Low metal loaded, catalyst compositions including acidic mixed metal oxide as support
View Patent ↗The invention provides a method of transaminating a reactant with a catalyst composition comprising support and catalyst portions. The support includes an acidic mixed metal oxide including a transitional alumina and a second metal oxide. The transitional alumina can comprise delta or theta alumina, in combination with other transitional phases, or an alpha or gamma alumina. The second metal oxide has a weight percentage less than the weight percentage of alumina. The catalyst portion is 25 weight percent or less of the catalyst composition and is composed of nickel and rhenium. The catalyst portion includes nickel in an amount in the range of 2 to 20 weight percent, based upon total catalyst composition weight, and there is no boron in the catalyst portion. The method provides high activity and selectivity for reactant transamination to a desired product while minimizing the formation of unwanted cyclic products.
1. A method for transaminating a reactant compound comprising the step of contacting the reactant compound with a catalyst composition comprising:
(a) a support portion comprising an acidic mixed metal oxide comprising a transitional alumina and a second metal oxide wherein the second metal oxide has a weight percentage that is less than the weight percentage of alumina; and
(b) a catalyst portion comprising nickel and rhenium, wherein (i) the catalyst portion is 25 weight percent or less of the catalyst composition, (ii) the catalyst portion comprises nickel in an amount in the range of 2 to 20 weight percent, based upon total catalyst composition weight, and (iii) there is no boron in the catalyst portion, and (iv) the catalyst portion is deposited as a shell structure on the support portion in a manner effective to provide a localized concentration of nickel and rhenium on an outer surface of the catalyst composition,
wherein the reactant compound becomes transaminated to an aminated product.
2. The method according to claim 1 , wherein the reactant compound is EDA and the aminated product is DETA.
3. The method according to claim 2 , wherein DETA is present in a product mixture containing PIP and the DETA to PIP ratio is in the range of 9:1 to 13:1 at 25% EDA conversion.
4. The method according to claim 1 , wherein the reactant compound is EDA and the aminated product is TETA.
5. The method according to claim 4 , wherein TETA is present in a product mixture containing PIP and the TETA to PIP ratio is in the range of 0.75:1 to about 1.5:1 at 25% EDA conversion.
6. The method according to claim 1 , wherein the support portion comprises the second metal oxide in an amount in the range of 5 weight percent to less than 50 weight percent, based upon the weight of the support portion.
7. The method according to claim 1 , wherein the catalyst portion is 20 weight percent or less of the catalyst composition.
8. The method according to claim 1 , wherein the nickel and rhenium are present in the catalyst portion in a weight ratio in the range of 3:1 to 14:1.
9. The method according to claim 1 , wherein the composition further comprises a selectivity promoter that is present at a promoter/nickel weight ratio of 0.5:1 or less.
10. The method according to claim 1 , wherein at least 50 weight % of the reactant compound forms the transaminated compound.
11. The method according to claim 1 , wherein the reactant is provided to a reaction vessel at a flow rate of at least 5 gmol/hr/kg catalyst.
12. The method according to claim 1 , wherein the reactant is contacted with a continuous stream of the catalyst composition in a reaction vessel.
13. The method according to claim 1 , wherein the reactant and the catalyst composition are contacted in the presence of hydrogen.
14. The method according to claim 13 , wherein the hydrogen is present at a level of 0.001 to 10 mol % of the liquid feed.
15. The method according to claim 1 , wherein the reactant and the catalyst composition are contacted at a temperature of from 110° C. to 180° C.
16. The method according to claim 1 , wherein the reactant and the catalyst composition are contacted at a pressure of from 200 psig to 2000 psig.