Device material for hole injection transport layer, ink for forming hole injection transport layer, device comprising hole injection transport layer, and method for producing the device

1. A device material for a hole injection transport layer, comprising:

a transition metal-containing nanoparticle or nanocluster which contains a transition metal oxide and

a fluorine-containing organic compound attached to the surface of the transition metal-containing nanoparticle or nanocluster by a protective agent in which a linking group which functions to link to the transition metal oxide is contained at the terminal end of a fluorine-containing organic compound;

wherein at least one kind of metal selected from the group consisting of molybdenum and vanadium is contained as the transition metal in the transition metal oxide contained in the transition metal-containing nanoparticle or nanocluster; and

wherein the linking group is one or more kinds selected from the group consisting of ammonium salt and functional groups represented by the following formulae (1a) to (1l) and (1-n):

wherein Z1, Z2 and Z3 are each independently a halogen atom or alkoxy group.

2. The device material for a hole injection transport layer according to claim 1 , wherein the fluorine-containing organic compound contains a fluorinated alkyl group.

3. An ink for forming a hole injection transport layer, comprising the device material for a hole injection transport layer defined by claim 1 and an organic solvent.

4. A method for producing a device comprising two or more electrodes facing each other on a substrate and a hole injection transport layer disposed between two of the electrodes, the method comprising the steps of:

forming a hole injection transport layer comprising the device material for a hole injection transport layer defined by claim 1 on a substrate on which first electrode layers are formed in a pattern, and

forming a pattern with altered wettability on a surface of the hole injection transport layer by disposing a photocatalyst-containing layer substrate in which a photocatalyst-containing layer containing at least a photocatalyst is formed on a base above the hole injection transport layer, with a gap which allows photocatalytic action associated with energy irradiation to affect the hole injection transport layer, and then by performing patterned energy irradiation.

5. The method for producing the device according to claim 4 , further comprising the step of forming a divider between the first electrode layers formed in a pattern on the substrate before the step of forming a hole injection transport layer.

6. The method for producing the device according to claim 5 , wherein the substrate on which the first electrode layers are formed is a transparent substrate; the divider is a divider which reflects or absorbs the energy rays applied in the step of forming a pattern with altered wettability; and in the step of forming a pattern with altered wettability, the pattern with altered wettability is formed on a surface of the hole injection transport layer by applying energy from the transparent substrate side.

7. The method for producing the device according to claim 4 , wherein the method of performing patterned energy irradiation in the step of forming a pattern with altered wettability is a method of performing patterned energy irradiation using a mask.

8. The method for producing the device according to claim 4 , wherein the method of performing patterned energy irradiation in the step of forming a pattern with altered wettability is a method of performing patterned energy irradiation by scanning ultraviolet laser in a pattern.

9. A method for producing a device comprising two or more electrodes facing each other on a substrate and a hole injection transport layer disposed between two of the electrodes, the method comprising the steps of:

forming a hole injection transport layer comprising the device material for a hole injection transport layer defined by claim 1 on a substrate on which electrode layers are formed in a pattern, and

forming a pattern with altered wettability on a surface of the hole injection transport layer by patterned vacuum ultraviolet irradiation.

10. The method for producing the device according to claim 4 , wherein the hole injection transport layer forming step comprises the steps of preparing an ink for forming a hole injection transport layer, which comprises a device material for a hole injection transport layer, wherein a fluorine-containing organic compound is attached to the surface of a transition metal-containing nanoparticle or nanocluster which contains at least a transition metal oxide and an organic solvent, and heating the ink in the presence of oxygen.

11. A device comprising two or more electrodes facing each other on a substrate and a hole injection transport layer disposed between two of the electrodes,

wherein the hole injection transport layer comprises a device material for a hole injection transport layer, comprising: a transition metal-containing nanoparticle or nanocluster which contains a transition metal oxide, and a fluorine-containing organic compound attached to the surface of the transition metal-containing nanoparticle or nanocluster, in which at least one kind of metal selected from the group consisting of molybdenum and vanadium is contained as the transition metal in the transition metal oxide contained in the transition metal-containing nanoparticle or nanocluster, and

wherein the fluorine-containing organic compound of the device material in the surface part of the hole injection transport layer is decomposed and removed.

12. A device comprising two or more electrodes facing each other on a substrate and a hole injection transport layer disposed between two of the electrodes,

wherein the device has a divider between the first electrode layers formed in a pattern on the substrate, and the device has the continuous hole injection transport layer on the first electrode layers in an opening of the divider and on the divider;

wherein the hole injection transport layer on the top of the divider contains a device material for a hole injection transport layer, comprising a transition metal-containing nanoparticle or nanocluster which contains a transition metal oxide, and a fluorine-containing organic compound attached to the surface of the transition metal-containing nanoparticle or nanocluster, in which at least one kind of metal selected from the group consisting of molybdenum and vanadium is contained as the transition metal in the transition metal oxide contained in the transition metal-containing nanoparticle or nanocluster; and

wherein, in the hole injection transport layer on the first electrode layers in the opening of the divider and on the side of the divider, at least part of the fluorine-containing organic compound of the device for a hole injection transport layer is decomposed and removed.

13. The device according to claim 11 , wherein the device is an organic EL device comprising an organic layer which comprises at least a light emitting layer.

14. The device according to claim 12 , wherein the device is an organic EL device comprising an organic layer which comprises at least a light emitting layer.

15. The method for producing the device according to claim 9 wherein the hole injection transport layer forming step comprises the steps of preparing an ink for forming a hole injection transport layer, which comprises a device material for a hole injection transport layer, wherein a fluorine-containing organic compound is attached to the surface of a transition metal-containing nanoparticle or nanocluster which contains at least a transition metal oxide and an organic solvent, and heating the ink in the presence of oxygen.

16. A device material for a hole injection transport layer, comprising:

a transition metal-containing nanoparticle or nanocluster which contains tungsten oxide and

a fluorine-containing organic compound attached to the surface of the transition metal-containing nanoparticle or nanocluster by a protective agent in which a linking group links to the tungsten oxide, and is contained at the terminal end of a fluorine-containing organic compound, and

wherein the linking group is one or more functional groups represented by the following formulae:

wherein Z 1 and Z 2 are each independently a halogen atom or alkoxy group.

17. The device material for a hole injection transport layer according to claim 16 , wherein the protective agent is represented by the following general formula (I):

Y-Q-(A′-FQ′) n -(A-FQ)  General formula (I)

wherein Y is the linking group; Q is a linear, branched or cyclic aliphatic hydrocarbon group, aromatic hydrocarbon group, aliphatic heterocyclic group, aromatic heterocyclic group or a combination thereof, or a direct bond; A and A′ are each independently —NH—, —N═, —S—, —O—, —NH(C═O)—,—O—(C═O)—, —O—(SO 2 )—, —O—(C═O)—O—, —S—(C═O)—O— or a direct bond; FQ and FQ′ are each independently the fluorine-containing organic compound; and n is an integer of 0 or 1 or more.

18. An ink for forming a hole injection transport layer, comprising the device material for a hole injection transport layer defined by claim 16 and an organic solvent.

19. A device comprising two or more electrodes facing each other on a substrate and a hole injection transport layer disposed between two of the electrodes,

wherein the hole injection transport layer comprises the device material for a hole injection transport layer defined by claim 16 , and the fluorine-containing organic compound of the device material in the surface part of the hole injection transport layer is decomposed and removed.

20. A device comprising two or more electrodes facing each other on a substrate and a hole injection transport layer disposed between two of the electrodes,

wherein the device has a divider between the first electrode layers formed in a pattern on the substrate, and the device has the continuous hole injection transport layer on the first electrode layers in an opening of the divider and on the divider, and

wherein, in the hole injection transport layer on the first electrode layers in the opening of the divider and on the side of the divider, at least part of the fluorine-containing organic compound of the device material for a hole injection transport layer defined by claim 16 is decomposed and removed, and the hole injection transport layer on the top of the divider contains the device material for a hole injection transport layer defined by claim 16 .