubble generating region between the inlet and the outlet;
the first side of the channel comprising an anode, the anode having a first catalyst comprising one of platinum or palladium for oxidizing the fuel within the channel;
the second side of the channel comprising an air-breathing cathode, the air-breathing cathode having a second catalyst comprising one of platinum, palladium, or nickel for reducing oxidant within the channel;
a one-way valve in communication with the channel, the one-way valve located upstream of the bubble generating region;
a vent in communication with the channel, the vent disposed over a portion of the channel downstream of the bubble generating region; and
wherein the mixture of fuel and electrolyte occupies substantially all of the channel between the cathode and the anode except for any space within the channel occupied by bubbles and wherein the fuel cell device has an open circuit potential of at least 0.4 V.
2. The device of claim 1 , wherein the fuel is oxidized at the anode by the first catalyst, producing carbon dioxide bubbles which are used to self-pump the mixture of the fuel and the electrolyte and ions which are reduced at the cathode by the second catalyst.
3. The device of claim 1 , wherein the second catalyst is formed from a different catalytic material than the first catalyst.
4. The device of claim 1 , wherein the one-way valve comprises a plurality of wetting capillaries.
5. The device of claim 1 , wherein the one-way valve comprises a partial obstruction disposed within the channel.
6. The device of claim 1 , wherein the vent comprises a non-wetting venting membrane.
7. The device of claim 1 , wherein the vent comprises a non-wetting porous membrane.
8. The device of claim 1 , wherein the channel diverges in a downstream direction along the bubble generating region.
9. The device of claim 1 , wherein the first catalyst comprises palladium.
10. The device of claim 9 , wherein the second catalyst comprises platinum.
11. The device of claim 1 , wherein the first catalyst comprises platinum.
12. The device of claim 1 , wherein the second catalyst comprises palladium.
13. The device of claim 1 , wherein the second catalyst comprises nickel.
14. The device of claim 1 , wherein the first catalyst and the second catalyst are formed from the same material.
15. A fuel cell comprising:
a plurality of the fuel cell devices of claim 1 operably coupled together.
16. A fuel cell system comprising:
a reservoir containing a solution comprising a mixture of fuel and an electrolyte;
a plurality of fuel cells, each fuel cell comprising:
a channel having a first side and a second side, an inlet coupled to the reservoir, an outlet downstream of the inlet, and a bubble generating region between the inlet and the outlet;
the first side of each channel comprising an anode, the anode having a first catalyst comprising one of platinum or palladiumfor oxidizing a fuel within the channel;
the second side of each channel comprising an air-breathing cathode, the air-breathing cathode having a second catalyst comprising one of platinum, palladium, or nickel for reducing oxidant within the channel;
a one-way valve in communication with the channel, the one-way valve located upstream of the bubble generating region;
a vent in communication with the channel, the vent disposed over a portion of the channel downstream of the bubble generating region; and
wherein the mixture of fuel and electrolyte occupies substantially all of the channel of each of the plurality of fuel cells between the cathode and the anode except for any space within the channel occupied by bubbles and wherein each fuel cell has an open circuit potential of at least 0.4 V.
17. The fuel cell system of claim 16 , wherein the channel for each fuel cell is fabricated on a single piece of substrate.