Carbonaceous nanocomposite having novel structure and fabrication method thereof
Disclosed is a carbonaceous nanocomposite including: a substrate; a graphene sheet formed on a top surface of the substrate in parallel with the substrate; and a carbonaceous nanomaterial provided on another surface of the graphene sheet, the nanomaterial having an aspect ratio of 2 to 75,000 to make a predetermined angle with the graphene sheet. The carbonaceous nanocomposite according to the present disclosure has excellent adhesivity to the substrate and can be attached to the substrate without undergoing a pasting process. Since a two-directional current flow is generated, the electrical resistance of the graphene and carbon nanotube is considerably reduced. In addition, the graphene allows the carbon nanotube to have a high current density and a high specific surface area, thereby accelerating a redox reaction. The excellent heat-radiating property of the graphene sheet allows fast transfer of heat generated in the carbon nanotube to outside, thereby avoiding degradation of the carbon nanotube. Thus, when employed as an electrode for a battery or a field emission display, a higher current density and an extended lifespan can be achieved when compared with the existing art.
1. A carbonaceous nanocomposite comprising:
a substrate, wherein the substrate is a SUS substrate that incorporates carbon;
a graphene sheet formed on the substrate, wherein the graphene sheet has a thickness of 2-100 nm;
a plurality of first carbonaceous nanomaterials disposed on the graphene sheet, wherein the first carbonaceous nanomaterial has two ends, wherein one end is chemically bonded to a first surface of the graphene sheet facing away from the substrate so that the first carbonaceous nanomaterial is affixed to the graphene sheet at a predetermined angle, wherein the first carbonaceous nanomaterials has an aspect ratio of 2 to 75,000; and
a plurality of second carbonaceous nanomaterials disposed between the substrate and a second surface of the graphene sheet facing toward the substrate.
2. The carbonaceous nanocomposite of claim 1 , wherein the graphene sheet comprises 1-100 layers.
3. The carbonaceous nanocomposite of claim 1 , wherein the predetermined angle is 5-90c′.
4. The carbonaceous nanocomposite of claim 1 , wherein the first carbonaceous nanomaterial is one or more selected from carbon nanotube, carbon nanowire and carbon nanofiber.
5. The carbonaceous nanocomposite of claim 4 , wherein the carbon nanotube is single-, double- or multi-walled carbon nanotube.
6. The carbonaceous nanocomposite of claim 4 , wherein the carbon nanotube has a diameter of 2-100 nm.
7. The carbonaceous nanocomposite of claim 1 , wherein the first carbonaceous nanomaterial is formed from one or more catalytic metal selected from Ni, Co, Fe, Pt, Au, Al, Cr, Cu, Mg, Mn, Rh, Si, Ti, W, U and Zr.
8. The carbonaceous nanocomposite of claim 1 , wherein the second carbonaceous nanomaterial is a multi-walled nanotube and/or a carbon nanowire.
9. An electrode for a battery fabricated using the carbonaceous nanocomposite of claim 1 .
10. A solar cell employing the electrode for a battery of claim 9 .
11. A field emission display fabricated using the carbonaceous nanocomposite of claim 1 .
12. A method for fabricating a carbonaceous nanocomposite, comprising:
providing a substrate, wherein the substrate is a SUS substrate that incorporates carbon;
forming a graphene sheet on a surface of the substrate in parallel with the substrate; and
growing a first carbonaceous nanomaterial on a first surface of the graphene sheet facing away from the substrate, wherein the first carbonaceous nanomaterial has an aspect ratio of 2 to 75,000 and makes a predetermined angle with the graphene sheet; and
growing a second carbonaceous nanomaterial between the substrate and a second surface of the graphene sheet facing toward the substrate, and
obtaining the carbonaceous nanocomposite of claim 1 .
13. The method for fabricating a carbonaceous nanocomposite according to claim 12 , wherein the graphene sheet is directly grown by chemical vapor deposition after depositing a catalytic metal by sputtering.
14. The method for fabricating a carbonaceous nanocomposite according to claim 12 , wherein the graphene sheet is formed by preparing graphene oxide and removing oxygen therefrom via heat treatment or chemical treatment.
15. The method for fabricating a carbonaceous nanocomposite according to claim 12 , which comprises mixing graphene oxide or the graphene sheet with an Fe/Mo solvent and then coating the mixture on the substrate.
16. The method for fabricating a carbonaceous nanocomposite according to claim 12 , wherein the first carbonaceous nanomaterial is one or more selected from carbon nanotube, carbon nanowire and carbon nanofiber.
17. The method for fabricating a carbonaceous nanocomposite according to claim 12 , wherein the first carbonaceous nanomaterial is formed by depositing a catalytic metal on the substrate on which the graphene sheet is formed or by immersing the substrate in an aqueous solution of a catalytic metal and then performing chemical vapor deposition.