Predominantly biodegradable release film
The present invention relates to a predominantly biodegradable double-separating film and comprising at least one carrier layer (a) that is based on at least one biodegradable polymer, and at least one release layer (b) that is based on at least one cured polysiloxane. The curing of said release layer is based, at least partially, on at least one cross-linked monomer or oligomer additive. Said additive also promotes adhesion between the carrier layer (a) and the release layer (b), and has no siloxane groups but does have at least two functional groups, of which at least one is a functional group with at least one carbon double bond. No adhesion-promoting layer is present between the carrier layer (a) and the release layer (b). In addition the invention relates to the use of such a separating film as a removable protection and cover film.
1. A two-layer, more than 50% by weight biodegradable removable protective film or liner film consisting of
(a) one backing layer based on at least one biodegradable polymer selected from the group consisting of lactic acid homopolymers, lactic acid copolymers, polylactides, polyhydroxyalkanoates, thermoplastic starch, polyester, at least partly hydrolyzed polyvinyl acetates, ethylene-vinyl alcohol copolymers, copolymers of at least two monomers of the stated polymers, and mixtures of at least two of the stated polymers and
(b) one release layer based on at least one cured polysiloxane which curing is based at least partly on a reaction with at least one crosslinking monomeric or oligomeric additive,
said additive also causing the adhesion between the backing layer (a) and the release layer (b), and no adhesion layer is present between the backing layer (a) and the release layer (b), whereby
the additive used contains no siloxane groups, and
has at least two functional groups of which at least one is a functional group containing at least one carbon double bond and
at least one functional group not consumed by the curing of the polysiloxane causing said adhesion promotion between the backing layer (a) and the release layer (b), which is selected from the group consisting of hydroxyl groups, carboxyl groups, and acid anhydride groups.
2. The removable protective film or liner film as claimed in claim 1 , wherein the cured polysiloxane has a degree of polymerization of ≧10.
3. The removable protective film or liner film as claimed in claim 1 , wherein said cured polysiloxane comprises at least one cured polysiloxane which is cured via functional groups of the polysiloxane, at least partly by crosslinking with at least one functional group of the additive that is selected from the group consisting of functional groups containing at least one carbon double bond, epoxide groups, isocyanate groups, hydroxyl groups, amine groups, amide groups, carboxyl groups, acid anhydride groups, alkoxy groups, phosphoric acid groups, phosphoric ester groups, silane groups, and alkoxysilane groups.
4. The removable protective film or liner film as claimed in claim 1 , wherein said cured polysiloxane comprises at least two cured polysiloxanes.
5. The removable protective film or liner film as claimed in claim 1 , wherein the release layer (b) is based on 0.01% to 30% by weight of the crosslinking additive which promotes adhesion.
6. The removable protective film or liner film as claimed in claim 1 , wherein the additive used has a molecular weight of not more than 5000 g/mol.
7. The removable protective film or liner film as claimed in claim 1 , wherein the additive used has at least two crosslinking functional groups of which at least one is a functional group containing at least one carbon double bond, and the further crosslinking functional group or groups is or are selected from the group consisting of functional groups containing at least one carbon double bond, epoxide groups, isocyanate groups, hydroxyl groups, amine groups, amide groups, carboxyl groups, acid anhydride groups, alkoxy groups, phosphoric acid groups, phosphoric ester groups, silane groups, and alkoxysilane groups.
8. The removable protective film or liner film as claimed in claim 1 , wherein the additive used has at least two crosslinking functional groups, and at least one of these functional groups
is a crosslinking functional group containing at least one carbon double bond and selected from the group consisting of (meth)acrylic acid groups, vinyl groups, allyl groups, and (meth)acrylic acid derivative groups,
and at least one further functional group
is a crosslinking functional group containing at least one carbon double bond and selected from the group consisting of (meth)acrylic acid groups, vinyl groups, allyl groups, and (meth)acrylic acid derivative groups,
or is a silane group,
or is an alkoxysilane group,
or is a functional group selected from the group consisting of epoxide groups, isocyanate groups, hydroxyl groups, amine groups, amide groups, carboxyl groups, and acid anhydride groups.
9. The removable protective film or liner film as claimed in claim 1 , wherein the adhesion of the release layer (b) and the backing layer (a) is promoted by reaction of at least one functional group of the additive with at least one functional group of the biodegradable polymer of the backing layer (a).
10. The removable protective film or liner film as claimed in claim 1 , wherein the additive used is a monomeric compound.
11. The removable protective film or liner film as claimed in claim 1 , having a release layer (b) on one surface of said backing layer (a).
12. The removable protective film or liner film as claimed in claim 1 , wherein said at least one functional group not consumed by the curing of the polysiloxane is selected from the group consisting of vinyl groups, allyl groups, (meth)acrylic acid groups, and (meth)acrylic acid derivative groups, epoxide groups, isocyanate groups, amine groups, amide groups, alkoxy groups, phosphoric acid groups, phosphoric ester groups, silane groups (Si—H groups), and alkoxysilane groups.
13. A multi-layer, more than 50% by weight biodegradable removable protective film or liner film consisting of
(a) one backing layer based on at least one biodegradable polymer selected from the group consisting of lactic acid homopolymers, lactic acid copolymers, polylactides, polyhydroxyalkanoates, thermoplastic starch, polyester, at least partly hydrolyzed polyvinyl acetates, ethylene-vinyl alcohol copolymers, copolymers of at least two monomers of the stated polymers, and mixtures of at least two of the stated polymers and
(b) one release layer based on at least one cured polysiloxane which curing is based at least partly on a reaction with at least one crosslinking monomeric or oligomeric additive,
said additive also causing the adhesion between the backing layer (a) and the release layer (b), with the consequence that no separate adhesion promoting layer is present between the backing layer (a) and the release layer (b), whereby
the additive used contains no siloxane groups,
has at least two functional groups of which at least one is a functional group containing at least one carbon double bond, and
at least one functional group not consumed by the curing of the polysiloxane causing said adhesion promotion between the backing layer (a) and the release layer (b), which is selected from the group consisting of hydroxyl groups, carboxyl groups, and acid anhydride groups,
(c) and having at least one further substrate layer (c) based on at least one biodegradable polymer selected from the group consisting of cellulose, cellulose derivatives, paper, and thermoplastic starch.
14. A method for producing the multilayer removable protective film or liner film as claimed in claim 13 , comprising co-extruding or producing by lamination the backing layer (a) or a laminate of at least one backing layer (a) and at least one substrate layer (c), subsequently coating the backing layer (a) or a laminate comprising at least the backing layer (a) coated on at least one surface with the release layer (b) based on a mixture of at least one uncured polysiloxane and at least one crosslinker and adhesion promoter additive, and curing this mixture by exposure to heat or electromagnetic radiation or by moisture, optionally by addition of at least one UV initiator and/or free-radical initiator, and joining to the backing layer (a).
15. A method of protecting a substrate comprising covering a portion of the substrate to be protected with the removable protective film or liner film as claimed in claim 13 .
16. A method of protecting adhesive foods comprising covering the adhesive foods with the removable protective film or liner film as claimed in claim 13 .
17. A method of lining during the processing of adhesive resins, fibers, fabrics or other materials, comprising lining the resins, fibers, fabrics or other materials with the removable protective film or liner film as claimed in claim 13 .
18. A method of protecting adhesive pharmaceutical products, or adhesive sanitary and hygiene products, comprising covering the products with the removable protective film or liner film as claimed in claim 13 .