Inerting process for impurities
An inerting process for impurities in aggregates intended for preparation of hydraulic or hydrocarbon compositions, includes adding to the composition or to one of its constituents a cationic polymer corresponding to at least one derivative of a natural polymer or a polymer of natural origin selected from the group including dextrin (in particular yellow dextrin and white dextrin), chitosan, chitin, alginates, hemicellulose, pectin, polyols or proteins.
1. A process for preparation of an inerted hydraulic or hydrocarbon composition, comprising:
a) providing aggregates comprising impurities and a hydraulic or hydrocarbon binder to prepare a hydraulic or hydrocarbon composition, and
b) adding a cationic polymer to the composition or to one of its constituents, the cationic polymer corresponding to at least one derivative of dextrin, chitosan or chitin.
2. The process according to claim 1 , wherein the cationic polymer is cationic dextrin.
3. The process according to claim 2 , wherein the cationic polymer is yellow cationic dextrin.
4. The process according to claim 1 , wherein the cationic polymer is substituted by quaternary amine groups.
5. The process according to claim 4 , wherein the quaternary amine groups are derived from a quaternary amine compound according to formulae (1) or (2):
wherein n is an integer from 1 to 16;
X is a halogen;
Z is an inorganic or organic anion;
R, R 1 , R 2 and R 3 , which may be identical or different, are each hydrogen or an organic radical, R 2 furthermore capable of being a group according to formulae (3) or (4):
wherein p is an integer from 2 to 10 and n, R, R 1 , R 2 , R 3 , X and Z are as previously defined.
6. The process according to claim 5 , wherein R, R 1 , R 2 and R 3 are each hydrogen or an alkyl, hydroxyalkyl, alkenyl or aryl group comprising up to 10 carbon atoms.
7. The process according to claim 5 , wherein R, R 1 , R 2 and R 3 are each hydrogen.
8. The process according to claim 6 , wherein the quaternary amine compound is selected from the group consisting of:
2,3-epoxypropyl-N,N,N-trimethylammonium chloride;
3-chloro-2-hydroxypropyl-N,N,N-trimethylammonium chloride;
3-chloro-2-hydroxypropyl-N,N-dimethylethanolammonium chloride; and
1,3-bis-(3-chloro-2-hydroxypropyl-N,N-diméthylammonium)N-propane dichlorohydrin.
9. The process according to claim 5 , wherein the quaternary amine compound is selected from the group consisting of betaine, betainyl chloride and betaine chloride.
10. The process according to claim 1 , wherein the cationic polymer has a degree of substitution of from 0.2 to 2.5.
11. The process according to claim 1 , wherein the hydraulic composition is a concrete or a mortar.
12. The process according to claim 1 , wherein the cationic polymer is added to a sand of the aggregates.
13. The process according to claim 1 , wherein the cationic polymer is added to a mixing water when preparing the hydraulic composition.
14. The process according to claim 1 , wherein the impurities are clays.
15. A process for preparation of an inerted hydraulic or hydrocarbon composition, comprising:
a) providing sand comprising impurities;
b) adding a cationic polymer to the sand of step a), the cationic polymer corresponding to at least one derivative of dextrin, chitosan or chitin, and
c) mixing the inerted sand obtained after step b) and a hydraulic or hydrocarbon binder to prepare the inerted hydraulic or hydrocarbon composition.
16. The process according to claim 15 , wherein the sand is contacted with the cationic polymer by spraying the cationic polymer in aqueous solution on the sand.
17. The process according to claim 15 , wherein the sand has a humidity value less than 10% by weight.
18. The process according to claim 15 , wherein the sand is treated with a dosage of 300 ppm to 10000 ppm by dry mass of cationic polymer relative to a mass of sand.
19. The process according to claim 15 , wherein the impurities are clays.
20. A process for preparation of an inerted hydraulic composition, comprising:
a) providing aggregate comprising impurities;
b) providing a hydraulic binder;
c) adding a cationic polymer to mixing water, the cationic polymer corresponding to at least one derivative of dextrin, chitosan or chitin, and
d) mixing the aggregates, hydraulic binder and mixing water to prepare the inerted hydraulic composition.
21. The process according to claim 1 , wherein the polymer is added at a quarry or at a concrete mixing plant.
22. The process according to claim 12 , wherein the cationic polymer is added by spraying an aqueous solution.