Process for upgrading a pyrolysis oil, in particular in a refinery
The invention relates to a process for upgrading a pyrolysis oil comprising the following steps: —hydrodeoxygenation treatment ( 10 ) of the pyrolysis oil ( 12 ) and separation of the effluent ( 16 ) obtained into a light aqueous fraction ( 18 ) and a heavy organic fraction ( 20 ), or separation of the pyrolysis oil into an aqueous fraction and a lignin-rich fraction, —pre-reforming ( 22 ) of said aqueous fraction ( 18 ) and treatment of the effluent ( 26 ) obtained in an SMR unit ( 28 ) in order to produce hydrogen ( 34 ), —hydrotreatment ( 40 ) and/or catalytic cracking and/or visbreaking of said heavy organic fraction ( 20 ).
1. A process for the upgrading of pyrolysis oil comprising the following stages:
prereforming a light aqueous fraction obtained after a hydrodeoxygenation treatment of the pyrolysis oil, followed by separation of an effluent stream obtained therefrom into a light aqueous fraction and a heavy organic fraction, wherein the hydrodeoxygenation of the pyrolysis oil is carried out in two reactors in series, the first operating at a temperature of 120 to 180° C., and the second operating at a higher temperature of 300 to 400° C., wherein the prereforming is carried out at a temperature of 225 to 450° C., under a pressure of 1 to 30 bar;
treating the prereformed aqueous fraction in an SMR unit in order to produce hydrogen; and
hydrotreating and/or catalytic cracking and/or viscobreaking the heavy organic fraction.
2. The upgrading process as claimed in claim 1 , in which the hydrogen produced from the light aqueous fraction is used for the hydrotreating and/or catalytic cracking of the heavy organic fraction and/or for the hydrodeoxygenation of the pyrolysis oil.
3. The upgrading process as claimed in claim 1 , in which the effluent stream obtained during the hydrotreating of the heavy organic fraction is separated into a light aqueous fraction and a heavy organic fraction, when the amount of aqueous fraction is sufficiently high to be able to be separated, this light aqueous fraction being sent to the prereforming with the light aqueous fraction resulting from the hydrodeoxygenation of the pyrolysis oil.
4. The upgrading process as claimed in claim 1 , in which the heavy organic phase resulting from the hydrodeoxygenation of the pyrolysis oil is fractionated before the hydrotreating stage.
5. The upgrading process as claimed in claim 1 , in which, during the hydrotreating stage, the heavy organic phase resulting from the hydrodeoxygenation of the pyrolysis oil, or the gas oil fraction resulting from the fractionation of the heavy organic phase resulting from the hydrodeoxygenation of the pyrolysis oil, is cotreated with a feedstock of the gas oil type resulting from an atmospheric distillation of crude oil (gas oil straight run) or from a vacuum distillation of the atmospheric residue (vacuum gas oil) or a feedstock of the type consisting of gas oil resulting from a conversion process.
6. The upgrading process as claimed in claim 1 , in which the light aqueous phase resulting from the hydrodeoxygenation of the pyrolysis oil comprises hydrocarbon products comprising at most 6 or 7 carbon atoms.
7. The upgrading process as claimed in claim 1 , in which the hydrodeoxygenation of the pyrolysis oil is carried out at a temperature of 150 to 350° C. and a pressure of 100 to 200 bar.
8. The upgrading process as claimed in claim 1 , in which the prereforming is carried out with a water/HC feedstock molar ratio of 10 to 15.
9. The process as claimed in claim 1 , in which a stage of catalytic conversion of residual CO, optionally followed by a stage of purification of the hydrogen, is carried out after the stage of treatment of the effluent stream in the SMR unit.