Polymer particles and coating compositions formulated from the polymer particles
The invention provides polymer particles useful in a variety of applications, including coating applications such as packaging coatings. The polymer particles preferably have a volume-averaged particle size of less than 40 microns, more preferably less than 20 microns. In preferred embodiments, the polymer particles are precipitated particles, more preferably precipitated polyester particles, which are optionally free of low-molecular weight surfactant.
1. A method, comprising:
providing a mixture comprising:
a solid crystallizable thermoplastic polymer having a number average molecular weight of at least 10,000 and a melting point of at least 120° C., wherein the polymer comprises a polyester polymer, and
an organic solvent having a boiling point of at least 120° C.;
heating the mixture to a temperature sufficient to dissolve, but not so high as to melt, the solid thermoplastic polymer in the organic solvent; and
cooling the mixture to form precipitated polymer particles having a volume-averaged particle size of less than 20 microns, wherein the polymer particles are suitable for use as a film-forming binder of a thermally cured interior food-contact food or beverage can coating composition, and wherein the polymer particles are (i) substantially epoxy-free and (ii) substantially free of low-molecular weight surfactant having a number average molecular weight of less than 500.
2. The method of claim 1 , wherein a sufficient amount of thermoplastic polymer is dissolved so that the mixture, after heating, includes at least 10% by weight of dissolved thermoplastic polymer, based on the total weight of organic solvent and thermoplastic polymer dissolved therein.
3. The method of claim 1 , wherein the precipitated polymer particles are formed without using any surfactant.
4. The method of claim 1 , wherein the organic solvent comprises cyclohexanone.
5. The method of claim 1 , wherein the organic solvent has a boiling point of at least 150° C.
6. The method of claim 1 , wherein the precipitated polymer particles comprise polyester particles having a volume-averaged particle size of less than 10 microns.
7. The method of claim 6 , wherein the polyester particles have a volume-averaged particle size of at least 1 micron.
8. The method of claim 1 , wherein the polyester polymer has a melting temperature from 120 to 200° C.
9. The method of claim 1 , wherein the polyester polymer comprises polyethylene terephthalate or a copolymer thereof.
10. The method of claim 1 , further comprising:
combining the precipitated polymer particles with one or more additives selected from a wax, a lubricant, a crosslinker, or a pigment.
11. The method of claim 1 , further comprising:
applying a coating composition including the precipitated polymer particles on a metal substrate prior to or after forming the metal substrate into a food or beverage can or portion thereof; and
thermally curing the coating composition to form an interior food-contact coating.
12. The method of claim 1 , wherein the polyester polymer has a melting temperature from 120 to 180° C.
13. The method of claim 1 , further comprising causing the coating composition to be used on a food or beverage can.
14. A method, comprising:
providing a mixture comprising:
a solid crystallizable thermoplastic polymer having a number average molecular weight of at least 10,000 and a melting point of at least 120° C., wherein the polymer comprises a polyester polymer, and
an organic solvent having a boiling point of at least 120° C.;
heating the mixture to a temperature sufficient to dissolve, but not so high as to melt, the solid thermoplastic polymer in the organic solvent;
cooling the mixture to form precipitated polymer particles having a volume-averaged particle size of less than 20 microns, wherein the polymer particles are suitable for use as a film-forming binder of a thermally cured interior food-contact food or beverage can coating composition, and wherein the polymer particles are (i) substantially epoxy-free and (ii) substantially free of low-molecular weight surfactant having a number average molecular weight of less than 500;
forming a liquid coating composition that includes the precipitated polyester particles; and
applying the coating composition on a metal substrate prior to or after forming the metal substrate into a food or beverage can or a portion thereof.
15. The method of claim 14 , wherein a sufficient amount of thermoplastic polymer is dissolved so that the mixture, after heating, includes at least 10% by weight of dissolved thermoplastic polymer, based on the total weight of organic solvent and thermoplastic polymer dissolved therein.
16. The method of claim 14 , wherein the precipitated polymer particles are formed without using any surfactant.
17. The method of claim 14 , wherein the organic solvent comprises cyclohexanone.
18. The method of claim 14 , wherein the organic solvent has a boiling point of at least 150° C., and wherein the polyester polymer has a melting temperature from 120 to 180° C.
19. The method of claim 14 , wherein the precipitated polymer particles comprise polyester particles having a volume-averaged particle size of less than 10 microns.
20. The method of claim 19 , wherein the polyester particles have a volume-averaged particle size of at least 1 micron, wherein the polyester polymer comprises polyethylene terephthalate or a copolymer thereof.
21. The method of claim 14 , further comprising curing the coating composition on the metal substrate to form a cured coating having a dry film thickness from about 2 to about 10 microns.