Carbonation of metal silicates for long-term CO2 sequestration
In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).
1. A process of sequestering carbon dioxide comprising the steps of:
(a) reacting a metal silicate with a first caustic alkali-metal hydroxide to produce a metal hydroxide comprising metal formerly contained in the metal silicate;
(b) reacting carbon dioxide with at least one of a second caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and
(c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a metal carbonate comprising metal formerly contained in the metal silicate of step (a).
2. A process according to claim 1 , wherein the reaction of step (c) further produces a reconstituted caustic alkali-metal hydroxide, and wherein the process further comprises an additional step (d) of recycling the reconstituted caustic alkali-metal hydroxide from step (c) into the reaction of step (a).
3. A process according to claim 1 , wherein steps (b) and (c) are conducted at a pressure not greater than about 50 bars above the vapor pressure of pure water.
4. A process according to claim 1 , wherein when the metal silicate is magnesium silicate the process produces at least one of magnesite and eitelite, or when the metal silicate is a calcium silicate the process produces calcite, or when the metal silicate is an iron-bearing silicate the process produces siderite.
5. A process according to claim 1 , wherein the metal silicate comprises calcium silcates, magnesium silicates, iron-bearing silicates, or mixtures thereof, and at least one of the first caustic alkali-metal hydroxide and the second caustic alkali-metal hydroxide is comprised of sodium hydroxide, potassium hydroxide, lithium hydroxide, or a mixture thereof.
6. A process according to claim 1 , further comprising reducing the particle size of the metal silicate to an average diameter of less than about two millimeters.