Method for producing siliceous film and polysilazane coating treatment liquid used therefor
View Patent ↗The present invention provides a method for forming a siliceous film. According to the method, a siliceous film having a hydrophilic surface can be formed from a polysilazane compound at a low temperature. In the method, a composition containing a polysilazane compound and a silica-conversion reaction accelerator is applied on a substrate surface to form a polysilazane film, and then a polysilazane film-treatment solution is applied thereon so that the polysilazane compound can be converted into a siliceous film at 300° C. or less. The polysilazane film-treatment solution contains a solvent, hydrogen peroxide and an alcohol.
1. A siliceous film formation method comprising
a polysilazane-film formation step, in which a composition comprising a polysilazane compound and a silica-conversion reaction accelerator is applied, by spin coating, on a substrate surface to form a polysilazane film;
a promoter application step, in which a polysilazane film-treatment solution is applied by casting on said polysilazane film; and
a hardening step, in which said polysilazane compound is converted into a siliceous film at a temperature of 300° C. or less;
wherein
said polysilazane film-treatment solution comprises a solvent, 0.5 to 10 wt% of hydrogen peroxide and 25 to 98 wt% of an alcohol, based on the total weight thereof.
2. The siliceous film formation method according to claim 1 , wherein said polysilazane compound is a perhydropolysilazane compound.
3. The siliceous film formation method according to claim 1 , wherein said silica-conversion reaction accelerator is selected from a metal carboxylate, a N-heterocyclic compound and an amine compound.
4. The siliceous film formation method according to claim 1 , wherein said alcohol is selected from the group consisting of monools, diols and oxyethers.
5. The siliceous film formation method according to claim 1 , wherein said solvent is water.
6. The siliceous film formation method according to claim 1 , wherein said hardening step is carried out at room temperature.
7. A polysilazane film-treatment solution
which is applied on a polysilazane film formed by applying, by spin coating, a composition containing a polysilazane compound and a silica-conversion reaction accelerator, so as to promote conversion of the polysilazane compound into silica;
characterized by comprising a solvent, 0.5 to 10 wt% of hydrogen peroxide and 25 to 98 wt% of an alcohol, based on the total weight thereof.
8. The method of claim 1 , where the alcohol can have 1 to 8 carbon atoms.
9. The composition of claim 7 , where the alcohol is selected from the group consisting of monools, diols and oxyethers.
10. The composition of claim 7 , where the alcohol can have 1 to 8 carbon atoms.
11. The composition of claim 7 , where the solvent is water.
12. The composition of claim 7 , where the alcohol is selected from methanol, ethanol, n-propanol, iso-propanol, butanol, hexanol octanol, ethylene glycol, propylene glycol, 1-methoxy-2-propanol, 2-ethoxyethanol and mixtures thereof.
13. The method of claim 1 , where the alcohol is selected from methanol, ethanol, n-propanol, iso-propanol, butanol, hexanol octanol, ethylene glycol, propylene glycol, 1-methoxy-2-propanol, 2-ethoxyethanol and mixtures thereof.