Austenite-type stainless steel hot-rolling steel material with excellent corrosion resistance, proof-stress, and low-temperature toughness and production method thereof
An austenitic stainless steel hot-rolled steel material can be provided which has sea-water resistance and strength superior to conventional steel. Low-temperature toughness can be maintained, which is preferable in a structural member of speedy craft. The steel material can include an austenitic stainless steel hot-rolled steel material which excels in the properties of corrosion resistance, proof stress, and low-temperature toughness. In such austenitic stainless steel hot-rolling steel material, e.g., PI [=Cr+3.3(Mo+0.5W)+16N] ranges from 35 to 40, δ cal [=2.9 (Cr+0.3Si+Mo+0.5W)−2.6 (Ni+0.3Mn+0.25Cu+35C+20N)−18] ranges from −6 to +2, and a 0.2% proof stress at room temperature is not less than 550 MPa, Charpy impact value measured using a V-notch test piece at −40° C. is not less than 100 J/cm2, and the pitting potential measured in a deaerated aqueous solution of 10% NaCl at 50° C. (Vc′100) is not less than 500 mV (as it relates to saturated Ag/AgCl).
1. An austenitic stainless hot-rolled steel material having a superior corrosion resistance and a low-temperature toughness, comprising:
C: not more than 0.03 mass %;
Si: more than 0.3 mass % and not more than 1.5 mass %;
Mn: 0.1 to 3.0 mass %;
P: not more than 0.05 mass %;
S: not more than 0.003 mass %;
Ni: 15.0 to 21.0 mass %;
Cr: 22.0 to 28.0 mass %;
Mo: 1.5 to 3.5 mass %;
N: 0.15 to 0.35 mass %;
Al: 0.005 to 0.1 mass %;
O: not more than 0.007 mass %; and
a remnant of the steel material comprising Fe and substantially inevitable impurities and a content of intermetallic compounds contained in the steel material is not more than 0.5 mass %, wherein
a PI value expressed by the following formula ranges from 35 to 40: PI=Cr+3.3(Mo+0.5W)+16N; and
a δcal value expressed by the following formula ranges from −6 to +4: δ cal=2.9(Cr+0.3Si+Mo+0.5W)−2.6(Ni+0.3Mn+0.25Cu+35C+20N)−18, wherein
a value by each element represents the content of the element expressed in terms of mass %.
2. The austenitic stainless hot-rolled steel material according to claim 1 , further comprising: at least one of:
Cu: 0.1 to 2.0 mass %;
Ti: 0.003 to 0.03 mass %;
Nb: 0.02 to 0.20 mass %;
V: 0.05 to 0.5 mass %;
W: 0.3 to 3.0 mass %;
B: 0.0003 to 0.0060 mass %;
Ca: 0.0005 to 0.0050 mass %;
Mg: 0.0005 to 0.0050 mass %; or
REM: 0.005 to 0.10 mass %.
3. A process for producing an austenitic stainless hot-rolled steel material having a superior corrosion resistance and a low-temperature toughness, comprising:
C: not more than 0.03 mass %;
Si: more than 0.3 mass % and not more than 1.5 mass %;
Mn: 0.1 to 3.0 mass %;
P: not more than 0.05 mass %;
S: not more than 0.003 mass %;
Ni: 15.0 to 21.0 mass %;
Cr: 22.0 to 28.0 mass %;
Mo: 1.5 to 3.5 mass %;
N: 0.15 to 0.35 mass %;
Al: 0.005 to 0.1 mass %;
O: not more than 0.007 mass %; and
a remnant of the steel material comprising Fe and substantially inevitable impurities and a content of intermetallic compounds contained in the steel material is not more than 0.5 mass %, wherein
a PI value expressed by the following formula ranges from 35 to 40: PI=Cr+3.3(Mo+0.5W)+16N; and
a δ cal value expressed by the following formula ranges from −6 to +4: δ cal=2.9(Cr+0.3Si+Mo+0.5W)−2.6(Ni+0.3Mn+0.25Cu+35C+20N)−18, wherein
a value by each element represents the content of the element expressed in terms of mass %, the process comprising:
performing a homogenizing-heat treatment on a cast steel or a semi-finished product after a rough hot-rolling processing at a temperature of 1200 to 1300° C. for at least one hour in order to reduce the content of the intermetallic compound in the steel material.
4. The process of claim 3 , wherein the austenitic stainless, hot rolled steel material having a superior corrosion resistance and a low-temperature toughness further comprises at least one of:
Cu: 0.1 to 2.0 mass %;
Ti: 0.003 to 0.03 mass %;
Nb: 0.02 to 0.20 mass %;
V: 0.05 to 0.5 mass %;
W: 0.3 to 3.0 mass %;
B: 0.0003 to 0.0060 mass %;
Ca: 0.0005 to 0.0050 mass %;
Mg: 0.0005 to 0.0050 mass %; or
REM: 0.005 to 0.10 mass %.
5. The austenitic stainless hot-rolled steel material according to claim 1 , wherein Si is 0.45 to 1.5 mass %.
6. The austenitic stainless hot-rolled steel material according to claim 2 , wherein Si is 0.45 to 1.5 mass %.
7. The process of claim 3 , wherein Si is 0.45 to 1.5 mass %.
8. The process of claim 4 , wherein Si is 0.45 to 1.5 mass %.