RARE EARTH REMOVAL OF HYDRATED AND HYDROXYL SPECIES
This disclosure relates generally to methods and rare earth-containing additives for removing target materials in the form of hydroxides, carbonates, hydrates, or oxyhydroxyls from, a typically aqueous, liquid medium.
1 . A composition of the form:
where 0≦X≦8,
wherein MS is one of the following:
M(H 2 O) 6 n , M(H 2 O) 5 OH (n-1 ), M(OH) (n-1) M(H 2 O) 4 (OH) 2 (n-2) , M(OH) 2 (n-2) , M(H 2 O) 3 (OH) 3 (n-3) , M(OH) 3 (n-3) , M(H 2 O) 2 (OH) 4 (n-4) , M(OH) 4 (n-4) , M(H 2 O)(OH) 5 (n-5) , M(OH) 5 (n-5) , M(OH) 6 (n-6) , M(H 2 O) 5 O (n-2) , M(H 2 O) 4 (O) 2 (n-4) , M(H 2 O) 3 (O) 3 (n-6) , M(H 2 O) 2 (O) 4 (n-8) , M(H 2 O)(O) 5 (n-10) , M(H 2 O) 5 CO 3 (n-2) , MCO 3 (n-2) , M(H 2 O) 4 (CO 3 ) 2 (n-4) , M(CO 3 ) 2 (n-4) , M(H 2 O) 3 (CO 3 ) 3 (n-6) , M(CO 3 ) 3 (n-6) , M(H 2 O) 2 (CO 3 ) 4 (n-8) , M(CO 3 ) 4 (n-8) , M(H 2 O)(CO 3 ) 5 (n-10) , M(CO 3 ) 5 (n-10) , M(CO 3 ) 6 (n-12) , M(H 2 O) 4 n , M(H 2 O) 3 OH (n-1) , M(H 2 O) 2 (OH) 2 (n-2) , M(H 2 O)(OH) 3 (n-3) , M(H 2 O) 3 O (n-2) , M(H 2 O) 2 (O) 2 (n-4) , and M(H 2 O)(O) 3 (n-6) ,
wherein “M” is a metal or metalloid having an atomic number selecting from the group consisting of 5, 13, 22-33, 40-52, 72-84, and 89-94,
wherein “n” is a real number <8, and
wherein “n” represents a charge or oxidation state of “M”.
2 . The composition of claim 1 , wherein the composition is in an aqueous medium and wherein the aqueous medium comprises a pH and Eh sufficient to favor MS as the primary species of M.
3 . The composition of claim 1 , wherein the cerium oxide has an oxidation state of (IV) and is in the form of a particulate and wherein M is lead.
4 . The composition of claim 1 , wherein MS is in the form of a hydroxide.
5 . The composition of claim 1 , wherein MS is in the form of an oxyhydroxl compound.
6 . The composition of claim 1 , wherein MS is in the form of a carbonate.
7 . The composition of claim 1 , wherein MS is in the form a metal or metalloid hydrate.
8 . The composition of claim 1 , wherein M is one or more of boron, vanadium, chromium, cadmium, antimony, lead, and bismuth and wherein MS is one or more of a hydroxide, a carbonate, and a metal or metalloid hydrate.
9 . A method, comprising:
contacting, in a liquid medium, a rare earth-containing additive with one or more of a metal or metalloid hydroxide, carbonate, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, and hydrate.
10 . The method of claim 9 , wherein the metal or metalloid has an atomic number selected from the group consisting of 5, 13, 22-33, 40-52, 72-84, and 89-94 and the one or more of a metal or metalloid hydroxide, carbonate, and hydrate has one or more of the following formulas:
M(H 2 O) 6 n , M(H 2 O) 5 OH (n-1 ), M(OH) (n-1) M(H 2 O) 4 (OH) 2 (n-2) , M(OH) 2 (n-2) , M(H 2 O) 3 (OH) 3 (n-3) , M(OH) 3 (n-3) , M(H 2 O) 2 (OH) 4 (n-4) , M(OH) 4 (n-4) , M(H 2 O)(OH) 5 (n-5) , M(OH) 5 (n-5) , M(OH) 6 (n-6) , M(H 2 O) 5 CO 3 (n-2) , MCO 3 (n-2) , M(H 2 O) 4 (CO 3 ) 2 (n-4) , M(CO 3 ) 2 (n-4) , M(H 2 O) 3 (CO 3 ) 3 (n-6) , M(CO 3 ) 3 (n-6) , M(H 2 O) 2 (CO 3 ) 4 (n-8) , M(CO 3 ) 4 (n-8) , M(H 2 O)(CO 3 ) 5 (n-10) , M(CO 3 ) 5 (n-10) , M(CO 3 ) 6 (n-12) , M(H 2 O) 4 n , M(H 2 O) 3 OH (n-1) , M(H 2 O) 2 (OH) 2 (n-2) , and M(H 2 O)(OH) 3 (n-3) ,
wherein “M” is the metal or metalloid,
wherein “n” is a real number ≦8, and
wherein “n” represents a charge or oxidation state of “M”.
11 . The method of claim 10 , wherein the liquid medium is aqueous and has an Eh and pH sufficient to render the one or more of a metal or metalloid hydroxide, carbonate, and hydrate as the primary species of M.
12 . The method of claim 11 , wherein the Eh and pH are determined using a Pourbaix diagram of one or more of FIGS. 2-47 and 57 - 65 .
13 . The method of claim 9 , wherein the rare earth-containing additive is in the form of cerium (IV) and/or cerium (III) and wherein M is lead.
14 . The method of claim 9 , wherein metal or metalloid is in the form of a hydroxide.
15 . The method of claim 9 , wherein metal of metalloid is in the form of a carbonate.
16 . The method of claim 9 , wherein metal or metalloid is in the form a metal or metalloid hydrate.
17 . The method of claim 9 , wherein the metal or metalloid is one or more of boron, vanadium, chromium, cadmium, antimony, lead, and bismuth.
18 . The method of claim 9 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, an oxidizing agent to oxidize a target material-containing species comprising the metal or metalloid to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, and hydrate.
19 . The method of claim 9 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, a reducing agent to reduce a target material-containing species comprising the metal or metalloid to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, and hydrate.
20 . The method of claim 9 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, a base and/or base equivalent to convert a target material-containing species comprising the metal or metalloid to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, and hydrate.
21 . The method of claim 9 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, an acid and/or acid equivalent to convert a target material-containing species comprising the metal or metalloid to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, and hydrate.
22 . The method of claim 9 , wherein the rare earth-containing additive is water soluble.
23 . The method of claim 9 , wherein the rare earth-contaning additive is water insoluble.
24 . A method, comprising:
contacting, in a liquid medium, a rare earth-containing additive with a metal or metalloid target material, the target material being in the form of a hydroxide, carbonate, hydrate, or oxyhydroxyl as a primary species, to remove the target material.
25 . The method of claim 24 , wherein the target material has an atomic number selected from the group consisting of 5, 13, 22-33, 40-52, 72-84, and 89-94 and the target material has one or more of the following formulas:
M(H 2 O) 6 n , M(H 2 O) 5 OH (n-1 ), M(OH) (n-1) M(H 2 O) 4 (OH) 2 (n-2) , M(OH) 2 (n-2) , M(H 2 O) 3 (OH) 3 (n-3) , M(OH) 3 (n-3) , M(H 2 O) 2 (OH) 4 (n-4) , M(OH) 4 (n-4) , M(H 2 O)(OH) 5 (n-5) , M(OH) 5 (n-5) , M(OH) 6 (n-6) , M(H 2 O) 5 O (n-2) , M(H 2 O) 4 (O) 2 (n-4) , M(H 2 O) 3 (O) 3 (n-6) , M(H 2 O) 2 (O) 4 (n-8) , M(H 2 O)(O) 5 (n-10) , M(H 2 O) 5 CO 3 (n-2) , MCO 3 (n-2) , M(H 2 O) 4 (CO 3 ) 2 (n-4) , M(CO 3 ) 2 (n-4) , M(H 2 O) 3 (CO 3 ) 3 (n-6) , M(CO 3 ) 3 (n-6) , M(H 2 O) 2 (CO 3 ) 4 (n-8) , M(CO 3 ) 4 (n-8) , M(H 2 O)(CO 3 ) 5 (n-10) , M(CO 3 ) 5 (n-10) , M(CO 3 ) 6 (n-12) , M(H 2 O) 4 n , M(H 2 O) 3 OH (n-1) , M(H 2 O) 2 (OH) 2 (n-2) , M(H 2 O)(OH) 3 (n-3) , M(H 2 O) 3 O (n-2) , M(H 2 O) 2 (O) 2 (n-4) , and M(H 2 O)(O) 3 (n-6) ,
wherein “M” is the metal or metalloid target material,
wherein “n” is a real number ≦8, and
wherein “n” represents a charge or oxidation state of “M”.
26 . The method of claim 25 , wherein the liquid medium is aqueous and has an Eh and pH sufficient to render the one or more of a metal or metalloid hydroxide, carbonate, and hydrate as the primary species of M.
27 . The method of claim 26 , wherein the Eh and pH are determined using a Pourbaix diagram of one or more of FIGS. 2-47 and 57 - 65 .
28 . The method of claim 24 , wherein the rare earth additive is in the form of cerium (IV) and/or cerium (III) and wherein M is lead.
29 . The method of claim 24 , wherein target material is in the form of a hydroxide.
30 . The method of claim 24 , wherein target material is in the form of a carbonate.
31 . The method of claim 24 , wherein target material is in the form a metal or metalloid hydrate.
32 . The method of claim 24 , wherein the target material is in the form of an oxyhydroxyl compound.
33 . The method of claim 24 , wherein the target material is one or more of boron, vanadium, chromium, cadmium, antimony, lead, and bismuth.
34 . The method of claim 24 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, an oxidizing agent to oxidize a target material-containing species to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate.
35 . The method of claim 24 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, a reducing agent to reduce a target material-containing species comprising the metal or metalloid to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate.
36 . The method of claim 24 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, a base and/or base equivalent to convert a target material-containing species comprising the metal or metalloid to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate.
37 . The method of claim 24 , wherein the contacting step comprises the sub-steps:
introducing, to the medium, an acid and/or acid equivalent to convert a target material-containing species comprising the metal or metalloid to a primary species in the form of the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate, the target material-containing species being different from the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate; and
thereafter contacting, in the medium, the rare earth-containing additive with the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate to remove the one or more of a metal or metalloid hydroxide, carbonate, oxyhydroxyl, and hydrate.
38 . The method of claim 24 , wherein the rare earth-containing additive is water soluble.
39 . The method of claim 24 , wherein the rare earth-containing additive is water insoluble.