Conductive crosslinked body and production process thereof, and transducer, flexible wiring board and electromagnetic wave shield using the conductive crosslinked body
The present invention provides a flexible conductive crosslinked body excellent in durability having a small influence of a reaction residue after the crosslinking on an object to which the conductive crosslinked body adheres, and a production process of the flexible conductive crosslinked body. The conductive crosslinked body is synthesized from a conductive composition containing a rubber polymer, an organic metal compound, and a conducting agent and has a crosslinked structure. The production process of the conductive crosslinked body includes: a mixed solution preparing step for preparing a mixed solution in which the rubber polymer, the conducting agent, and the organic metal compound are mixed in a solvent capable of dissolving the rubber polymer and capable of chelating the organic metal compound; and a crosslinking step for removing the solvent from the mixed solution to allow a crosslinking reaction to proceed. The conductive crosslinked body is suitable as an electrode or a wire for a transducer, a wire for a flexible wiring board, and an electromagnetic wave shield.
1. A conductive crosslinked body used for a transducer including an elastomer dielectric film, a plurality of electrodes that are arranged via the dielectric film, and a wire connected with each of the plurality of electrodes, at least one of the electrodes and the wire being formed of the conductive crosslinked body, characterized by being synthesized from a conductive composition containing a rubber polymer having a functional group capable of reacting with active hydrogen or a nucleophilic substituent having active hydrogen, an organic metal compound, and an electrically conducting agent,
wherein a content of the electrically conducting agent is 0.1 vol % or more and 35 vol % or less per 100 vol % of a volume of the conductive crosslinked body, and
the conductive crosslinked body has a crosslinked structure and is expandable/contractible.
2. The conductive crosslinked body according to claim 1 , wherein the organic metal compound is one or more type(s) selected from a metal alkoxide compound, a metal acylate compound, and a metal chelate compound.
3. The conductive crosslinked body according to claim 1 or 2 , wherein the organic metal compound contains one or more type(s) of elements selected from silicon, titanium, zirconium, hafnium, aluminum, gallium, magnesium, zinc, and boron.
4. The conductive crosslinked body according to claim 1 or 2 , wherein the crosslinked structure is formed by a reaction of the functional group of the rubber polymer with the organic metal compound.
5. The conductive crosslinked body according to claim 4 , wherein the functional group is one or more type(s) selected from a carboxy group, a hydroxy group, an amino group, and an epoxy group.
6. The conductive crosslinked body according to claim 5 , wherein the conducting agent contains carbon black.
7. A production process of the conductive crosslinked body as claimed in claim 1 , characterized by comprising:
a mixed solution preparing step for preparing a mixed solution in which the rubber polymer, the conducting agent, and the organic metal compound are mixed in a solvent that is capable of dissolving the rubber polymer and capable of chelating the organic metal compound; and
a crosslinking step for removing the solvent from the mixed solution so as to allow a crosslinking reaction to proceed.
8. A transducer characterized by comprising:
an elastomer dielectric film;
a plurality of electrodes that is arranged via the dielectric film; and
a wire that is connected with each of the plurality of electrodes, wherein
at least one of the electrodes and the wire is formed of the conductive crosslinked body as claimed in claim 1 .
9. The transducer according to claim 8 , wherein the transducer is an actuator in which the dielectric film expands and contracts in accordance with a voltage applied between the plurality of electrodes.