METHODS FOR REMOVING CONTAMINANTS FROM ALGAL OIL
Methods for removing contaminants from algal oil are provided. In an embodiment, a method comprises the steps of combining a sulfuric acid-aqueous solution that has a pH of about 1 or less with a contaminant-containing algal oil at treatment conditions effective to form an effluent. The effluent comprises a treated algal oil phase and contaminants in an acidic aqueous phase. The contaminants comprise metals, phosphorus, or combinations thereof The acidic aqueous phase is removed from the effluent to form a contaminant-depleted algal oil.
1 . A method for removing contaminants from algal oil, the method comprising the steps of:
combining a sulfuric acid-aqueous solution that has a pH of about 1 or less with a contaminant-containing algal oil at treatment conditions effective to form an effluent that comprises a treated algal oil phase and contaminants in an acidic aqueous phase, wherein the contaminants comprise metals, phosphorus, or combinations thereof; and
removing the acidic aqueous phase from the effluent to form a contaminant-depleted algal oil.
2 . The method of claim 1 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution that has the pH of from about 1 to about −1 with the contaminant-containing algal oil.
3 . The method of claim 1 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution that has the pH of from about 0 to about −0.5 with the contaminant-containing algal oil.
4 . The method of claim 1 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution with the contaminant-containing algal oil at the treatment conditions that include a residence time of from about 30 minutes to about 8 hours, wherein the residence time is defined by an amount of time that the contaminant-containing algal oil is in contact with the sulfuric acid-aqueous solution to form the effluent.
5 . The method of claim 4 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution with the contaminant-containing algal oil at the treatment conditions that include the residence time of from about 1 to about 5 hours.
6 . The method of claim 1 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution with the contaminant-containing algal oil at the treatment conditions that include a temperature of from about 15 to about 45° C.
7 . The method of claim 1 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution with the contaminant-containing algal oil at the treatment conditions that include a pressure of from about 80 to about 120 kPa.
8 . The method of claim 1 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution with the contaminant-containing algal oil at a predetermined acid to oil ratio of from about 1:4 to about 4:1, wherein the predetermined acid to oil ratio is defined by a first weight of the sulfuric acid-aqueous solution to a second weight of the contaminant-containing algal oil.
9 . The method of claim 8 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution with the contaminant-containing algal oil at the predetermined acid to oil ratio of from about 1:2 to about 2:1.
10 . The method of claim 1 , wherein the step of combining comprises combining the contaminant-containing algal oil with the sulfuric acid-aqueous solution that comprises sulfuric acid present in an amount of from about 1 to about 50 wt. % of the sulfuric acid-aqueous solution.
11 . The method of claim 1 , wherein the step of removing comprises separating the acidic aqueous phase from the effluent to form an acidic contaminant-containing aqueous solution, and the method further comprises the step of:
introducing a base-containing composition to the acidic contaminant-containing aqueous solution to neutralize the acidic contaminant-containing aqueous solution.
12 . The method of claim 1 , wherein the step of combining comprises combining the sulfuric acid-aqueous solution with the contaminant-containing algal oil that contains the contaminants comprising Ca, Fe, Mg, Na, Zn, K, P, or combinations thereof.
13 . The method of claim 1 , wherein the step of removing comprises forming the contaminant-depleted algal oil containing about 10 wt. % or less of the contaminants that were originally present in the contaminant-containing algal oil.
14 . A method for removing contaminants from algal oil, the method comprising the steps of:
introducing a contaminant-containing algal oil and a sulfuric acid-aqueous solution that has a pH of about 1 or less to a reactor that is operating at treatment conditions effective to form an effluent that comprises a treated algal oil phase and contaminants in an acidic aqueous phase, wherein the contaminants comprise metals, phosphorus, or combinations thereof; and
introducing the effluent to an oil-water separation zone to remove the acidic aqueous phase from the effluent and form a contaminant-depleted algal oil.
15 . The method of claim 14 , wherein the step of introducing the contaminant-containing algal oil comprises introducing the sulfuric acid-aqueous solution that has the pH of from about 1 to about −1 to the reactor.
16 . The method of claim 14 , wherein the step of introducing the contaminant-containing algal oil comprises operating the reactor at the treatment conditions that include a residence time of from about 30 minutes to about 8 hours, wherein the residence time is defined by an amount of time that the contaminant-containing algal oil is in contact with the sulfuric acid-aqueous solution to form the effluent.
17 . The method of claim 14 , wherein the step of introducing the contaminant-containing algal oil comprises operating the reactor at the treatment conditions that include a temperature of from about 15 to about 45° C.
18 . The method of claim 14 , wherein the step of introducing the contaminant-containing algal oil comprises operating the reactor at the treatment conditions that include a pressure of from about 80 to about 120 kPa.
19 . The method of claim 14 , wherein the step of introducing the effluent comprises separating the acidic aqueous phase from the effluent to form an acidic contaminant-containing aqueous solution, and the method further comprises the step of:
introducing the acidic contaminant-containing aqueous solution and a base-containing composition to a neutralizing zone to neutralize the acidic contaminant-containing aqueous solution with the base-containing composition.
20 . A method for removing contaminants from algal oil, the method comprising the steps of:
introducing a contaminant-containing algal oil and a sulfuric acid-aqueous solution at a predetermined acid to oil ratio of from about 1:4 to about 4:1 to a reactor that is operating at treatment conditions effective to form an effluent that comprises a treated algal oil phase and contaminants in an acidic aqueous phase, wherein the contaminants comprise metals, phosphorus, or combinations thereof and the sulfuric acid-aqueous solution comprises sulfuric acid that is present in an amount of from about 1 to about 50 wt. % of the sulfuric acid-aqueous solution, and wherein the predetermined acid to oil ratio is defined by a first weight of the sulfuric acid-aqueous solution to a second weight of the contaminant-containing algal oil; and
introducing the effluent to an oil-water separation zone to remove the acidic aqueous phase from the effluent and form a contaminant-depleted algal oil.