Nanocomposite and method of making thereof
An embodiment of an inorganic nanocomposite includes a nanoparticle phase and a matrix phase. The nanoparticle phase includes nanoparticles that are arranged in a repeating structure. In an embodiment, the nanoparticles have a spherical or pseudo-spherical shape and are incompatible with hydrazine. In another embodiment, the nanoparticles have neither a spherical nor pseudo-spherical shape. The matrix phase lies between the nanoparticles of the nanoparticle phase. An embodiment of a method of making an inorganic nanocomposite of the present invention includes forming a nanoparticle superlattice on a substrate. The nanoparticle superlattice includes nanoparticles. Each nanoparticle has organic ligands attached to a surface of the nanoparticle. The organic ligands separate adjacent nanoparticles within the nanoparticle superlattice. The method also includes forming a solution that includes an inorganic precursor. The nanoparticle superlattice is placed in the solution for a sufficient time for the inorganic precursor to replace the organic ligands.
1. An inorganic nanocomposite comprising:
a nanoparticle phase comprising nanoparticles arranged in a repeating structure; and
an inorganic matrix phase between the nanoparticles of the nanoparticle phase,
wherein the nanoparticle phase comprises a transparent conducting metal oxide and the matrix phase comprises a metal oxide, and wherein the inorganic nanocomposite is part of an electrochromic device.
2. The inorganic nanocomposite of claim 1 wherein the repeating structure is a close packed structure.
3. The inorganic nanocomposite of claim 1 wherein the nanoparticles comprise nanoparticles that have a spherical or pseudo-spherical shape.
4. The inorganic nanocomposite of claim 1 wherein the nanoparticles are aligned nanoparticles selected from the group consisting of nanorods, nanowires, and tetrapods.
5. The inorganic nanocomposite of claim 1 wherein the transparent conducting oxide of the nanoparticles comprises a metal selected from the group comprising Sn, Zn, and W.
6. The inorganic nanocomposite of claim 1 further comprising a substrate attached to the inorganic matrix phase.
7. The inorganic nanocomposite of claim 1 , wherein the repeating structure has three-dimensional ordering.
8. The inorganic nanocomposite of claim 1 , wherein the inorganic matrix phase comprises a polyoxometalate.
9. The inorganic nanocomposite of claim 1 , wherein the inorganic nanocomposite is formed from:
a superlattice of the nanoparticles arranged in the repeating structure, each nanoparticle having organic ligands attached to a surface; and
a solution containing the metal oxide of the inorganic matrix phase, wherein the metal oxide replaces the organic ligands.
10. The electrochromic device comprising the inorganic nanocomposite of claim 1 .
11. A window coating comprising the electrochromic device of claim 10 .