Nitride semiconductor light emitting device and method of manufacturing the same
View Patent ↗The present invention provides a nitride semiconductor light emitting device having an n-electrode that has an Au face excellent in ohmic contacts to an n-type nitride semiconductor and excellent in mounting properties, and a method of manufacturing the same. The nitride semiconductor light emitting device uses an n-electrode having a three-layer laminate structure that is composed of a first layer containing aluminum nitride and having a thickness not less than 1 nm or less than 5 nm, a second layer containing one or more metals selected from Ti, Zr, Hf, Mo, and Pt, and a third layer made of Au, from the near side of the n-type nitride semiconductor in order of mention. The n-electrode thus formed is then annealed to obtain ohmic contacts to the n-type nitride semiconductor.
1. A nitride semiconductor light emitting device, comprising:
a substrate selected from one of sapphire, GaN, SiC, and Si;
an expitaxially-grown n-type GaN semiconductor layer formed over the substrate;
a plurality of expitaxially-grown nitride semiconductor layers, formed over the n-type GaN semiconductor layer, comprising an n-type nitride semiconductor layer, a light emitting layer, and a p-type nitride semiconductor layer;
a p-type electrode formed after said epitaxial growth and electrically connected to the p-type nitride semiconductor layer; and
an n-type electrode formed on an exposed surface of the n-type GaN semiconductor layer after said epitaxial growth,
wherein the exposed surface of the n-type GaN semiconductor layer comprises etched portions of the plurality of nitride semiconductor layers,
wherein the n-type electrode comprises a first layer, a second layer, and a third layer, disposed on the exposed surface of the n-type GaN semiconductor layer, and provided in order as listed,
wherein the first layer contains aluminum nitride provided in contact with the exposed surface of the n-type GaN semiconductor layer and has a thickness of at least 1 nm and less than 5 nm,
wherein the second layer contains one or more metals selected from Ti, Zr, Hf, Mo, and Pt, and
wherein the third layer is made of Au.
2. The nitride semiconductor light emitting device according to claim 1 ,
wherein an electrical property making a junction between the n-type electrode and the n-type GaN semiconductor layer is an ohmic property.
3. The nitride semiconductor light emitting device according to claim 1 ,
wherein the second layer of the n-type electrode comprises a two-layer structure having Ti disposed adjacent to the first layer and Pt disposed adjacent to the third layer.
4. The nitride semiconductor light emitting device according to claim 1 ,
wherein the aluminum nitride is provided in a form of islands, so as to expose at least part of the exposed surface of the n-type GaN semiconductor layer.
5. The nitride semiconductor light emitting device according to claim 1 ,
wherein the nitride semiconductor light emitting device is a light emitting diode (LED).
6. A nitride semiconductor light emitting device, comprising:
an n-type GaN substrate comprising a first surface and a second surface;
a plurality of expitaxially-grown nitride semiconductor layers, formed over the first surface of the n-type GaN substrate, comprising an n-type nitride semiconductor layer, a light emitting layer, and a p-type nitride semiconductor layer;
a p-type electrode formed after said epitaxial growth and electrically connected to the p-type nitride semiconductor layer; and
an n-type electrode formed on the second surface of the n-type GaN substrate,
wherein the n-type electrode comprises a first layer, a second layer, and a third layer, disposed at a second surface side of the n-type GaN substrate, and provided in order as listed,
wherein the first layer contains aluminum nitride provided in contact with the second surface of the n-type GaN substrate and has a thickness of at least 1 nm and less than 5 nm,
wherein the second layer contains one or more metals selected from Ti, Zr, Hf, Mo, and Pt, and
wherein the third layer is made of Au.
7. The nitride semiconductor light emitting device according to claim 6 ,
wherein an electrical property making a junction between the n-type electrode and the n-type GaN substrate is an ohmic property.
8. The nitride semiconductor light emitting device according to claim 6 ,
wherein the second layer of the n-type electrode comprises a two-layer structure having Ti disposed adjacent to the first layer and Pt disposed adjacent to the third layer.
9. The nitride semiconductor light emitting device according to claim 6 ,
wherein the aluminum nitride is provided in a form of islands, so as to expose at least part of the n-type GaN substrate.
10. The nitride semiconductor light emitting device according to claim 6 ,
wherein the nitride semiconductor light emitting device is a laser diode (LD).