CNS-infused carbon nanomaterials and process therefor
A composition includes a carbon nanotube (CNT) yarn or sheet and a plurality of carbon nanostructures (CNSs) infused to a surface of the CNT yarn or sheet, wherein the CNSs are disposed substantially radially from the surface of the CNT yarn or outwardly from the sheet. Such compositions can be used in various combinations in composite articles.
1. A composition comprising:
a carbon nanotube (CNT) yarn;
a plurality of carbon nanostructures (CNSs) infused to a surface of the carbon nanotube yarn;
wherein the CNSs are disposed substantially radially from the surface of the the CNT yarn;
wherein the CNSs comprise a carbon nanotube array that includes individual carbon nanotubes, branched carbon nanotubes, and crosslinked carbon nanotubes in a random distribution with one another; and
a barrier coating on the CNT yarn from which the CNSs are grown, the barrier coating comprising a material selected from the group consisting of an alkoxysilane, a methylsiloxane, and alumoxane, spin on glass, and glass nanoparticles.
2. The composition of claim 1 , wherein the CNT yarn comprises single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, or mixtures thereof.
3. The composition of claim 2 , wherein the CNT yarn comprises single-walled carbon nanotubes.
4. The composition of claim 1 , wherein the plurality of CNSs comprise elements of single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, or mixtures thereof.
5. The composition of claim 1 , further comprising a matrix material to provide a composite.
6. The composition of claim 5 , wherein the matrix material comprises one selected from the group consisting of a thermoplastic resin, a thermoset resin, a further carbon phase, a ceramic and a metal.
7. An article comprising a plurality of carbon nanotube (CNT) yarns in a bundle, each of the plurality of CNT yarns of the bundle comprising a plurality of carbon nanostructures (CNSs) infused to a surface of each of the plurality CNT yarns, the CNSs being disposed substantially radially from the surfaces of each of the plurality of CNT yarns;
wherein the CNSs comprise a carbon nanotube array that includes individual carbon nanotubes, branched carbon nanotubes, and crosslinked carbon nanotubes in a random distribution with one another; and
a barrier coating on the CNT yarns from which the CNSs are grown, the barrier coating comprising a material selected from the group consisting of an alkoxysilane, a methylsiloxane, and alumoxane, spin on glass, and glass nanoparticles.
8. A composition comprising:
a carbon nanotube sheet;
a plurality of carbon nanostructures infused to at least one surface of the carbon nanotube sheet, the carbon nanostructures being disposed substantially outward from the at least one surface of the carbon nanotube sheet;
wherein the carbon nanostructures comprise a carbon nanotube array that includes individual carbon nanotubes, branched carbon nanotubes, and crosslinked carbon nanotubes in a random distribution with one another; and
a barrier coating on the carbon nanotube sheet from which the carbon nanostructures are grown, the barrier coating comprising a material selected from the group consisting of an alkoxysilane, a methylsiloxane, an alumoxane, spin on glass, and glass nanoparticles.
9. The composition of claim 8 , wherein the carbon nanotube sheet comprises single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, or mixtures thereof.
10. The composition of claim 9 , wherein the carbon nanotube sheet comprises single-walled carbon nanotubes.
11. The composition of claim 8 , wherein the carbon nanotube array comprises elements of single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, or mixtures thereof.
12. The composition of claim 8 , further comprising a matrix material to provide a composite.
13. The composition of claim 12 , wherein the matrix material comprises one selected from the group consisting of a thermoplastic resin, a thermoset resin, a further carbon phase, a ceramic and a metal.
14. A multilayered article comprising:
a plurality of carbon nanotube sheets stacked upon one another, each carbon nanotube sheet comprising a plurality of carbon nanostructures infused to at least one surface of each of the plurality of carbon nanotube sheets;
wherein the carbon nanostructures comprise a carbon nanotube array that includes individual carbon nanotubes, branched carbon nanotubes, and crosslinked carbon nanotubes in a random distribution with one another; and
a barrier coating on the carbon nanotube sheets from which the carbon nanostructures are grown, the barrier coating comprising a material selected from the group consisting of an alkoxysilane, a methylsiloxane, an alumoxane, spin on glass, and glass nanoparticles.