Polymer composition
Polymer composition comprising a) 10-99.99% by weight of at least one polyolefin, b) 0-50% by weight of a thermoplastic that is not a polyolefin, c) 0.005-1% by weight of per se known polymer additives, as well as an additional component chosen among d) at least one polybranched organic/inorganic hybrid polymer which has an inorganic core carrying organic branches, the core and branches forming a particulate structure, or/and e) a fat-soluble metal compound prepared by reacting a metal salt and an acidic, organic compound in a process in which a suitable oxidation agent ensures that all the metal in the end product is present in its highest stable oxidation state at standard conditions (25° C. and maximum 98% humidity).
1. Polymer composition comprising:
a) 10-99.99% by weight of at least one polyolefin,
b) 0-50% by weight of a thermoplastic that is not a polyolefin,
c) 0.005-1% by weight of per se known polymer additives,
d) at least one polybranched organic/inorganic hybrid polymer comprising an inorganic core carrying organic branches that constitute a particle structure, and optionally comprising
e) a fat-soluble metal compound prepared by allowing a metal salt to react with an acidic, organic compound in a process in which a suitable oxidation means ensures that all metal in the final product is present in its highest stable oxidation state at standard conditions (25° C. and maximum 98% humidity).
2. Polymer composition as claimed in claim 1 , characterized in that component d) and component e) together constitute from 0.01 to 90% by weight of the polymer composition.
3. Polymer composition as claimed in claim 1 , characterized in that the particulate polybranched organic/inorganic hybrid polymer is prepared by a sol-gel process, said process comprising the following steps in chronological sequence:
A) the core is made by controlled hydrolysis and condensation of a silane of the structure:
X—B—Si(—Y)3
where X═NR1R2, R1, R2 are chosen among hydrogen, saturated or unsaturated C1-C18 alkyl, substituted or non-substituted aryl, in which the carbon chains of said compounds optionally may include one or more of the elements oxygen, nitrogen, sulphur, phosphorous, silicon, and boron and/or optionally containing one or more hydrolysable silane units, or where R1, R2 are chosen from condensation products or addition products of one or more type of chemical compounds such as acids, alcohols, phenols, amines, aldehydes or epoxides, B is a linkage group chosen among saturated and saturated C1-C18 alkylene, substituted or unsubstituted arylene in which the carbon chains of said compounds may optionally include one or more branches and/or one or more of the elements oxygen, nitrogen, sulphur, phosphorous, silicon, and boron, Y is chosen among hydrolysable residues such as alkoxy, carboxyl, halogen,
B) the organic branches are developed by
i) when at least one of R1, R2 is H, adding at least one reactant that is able to cause N—H hydrogen atoms of the X—B group of the core to be substituted through reactions typical for primary and secondary amines, and/or
ii) adding an acid that is able to cause an addition to the N atoms of the X—B group of the core so that the N atoms are wholly or partially converted to quaternary nitronium ions.
4. Polymer composition as claimed in claim 1 , characterized in that the particulate, polybranched organic/inorganic hybrid polymer is manufacture by a sol-gel process based on at least partially hydrolysed organic amino-functional silanes prepared by controlled hydrolysis and condensation of a silane of the structure:
X—B—Si(—Y)3
Where X═NR1R2, R1, R2 are chosen among hydrogen, saturated or unsaturated C1-C18 alkyl, substituted or non-substituted aryl, in which the carbon chains of said compounds optionally may include one or more of the elements oxygen, nitrogen, sulphur, phosphorous, silicon, and boron and/or optionally containing one or more hydrolysable silane units, or where R1, R2 are chosen from condensation products or addition products of one or more type of chemical compounds such as acids, alcohols, phenols, amines, aldehydes or epoxides, B is a linkage group chosen among saturated and saturated C1-C18 alkylene, substituted or unsubstituted arylene in which the carbon chains of said compounds may optionally include on e or more branches and/or one or more of the elements of oxygen, nitrogen, sulphur, phosphorous, silicon, and boron, Y is chosen among hydrolysable residues such as alkoxy, carboxyl, halogen, while N—H hydrogen atoms of the hybrid polymer subsequent to hydrolysis and condensation may be replaced by organic residues, characterized in that the organic branches are prepared by:
i) when at least one of R1, R2 is H, adding at least one reactant that is able to cause N—H hydrogen atoms of the X—B group of the core to be substituted through reactions typical for primary and secondary amines, and/or
ii) adding an acid that is able to cause an addition to the N atoms of the X—B group of the core so that the N atoms are wholly or partially converted to quaternary nitronium ions.
5. Polymer composition as claimed in claim 3 , characterized in that substitution of N—H hydrogen atoms in the branches organic/inorganic hybrid polymer in step Bi) is conducted by means of an addition reaction.
6. Polymer composition as claimed in claim 3 , characterized in that substitution of N—H hydrogen atoms in the branches organic/inorganic hybrid polymer in step Bii) is conducted by means of a substitution reaction.
7. Polymer composition as claimed in claim 5 , characterized in that the addition reaction comprises substitution of N—H hydrogen atoms by an A=B double bond where A, B are chosen among the elements C, O, N, S and P.
8. Polymer composition as claimed in claim 5 , characterized in that the addition reaction comprises ring opening of an epoxy group.
9. Polymer composition as claimed in claim 8 , characterized in that the ring opening of an epoxy group is followed by the reaction with a ketone or an aldehyde.
10. Polymer composition as claimed in claim 5 , characterized in that the addition reaction comprises substitution of N—H hydrogen atoms by an isocyanate.
11. Polymer composition as claimed in claim 5 , characterized in that the addition reaction comprises ring opening by a cyclic acid anhydride or ring opening by a cyclic acid derivative.
12. Polymer composition as claimed in claim 11 , characterized in that the cyclic acid derivative is a derivative of carbonic acid.
13. Polymer composition as claimed in claim 6 , characterized in that the substitution reaction comprises a reaction with at least one derivative of a linear or cyclic mono functional carboxylic acid.
14. Polymer composition as claimed in claim 6 , characterized in that the substitution reaction comprises a reaction with at least one derivative of a linear or cyclic mono functional carboxylic acid.
15. Polymer composition as claimed in claim 3 , characterized in that the acid being added in step Bii) is a Lewis acid or a Broensted acid.
16. Polymer composition as claimed in claim 3 , characterized in that the substitution of N—H hydrogen atoms in step i) is conducted in an aqueous medium and/or that the substitution in step ii) is conducted in an aqueous medium.
17. Polymer composition as claimed in claim 1 , characterized in that the fat-soluble metal compound is the reaction product of a metal salt and a C8-C24 fatty acid or a C8-C24 fatty acid derivative in a process in which a suitable oxidation agent ensures that the metal is present in its highest stable oxidation state at standard conditions (25° C. and maximum 98% humidity).
18. Polymer composition as claimed in claim 17 , characterized in that the C8-C24 fatty acid or a C8-C24 fatty acid derivative is completely or partially halogenated.
19. The polymer composition of claim 1 , further comprising a fat-soluble metal compound prepared by allowing a metal salt to react with an acidic, organic compound in a process in which a suitable oxidation means ensures that all metal in the final product is present in its highest stable oxidation state at standard conditions (25° C. and maximum 98% humidity).