Tube-shaped sputtering target
View Patent ↗A tube-shaped sputtering target is provided having a carrier tube and an indium-based sputtering material arranged on the carrier tube. The sputtering material has a microstructure having a mean grain size of less than 1 mm, measured as the mean diameter of the grains on the sputtering-roughened surface of the sputtering material.
1. A tube-shaped sputtering target comprising a carrier tube and an indium-based sputtering material arranged on the carrier tube, wherein the sputtering material has a microstructure having a mean grain size of less than 1 mm, measured as a mean diameter of grains on a sputtering-roughened surface of the sputtering material, wherein the sputtering material comprises a copper and/or gallium fraction of at most 1% by weight, and wherein the sputtering material has a homogeneous microstructure at least at a distance of more than 1 mm from a surface of the carrier tube facing the sputtering material.
2. The sputtering target according to claim 1 , wherein the sputtering material contains at least one metal from the group of tin and zinc.
3. The sputtering target according to claim 1 , wherein the microstructure has a mean grain size of less than 500 μm.
4. The sputtering target according to claim 1 , wherein the microstructure has a mean grain size of less than 200 μm.
5. The sputtering target according to claim 1 , wherein the sputtering material has a liquidus temperature of no more than 350° C.
6. The sputtering target according to claim 1 , wherein the mean grain size of the sputtering material is established over its thickness measured radially from a target surface to at least 1 mm over the carrier tube.
7. The sputtering target according to claim 1 , wherein the sputtering material consists of a metal having a purity of at least 99.99%.
8. The sputtering target according to claim 1 , wherein the sputtering material consists of a metal having a purity of at least 99.999%.
9. The sputtering target according to claim 1 , wherein at least 90% of the grains are of a size in a range of +/−70% around the mean grain size.
10. The sputtering target according to claim 1 , wherein at least 90% of the grains are of a size in a range +/−50% around the mean grain size.
11. The sputtering target according to claim 1 , wherein the grains of the microstructure of the sputtering material each have a smallest and a largest diameter, and wherein a ratio of largest to smallest diameter of a majority of the grains is greater than 1.5.
12. The sputtering target according to claim 11 , wherein at least the majority of the grains has a shape that deviates from spherical shape.
13. The sputtering target according to claim 1 , wherein the grains of the microstructure of the sputtering material each have a smallest and a largest diameter, and wherein a ratio of largest to smallest diameter of a majority of the grains is greater than 2.
14. The sputtering target according to claim 1 , wherein the grains of the microstructure of the sputtering material each have a smallest and a largest diameter, and wherein a ratio of largest to smallest diameter of a majority of the grains is greater than 3.
15. The sputtering target according to claim 1 , wherein a density of the sputtering material is at least 90% of theoretical density.
16. The sputtering target according to claim 1 , wherein a density of the sputtering material is at least 95% of the theoretical density.
17. The sputtering target according to claim 1 , wherein individual grains of the sputtering material are passivated on their surface by an oxide layer.
18. The sputtering target according to claim 1 , wherein oxygen content of the sputtering material is in a range of 50 to 500 ppm, based on the entire sputtering material.
19. The sputtering target according to claim 1 , wherein oxygen content of the sputtering material is in a range of 70 to 300 ppm, based on the entire sputtering material.
20. The sputtering target according to claim 1 , wherein the carrier tube is made of a non-magnetic material.
21. The sputtering target according to claim 20 , wherein the carrier tube is made of a non-magnetic steel alloy, and an iron content of the sputtering material is no more than 5 ppm higher than an iron content of a starting material for the sputtering material, measured at a minimal distance of 1 mm from the carrier tube or from a layer of adhesion promoter optionally arranged between the sputtering material and the carrier tube.
22. The sputtering target according to claim 20 , wherein the carrier tube is made of a non-magnetic steel alloy, and an iron content of the sputtering material is no more than 1 ppm higher than an iron content of a starting material for the sputtering material, measured at a minimal distance of 1 mm from the carrier tube or from a layer of adhesion promoter optionally arranged between the sputtering material and the carrier tube.
23. The sputtering target according to claim 1 , wherein the sputtering target has a length of at least 500 mm.
24. A method for producing a photovoltaic absorber, the method comprising depositing layers of absorber material on a photovoltaic cell, either directly or in a multi-step process, by sputtering the sputtering target according to claim 1 .
25. A method for deposition of oxidic layers, the method comprising reactive sputtering of the sputtering target according to claim 1 .