CHARACTERIZATION OF CRUDE OIL BY NEAR INFRARED SPECTROSCOPY
A system and a method for calculating the cetane number, pour point, cloud point and aniline point of a gas oil fraction of a crude oil from the density and near infrared spectroscopy of a sample of the crude oil.
1 . A system for evaluating a crude oil sample and calculating indicative properties of a gas oil fraction of the crude oil without first distilling the gas oil fraction from the crude oil, the system comprising:
a near infrared spectrometer;
a non-volatile memory device that stores calculation modules and data;
a processor coupled to the non-volatile memory;
a first calculation module that calculates a near infrared absorbance index from a summation of near infrared spectroscopy absorbance values of the crude oil for peaks detected at a predetermined series of wavenumbers;
a second calculation module that derives the cetane number for the gas oil fraction as a function of the near infrared absorbance index and density of the sample;
a third calculation module that derives the pour point for the gas oil fraction as a function of the near infrared absorbance index and density of the sample;
a fourth calculation module that derives the cloud point for the gas oil fraction as a function of the near infrared absorbance index and density of the sample; and
a fifth calculation module that derives the aniline point for the gas oil fraction as a function of the near infrared absorbance index and density of the sample.
2 . The system of claim 1 , wherein the gas oil boils in the nominal range 180-370° C.
3 . The system of claim 1 , wherein the wavenumber of near infrared spectrum is in the range 4,000-12,821 cm −1 .
4 . A method for evaluating a crude oil sample and calculating indicative properties, the method comprising:
determining the density of the crude oil sample;
subjecting said crude oil sample to near infrared spectroscopy analysis;
calculating a near infrared absorbance index from a summation of near infrared spectroscopy spectra data absorbance values of the crude oil sample for peaks detected at a predetermined series of wavenumbers;
calculating a cetane number as a function of the near infrared absorbance and density of the sample;
calculating pour point as a function of the near infrared absorbance and density of the sample;
calculating a cloud point as a function of the near infrared absorbance and density of the sample; and
calculating an aniline point as a function of the near infrared absorbance and the density of the sample.
5 . The method of claim 4 , wherein the gas oil boils in the nominal range 180-370° C.
6 . The method of claim 4 , wherein the wavenumber of near infrared spectrum is in the range 4,000-12,821 cm −1 .
7 . A system for evaluating a crude oil sample and determining an indicative property, the system comprising:
a near infrared spectrometer;
a non-volatile memory device that stores calculation modules and data, the data including density of the crude oil sample and near infrared spectroscopy absorbance values obtained from the near infrared spectrometer;
a processor coupled to the non-volatile memory;
a first calculation module that calculates a near infrared absorbance index from a summation of near infrared spectroscopy absorbance values of the crude oil for peaks detected at a predetermined series of wavenumbers; and
a second calculation module that calculates the indicative property as a function of the near infrared absorbance index and the density of the sample.
8 . The system of claim 7 , wherein the indicative property is the cetane number.
9 . The system of claim 7 , wherein the indicative property is the pour point.
10 . The system of claim 7 , wherein the indicative property is the cloud point.
11 . The system of claim 7 , wherein the indicative property is the aniline point.
12 . A method for evaluating a crude oil sample and calculating an indicative property, the method comprising:
determining the density of the crude oil sample;
subjecting the crude oil sample to near infrared spectroscopy analysis;
calculating a near infrared absorbance index from a summation of near infrared spectroscopy spectra absorbance values of the crude oil sample for peaks detected at a predetermined series of wavenumbers; and
calculating and recording the indicative property as a function of the near infrared absorbance index and the density of the sample.
13 . The method of claim 12 , wherein the indicative property is the cetane number.
14 . The method of claim 12 , wherein the indicative property is the pour point.
15 . The method of claim 12 , wherein the indicative property is the cloud point.
16 . The method of claim 12 , wherein the indicative property is the aniline point.