Insulating sheet, circuit board, and process for production of insulating sheet
An object of the present invention is to provide an insulating sheet superior in heat dissipation efficiency, heat resistance, insulation efficiency and moldability. Provided is a sheet-shaped insulating sheet of a resin composition containing an epoxy resin, a curing agent and an inorganic filler, wherein one or both of the epoxy resin and the curing agent have a naphthalene structure, the inorganic filler contains hexagonal boron nitride, and the inorganic filler is contained in an amount of 70 to 85 vol % in the entire resin composition. It is possible to increase the filling efficiency of an inorganic filler in the insulating sheet by using an epoxy resin and/or a curing agent having a naphthalene structure, which are favorably compatible with the hexagonal boron nitride contained in the inorganic filler.
1. A sheet-shaped insulating sheet of a resin composition containing an epoxy resin, a curing agent and an inorganic filler, wherein one or both of the epoxy resin and the curing agent have a naphthalene structure, wherein the inorganic filler contains hexagonal boron nitride, and the hexagonal boron nitride is contained in an amount of 80 to 85 vol % in the entire resin composition, and the hexagonal boron nitride contains coarse particles having an average particle diameter of 10 to 400 μm and fine particles having an average particle diameter of 0.5 to 4.0 μm, wherein the blending rate of the coarse particles is 85% or more.
2. The insulating sheet according to claim 1 , which is in the B stage state.
3. The insulating sheet according to claim 1 , which is in the C stage state.
4. The insulating sheet according to claim 1 , wherein the hexagonal boron nitride is oriented in a plane flow direction or a thickness direction of the sheet.
5. An insulating sheet, which is obtained by laminating multiple pieces of an insulating sheet according to claim 2 , and cutting the laminate in a thickness direction.
6. A circuit board, comprising a metal substrate, an insulating sheet according to claim 1 laminated on the metal substrate, and an electronic circuit formed on the insulating sheet.
7. The circuit board according to claim 6 , having electronic parts mounted on the electronic circuit.
8. The sheet-shaped insulating sheet defined in claim 1 , produced by a method comprising a laminating step of laminating a resin composition containing an epoxy resin, a curing agent and an inorganic filler, wherein one or both of the epoxy resin and the curing agent have a naphthalene structure, the inorganic filler contains hexagonal boron nitride, and the inorganic filler is contained in an amount of 80 to 85 vol % in the entire resin composition, between two supporting films and a molding step of molding the laminate after the laminating step into an insulating sheet having a thickness of 50 to 500 μm.
9. The sheet-shaped insulating sheet defined in claim 8 , wherein molding means in the molding step is a roll press and a temperature of the resin composition during molding is 5 to 300° C.
10. The sheet-shaped insulating sheet defined in claim 8 , wherein the supporting film is a polymer film release-treated on a surface in contact with the resin composition.
11. The sheet-shaped insulating sheet defined in claim 8 , wherein the supporting film is a metal foil.
12. The sheet-shaped insulating sheet defined in claim 2 , produced by a laminating step of laminating multiple pieces of the insulating sheet, a cutting step of cutting the laminate after the laminating step in a thickness direction, and a planarization step of making the terminal cut face planar.
13. A method of producing the insulating sheet defined in claim 1 , comprising a laminating step of laminating a resin composition containing an epoxy resin, a curing agent and an inorganic filler, wherein one or both of the epoxy resin and the curing agent have a naphthalene structure, the inorganic filler contains hexagonal boron nitride, and the inorganic filler is contained in an amount of 80 to 85 vol % in the entire resin composition, between two supporting films and a molding step of molding the laminate after the laminating step into an insulating sheet having a thickness of 50 to 500 μm.
14. The method of producing the insulating sheet according to claim 13 , wherein molding means in the molding step is a roll press and a temperature of the resin composition during molding is 5 to 300° C.
15. The method of producing the insulating sheet according to claim 13 , wherein the supporting film is a polymer film release-treated on a surface in contact with the resin composition.
16. The method of producing the insulating sheet according to claim 13 , wherein the supporting film is a metal foil.
17. A method of producing the insulating sheet defined in claim 2 , comprising a laminating step of laminating multiple pieces of an insulating sheet according to claim 2 , a cutting step of cutting the laminate after the laminating step in a thickness direction, and a planarization step of making the terminal cut face planar.
18. A sheet-shaped insulating sheet of a resin composition containing an epoxy resin, a curing agent and an inorganic filler, wherein both of the epoxy resin and the curing agent have a naphthalene structure, wherein the inorganic filler contains hexagonal boron nitride, and the hexagonal boron nitride is contained in an amount of 80 to 85 vol % in the entire resin composition, and the hexagonal boron nitride contains coarse particles having an average particle diameter of 10 to 400 μm and fine particles having an average particle diameter of 0.5 to 4.0 μm, wherein the blending rate of the coarse particles is 85% or more.