Use of certain chemical elements for inhibiting the formation of precipitates containing zirconium molybdate in an aqueous solution containing the element molybdenum and the element zirconium

1. A method for inhibiting the formation of a precipitate in an aqueous solution, wherein the precipitate comprises zirconium molybdate and the aqueous solution comprises the element molybdenum and the element zirconium, the method comprising adding at least one chemical element selected from the group consisting of plutonium, tellurium, antimony and mixtures thereof to the aqueous solution.

2. The method according to claim 1 , wherein the chemical element is selected from the group consisting of plutonium with valence (IV), tellurium with valence (VI), antimony and mixtures thereof.

3. The method according to claim 1 , wherein the aqueous solution is a nitric acid solution.

4. The method according to claim 3 , wherein the nitric acid solution stems from the dissolution of a used nuclear fuel by nitric acid.

5. The method according to claim 3 , wherein the nitric acid solution has normality ranging from 0.5 to 6 N.

6. The method according to claim 3 , wherein the nitric acid solution has a temperature ranging from 20° C. to the boiling temperature of the solution.

7. The method according to claim 1 , wherein the chemical element is plutonium with valence (IV).

8. The method according to claim 1 , wherein the plutonium has a concentration ranging from 1 to 50 g·L −1 for a nitric acid solution having a normality from 0.5 to 6 N, the solution comprising the molybdenum at a concentration from 0.5 to 6 g·L −1 and the zirconium at a concentration from 0.5 to 6 g·L −1 .

9. The use method according to claim 1 , wherein the chemical element is tellurium with valence (VI).

10. The method according to claim 1 , wherein the tellurium has a concentration ranging from 0.05 to 1 g·L −1 for a nitric acid solution having normality from 0.5 to 6 N, the solution comprising the molybdenum at a concentration from 0.5 to 6 g·L −1 and the zirconium at a concentration from 0.5 to 6 g·L −1 .

11. A method for reprocessing a used nuclear fuel comprising the element molybdenum and the element zirconium, successively comprising the following steps:

dissolving the used nuclear fuel into nitric acid, by which a solution is obtained comprising the molybdenum and the zirconium in amounts capable of generating the formation of a precipitate comprising zirconium molybdate; and

adding at least one element selected from the group consisting of plutonium, tellurium, antimony and mixtures thereof to the solution so as to attain in the solution a concentration of said at least one element required for inhibiting the formation of the precipitate comprising zirconium molybdate.

12. The method according to claim 11 comprising, for a solution of nitric acid having a normality from 0.5 to 6 N comprising the molybdenum at a concentration from 0.5 to 6 g·L −1 and the zirconium at a concentration from 0.5 to 6 g·L −1 , adding the tellurium, during an additional successive step, in an amount so as to obtain a concentration of the tellurium ranging from 0.05 to 1 g·L −1 .

13. The method according to claim 11 comprising, for a solution of nitric acid having a normality from 0.5 to 6 N comprising the molybdenum at a concentration from 0.5 to 6 g·L −1 and the zirconium at a concentration from 0.5 to 6 g·L −1 , adding the plutonium, during an additional successive step, in an amount so as to obtain a concentration of the plutonium ranging from 1 to 50 g·L −1 .