Quality multi-spectral zinc sulfide
View Patent ↗Low scatter water clear zinc sulfide with reduced metal contamination is prepared by cleaning an inert foil with an acid cleaning method and also cleaning zinc sulfide to reduce metal contamination. The zinc sulfide is wrapped in the inert foil and then treated by a HIP process to provide a water-clear zinc sulfide. The low scatter water-clear zinc sulfide may be used in articles such as windows and domes.
1. A method for making water clear zinc sulfide comprising:
a) removing metallic contaminants from an inert platinum foil by etching and cleaning with a solution comprising sulfuric acid and one or more oxidizing agents, or an aqueous nitric acid solution to provide a clean inert platinum foil;
b) removing one or more metallic contaminants chosen from nickel, copper, chromium, cobalt and palladium from a zinc sulfide substrate to provide a clean zinc sulfide substrate, wherein the metallic contaminants are removed from the zinc sulfide substrate by organic acid cleaning, cyanide cleaning, cyanate cleaning, thiocompound cleaning, amine cleaning or combinations thereof;
c) wrapping the clean zinc sulfide substrate in the clean inert platinum foil; and
d) treating the clean zinc sulfide substrate wrapped in the clean inert platinum foil by a HIP process to provide the water clear zinc sulfide, wherein the water clear zinc sulfide comprises transmission at a wavelength of 0.3 μm to 1 μm, a forward scatter of less than or equal to 3%/cm as measured in a half cone of 3 degrees from the direction of incident beam at 0.6328 μm wavelength as measured with a helium/neon laser and a refractive index homogeneity of less than or equal to 15 ppm.
2. The method of making water clear zinc sulfide of claim 1 , wherein the one or more oxidizing agents are chosen from sodium permanganate, potassium permanganate and hydrogen peroxide.
3. The method of making water clear zinc sulfide of claim 1 , wherein the inert platinum foil is etched and cleaned with the aqueous nitric acid solution.
4. The method of making water clear zinc sulfide of claim 1 , wherein the zinc sulfide substrate is chosen from windows, domes, lenses or beam splitters.
5. The method of making water clear zinc sulfide of claim 1 , wherein the refractive index homogeneity is from 0.5 ppm to 15 ppm.
6. The method of claim 1 , wherein the organic acid is chosen from one or more of acetic acid, oxalic acid, citric acid, salts thereof and mixtures thereof.
7. A method for making water clear zinc sulfide comprising:
a) removing metallic contaminants from an inert platinum foil by etching and cleaning with a solution comprising sulfuric acid and one or more oxidizing agents, or an aqueous nitric acid solution to provide a clean inert platinum foil;
b) removing one or more metallic contaminants chosen from nickel, copper, chromium, cobalt and palladium from a zinc sulfide substrate to provide a clean zinc sulfide substrate, wherein the metallic contaminants are removed from the zinc sulfide substrate by cyanide cleaning, cyanate cleaning, thiocompound cleaning, amine cleaning or combinations thereof;
c) wrapping the clean zinc sulfide substrate in the clean inert platinum foil; and
d) treating the clean zinc sulfide substrate wrapped in the clean inert platinum foil by a HIP process to provide the water clear zinc sulfide, wherein the water clear zinc sulfide comprises transmission at a wavelength of 0.3 μm to 1 μm, a forward scatter of less than or equal to 3%/cm as measured in a half cone of 3 degrees from the direction of incident beam at 0.6328 μm wavelength as measured with a helium/neon laser and a refractive index homogeneity of less than or equal to 15 ppm.