Process for the production of naphthenic process oils by hydrogenation
A method for producing naphthenic process oils that have a high content of naphthenic carbon atoms of 20-60 wt % and a low content of polycyclic aromatics of less than 3 wt %, determined in accordance with IP 346, by the hydrogenation of a process oil educt that has a high content of polycyclic aromatics, are provided. The method enables secondary extracts, such as are formed in the production of label-free process oils, even in a mixture with primary extracts, to be utilized in an economically meaningful way. The resulting process oils are likewise label-free, so that the use of PCA-containing process oils can be reduced and less of these substances will get into the environment. By avoiding heating oil, CO2 emissions are also reduced. Also, through the direct hydrogenation of DAE, high value naphthenic process oils are obtained. The process oils that are obtained contain surprisingly high amounts of naphthenic hydrocarbon compounds.
1. A method for producing naphthenic process oils that have a carbon distribution CA to CN to CP of 0-30 wt % to 20-65 wt % to 20-55 wt %, determined in according with ASTM D 2140, and a content of polycyclic aromatics (PCAs) of less than 3 wt %, in according with IP 346, wherein a process oil educt that has a content of polycyclic aromatics of at least 3 wt %, determined in accordance with IP 346, and a content of naphthenic carbon atoms CN≦25% wt %, is hydrogenated with hydrogen using a metal catalyst at temperatures of 200-400° C. and pressures of 80-250 bar.
2. The method as in claim 1 , wherein the hydrogenation is carried out at temperatures of 250-400° C.
3. The method as in claim 2 , wherein the hydrogenation is carried out at temperatures of 300-375°.
4. The method as in claim 1 , wherein the metal catalyst is based on a nickel, cobalt, molybdenum, chromium, vanadium, nickel-molybdenum, chromium-vanadium catalyst, a metal oxide, a metal sulfide, or a mixture thereof.
5. The method as in claim 1 , wherein the naphthenic process oil that is produced has a content of naphthenic carbon atoms CN of 30-65 wt %.
6. The method as in claim 1 , wherein the average residence time is 6-60 min.
7. The method as in claim 1 , wherein the process oil educt that is used is a secondary extract from the production of TDAE or MES.
8. The method as in claim 1 , wherein the process oil product that is used is a DAE.
9. The method as in claim 1 , wherein the process oil educt that is used is a mixture of secondary extract and DAE.
10. The method as in claim 8 , wherein the mixture is 75 wt % to 25 wt % up to 25 wt % to 75 wt % secondary extract to DAE.
11. The method as in claim 1 , wherein the aniline point of the naphthenic process oil is between 30 and 115°, determined in accordance with DIN ISO 2977.