Substrate, method of producing substrate, superconducting wire, and method of producing superconducting wire
View Patent ↗A substrate of the present invention includes a copper layer, an alloy layer containing copper and nickel, formed on the copper layer, a nickel layer formed on the alloy layer, and an intermediate layer formed on the nickel layer. The concentration of nickel in the alloy layer at the interface between the alloy layer and the nickel layer is greater than the concentration of nickel in the alloy layer at the interface between the alloy layer and the copper layer. According to the present invention, there can be provided a substrate that allows the AC loss of a superconducting wire to be reduced, a method of producing a substrate, a superconducting wire, and a method of producing a superconducting wire.
1. A substrate comprising:
a copper layer,
an alloy layer containing copper and nickel, formed on said copper layer,
a nickel layer formed on said alloy layer, and
an intermediate layer formed on said nickel layer,
wherein a concentration of nickel in said alloy layer at an interface between said alloy layer and said nickel layer is greater than the concentration of nickel in said alloy layer at the interface between said alloy layer and said copper layer, and copper does not diffuse to a surface of said nickel layer.
2. The substrate according to claim 1 , wherein the concentration of nickel in said alloy layer decreases monotonically from the interface between said alloy layer and said nickel layer towards the interface between said alloy layer and said copper layer.
3. A method of producing a substrate, comprising the steps of:
preparing a substrate having a nickel layer formed on a copper layer through plating,
alloying a portion including a surface of said nickel layer while leaving a remaining portion of said nickel layer, and
epitaxial-growing an intermediate layer on said nickel layer after the step of alloying said nickel layer.
4. The method of producing a substrate according to claim 3 , wherein the step of alloying said nickel layer is carried out under reduced pressure, absent of hydrogen gas.
5. A superconducting wire comprising:
a copper layer,
an alloy layer containing copper and nickel, formed on said copper layer,
a nickel layer formed on said alloy layer,
an intermediate layer formed on said nickel layer, and
a superconducting layer formed on said intermediate layer,
wherein a concentration of nickel in said alloy layer at an interface between said alloy layer and said nickel layer is greater than the concentration of nickel in said alloy layer at the interface between said alloy layer and said copper layer, and cooper does not diffuse to a surface of said nickel layer.
6. The superconducting wire according to claim 5 , wherein the concentration of nickel in said alloy layer decreases monotonically from the interface between said alloy layer and said nickel layer towards the interface between said alloy layer and said copper layer.
7. A method of producing a superconducting wire comprising the steps of:
preparing a substrate having a nickel layer formed on a copper layer through plating,
alloying a portion including a surface of said nickel layer while leaving a remaining portion of said nickel layer,
epitaxial-growing an intermediate layer on said nickel layer after said step of alloying said nickel layer, and
forming a superconducting layer on said intermediate layer.
8. The method of producing a superconducting wire according to claim 7 , wherein the step of alloying said nickel layer is carried out under reduced pressure, absent of hydrogen gas.