Granted Patent B2

US 8,697,337 · App. 13/355,769 · Granted Apr 15, 2014

Abstract

Claims (25)

1. A method of laminating a film to a substrate using heat and pressure, wherein the substrate is a photosensitive printing blank comprising at least one photocurable layer, the method comprising the steps of:

a. supplying the substrate to a nip formed between a heated laminating roller and a second roller;

b. supplying a laminating film from a laminating film supply roller over an outer surface of the heated laminating roller and into the nip formed between the heated laminating roller and the second roller; wherein the laminating film first contacts a top surface of the photosensitive printing blank at a point where the photosensitive printing blank advances through the nip;

c. rotating the heated laminating roller in a first direction and the second roller in an opposite direction to advance the photosensitive printing blank with the laminating film thereon through the nip, thereby laminating the film to the top surface of the photosensitive printing blank;

wherein the laminating film is laminated to the top surface of the photosensitive printing blank prior to a step of imagewise exposing the at least one photocurable layer to actinic radiation to selectively crosslink and cure portions of the at least one photocurable layer; and

wherein a wrap angle between the laminating film and the heated laminating roller as measured between a point where the laminating film first contacts the outer surface of the heated laminating roller and the point where the laminating film first contacts the top surface of the photosensitive printing blank is at least 125°.

2. The method according to claim 1 , wherein the photosensitive printing blank is substantially planar.

3. The method according to claim 1 , wherein the wrap angle between the laminating film and the heated laminating roller as measured between the point where the laminating film first contacts the outer surface of the heated laminating roller and the point where the laminating film first contacts the top surface of the planar photosensitive printing blank is at least 145°.

4. The method according to claim 3 , wherein the wrap angle between the laminating film and the heated laminating roller as measured between the point where the laminating film first contacts the outer surface of the heated laminating roller and the point where the laminating film first contacts the top surface of the planar photosensitive printing blank is at least 180°.

5. The method according to claim 1 , wherein the wrap angle between the laminating film and the heated laminating roller as measured between the point where the laminating film first contacts the outer surface of the heated laminating roller and the point where the laminating film first contacts the top surface of the photosensitive printing blank is controlled by positioning a splitter bar at a suitable location between the laminating film supply roller and the heated laminating roller and in contact with the laminating film.

6. The method according to claim 5 , wherein the splitter bar puts tension on the laminating film, thereby increasing the wrap angle between the laminating film and the heated laminating roller.

7. The method according to claim 1 , wherein the photosensitive printing blank comprises a laser ablatable mask layer disposed on the at least one photocurable layer, wherein the laser ablatable mask layer is laser ablated to create an in situ negative in the laser ablatable mask layer, and

wherein the laminating film is laminated to the top of the laser ablatable mask layer.

8. The method according to claim 7 , wherein the laminating film is an oxygen barrier membrane, and wherein after the oxygen barrier membrane is laminated to the top of the laser ablatable mask layer, the method further comprises the steps of:

a. exposing the at least one photocurable layer to actinic radiation through the barrier membrane and the in situ negative;

b. removing the barrier membrane; and

c. developing the imaged and exposed photosensitive printing blank to reveal a relief image therein, said relief image comprising a plurality of relief dots;

wherein the presence of the oxygen barrier membrane produces printing dots having at least one geometric characteristic selected from the group consisting of planarity of a top surface of the printing dots, shoulder angle of the printing dots and edge sharpness of the printing dots, beneficially changed in relation to dots formed without the use of the barrier membrane.

9. The method according to claim 1 , wherein the laminating film is an oxygen barrier membrane.

10. The method according to claim 9 , wherein the oxygen barrier membrane comprises a material selected from the group consisting of polyamides, polyvinyl alcohol, hydroxyalkyl cellulose, copolymers of ethylene and vinyl acetate, amphoteric interpolymers, cellulose acetate butyrate, alkyl cellulose, butyral, cyclic rubbers, polypropylene, polyethylene, polyvinyl chloride, polyester and combinations of one or more of the foregoing.

11. The method according to claim 9 , where the oxygen barrier membrane has an oxygen diffusion coefficient of less than 6.9×10 −9 m 2 /sec.

12. The method according to claim 9 , wherein the oxygen barrier membrane has a thickness of between about 5 and about 300 microns.

13. The method according to claim 9 , wherein the oxygen barrier membrane has an optical transparency of at least about 50%.

14. The method according to claim 1 , wherein the heated laminating roller is maintained at a temperature of at least about 150° F.

15. The method according to claim 14 , wherein the heated laminating roller is maintained at a temperature of at least about 200° F.

Assignments (10)