Semiconductor nanocrystals used with LED sources
The present invention relates to the use of light-converting, colloidal, doped semiconductor nanocrystals to provide a new generation of high performance, low cost monochromatic and white light sources based on LEDs.
1. A light converting composition comprising luminescent semiconductor nanocrystals capable of receiving substantially all of the fixed wavelength range of light of a light source and converting said fixed wavelength range of light to at least one different wavelength range of light, wherein said luminescent semiconductor nanocrystals comprise undoped, direct bandgap, luminescent low reabsorption (LR) semiconductor nanocrystals, having, simultaneously, an emission center core surrounded by at least one absorbing shell, wherein the emission and absorption of said low reabsorption (LR) semiconductor nanocrystals is physically separated to provide well separated absorption and emission spectral bands reducing self-quenching of the emission of the low reabsorption (LR) semiconductor nanocrystals to zero, wherein said at least one absorbing shell has 5 to 500 times the volume of said emission center core, and wherein said absorbing shell comprises two to twenty monolayers.
2. The light converting composition of claim 1 wherein substantially all is said semiconductor nanocrystals capable of receiving 90% or greater of the fixed wavelength range of light of a light source and converting said fixed wavelength range of light to at least one different wavelength range of light.
3. The light converting composition of claim 1 wherein said semiconductor nanocrystal comprises at least one of the group consisting of ZnSe, CdSe and InP.
4. The light converting composition of claim 1 wherein said semiconductor nanocrystals comprise a mixture of different semiconductor nanocrystals.
5. The light converting composition of claim 4 wherein said different semiconductor nanocrystals absorb in the same range, but emit in different ranges.
6. The light converting composition of claim 1 wherein said semiconductor nanocrystals comprise, simultaneously, an emission center surrounded by at least one absorbing shell and a protective exterior shell.
7. The light converting composition of claim 1 wherein said fixed wavelength range of light is less than 460 nm.
8. The light converting composition of claim 1 wherein said at least one different wavelength range of light is at least one member selected from the group consisting of red, blue, yellow, orange, green and combinations thereof.
9. The light converting composition of claim 1 , wherein said semiconductor nanocrystals are dispersed in a matrix.
10. The light converting composition of claim 1 , wherein said semiconductor nanocrystals are dispersed in a solid or fluid encapsulant.
11. The light converting composition of claim 1 further comprising ligand located on the outer surface of the semiconductor nanocrystals.
12. An LED source comprising an LED wafer and at least one layer of a light converting composition comprising luminescent semiconductor nanocrystals capable of receiving substantially all of the light of the LED wafer and converting said light of the LED wafer to at least one different wavelength range of light, wherein said undoped, direct bandgap, luminescent semiconductor nanocrystals comprise low reabsorption (LR) semiconductor nanocrystals, having, simultaneously, an emission center core surrounded by at least one absorbing shell, wherein the emission and absorption of said low reabsorption (LR) semiconductor nanocrystals is physically separated to provide well separated absorption and emission spectral bands reducing self-quenching of the emission of the low reabsorption (LR) semiconductor nanocrystals to zero, wherein said at least one absorbing shell has 5 to 500 times the volume of said emission center core, and wherein said absorbing shell comprises two to twenty monolayers.
13. A device comprising an LED light source in combination with a light converting composition comprising semiconductor nanocrystals capable of receiving substantially all of the light of said LED light source and converting it to at least one different wavelength range of light, wherein said semiconductor nanocrystals comprise undoped, direct bandgap, low reabsorption (LR) semiconductor nanocrystals, having, simultaneously, an emission center core surrounded by at least one absorbing shell, wherein the emission and absorption of said low reabsorption (LR) semiconductor nanocrystals is physically separated to provide well separated absorption and emission bands reducing self-quenching of the emission of the low reabsorption (LR) semiconductor nanocrystals to zero, wherein said at least one absorbing shell has 5 to 500 times the volume of said emission center core, and wherein said absorbing shell comprises two to twenty monolayers.
14. The device of claim 13 wherein said light converting composition is adjacent to the LED light source.
15. The device of claim 13 wherein said light converting composition is in contact with the LED light source.
16. The device of claim 13 wherein said light converting composition is remote from the light source.
17. The device of claim 13 wherein substantially all of the emission of said device is emitted from said semiconductor nanocrystals.