Organic light emitting display devices and methods of manufacturing organic light emitting display devices
An organic light emitting display device comprising a first electrode; a hole transport layer, an emitting layer and an electron transport layer disposed sequentially on the first electrode; and a second electrode formed on the electron transport layer, wherein the emitting layer comprises a host material comprising a calixarene compound represented by Chemical Formula (1) wherein, in the Chemical Formula (1), each of R 1 to R 4 is defined as in the specification.
1. An organic light emitting display device, comprising:
a first electrode;
a hole transport layer, an emitting layer and an electron transport layer disposed sequentially on the first electrode; and
a second electrode formed on the electron transport layer,
wherein the emitting layer comprises a host material comprising a calixarene compound represented by Chemical Formula (1) and a dopant material,
wherein, in the Chemical Formula (1), each of R 1 to R 4 independently represents one selected from the group consisting of a phenyl group, a biphenyl group, a naphthyl group, an anthracene group, a phenanthrene group, a pyrene group and a benzopyrene group which are unsubstituted or substituted with an aromatic group, an indole group or an indole group substituted with an aryl group, or a phenyl group substituted with 9-carbazole.
2. The organic light emitting display device of claim 1 , wherein the host material comprises at least one calixarene compound selected from the compounds represented by Chemical Formula (2), Chemical Formula (3), Chemical Formula (4) and Chemical Formula (5)
3. The organic light emitting display device of claim 1 , wherein the host material comprises a calixarene compound represented by Chemical Formula (6)
4. The organic light emitting display device of claim 1 , the host material comprises at least one calixarene compound selected from the compounds represented by Chemical Formula (7), Chemical Formula (8) and Chemical Formula (9)
5. The organic light emitting display device of claim 1 , wherein the dopant material comprises at least one organometallic compound having a metal selected from the group consisting of iridium (Ir), platinum (Pt), osmium (Os) and gold (Au).
6. The organic light emitting display device of claim 1 , wherein the dopant material comprises at least one selected from the group consisting of PtOEP, Ir(ppy) 3 and BTPIr.
7. The organic light emitting display device of claim 1 , further comprising a hole injection layer formed between the first electrode and the hole transport layer.
8. The organic light emitting display device of claim 1 , further comprising an electron injection layer formed between the electron transport layer and the second electrode.
9. The organic light emitting display device of claim 1 , further comprising a hole blocking layer formed between the emitting layer and the electron transport layer.
10. The organic light emitting display device of claim 1 , further comprising an electron blocking layer formed between the emitting layer and the hole transport layer.
11. The organic light emitting display device of claim 1 , further comprising a switching device electrically connected to the first electrode, wherein the first electrode is electrically connected to a source electrode or a drain electrode of the switching device and the first electrode serves as an anode providing holes.
12. The organic light emitting display device of claim 1 , wherein the host material serves as a fluorescent host material or phosphorescent host material, and the dopant material includes a fluorescent dopant material or a phosphorescent dopant material.
13. A method for manufacturing an organic light emitting display device, comprising:
preparing a substrate having a switching device;
forming a first electrode on the substrate;
forming a hole transport layer, an emitting layer and an electron transport layer sequentially on the first electrode; and
forming a second electrode on the electron transport layer,
wherein the emitting layer is formed using a host material comprising a calixarene compound represented by Chemical Formula (1) and a dopant material,
wherein, in the Chemical Formula (1), each of R 1 to R 4 independently represents one selected from the group consisting of a phenyl group, a biphenyl group, a naphthyl group, an anthracene group, a phenanthrene group, a pyrene group and a benzopyrene group which are unsubstituted or substituted with an aromatic group, an indole group or an indole group substituted with an aryl group, or a phenyl group substituted with 9-carbazole.
14. The method for manufacturing an organic light emitting display device of claim 13 , further comprising:
forming a hole injection layer on the first electrode prior to forming the hole transport layer; and
forming an electron injection layer on the electron transport layer prior to forming the second electrode.
15. The method for manufacturing an organic light emitting display device of claim 13 , further comprising:
forming an electron blocking layer on the hole transport layer prior to forming the emitting layer; and
forming a hole blocking layer on the emitting layer after forming the emitting layer.