Absorber tube and method for the reversible loading and unloading of a getter material
An absorber tube, especially for solar collectors in solar thermal power plants with at least one collector mirror, is provided. The absorber tube includes a metal tube for supplying and heating a heat transfer medium, a sheath tube surrounding the metal tube to form an annular space that can be evacuated, a wall extending through the sheath tube and the metal tube to seal the annular space, and a getter material binding free hydrogen in the annular space. The absorber tube has a temperature variation device that changes the temperature of the getter material and the wall.
1. An absorber tube for solar collectors in solar thermal power plants, comprising:
a collector mirror that reflects solar irradiation and directs the reflected solar irradiation onto the absorber tube;
a metal tube that conducts and heats a heat transfer medium;
a sheath tube surrounding the metal tube, the sheath tube forming an annular space that can be evacuated;
a wall running between the sheath tube and the metal tube to seal the annular space;
a getter material configured to bind free hydrogen that is present in the annular space;
a membrane in the wall that is permeable to the free hydrogen, and purges free hydrogen from the annular space; and
a temperature changing device that changes a temperature of the getter material, the wall, and the membrane.
2. The absorber tube according to claim 1 , wherein the wall comprises a transition element and an outer ring, the membrane being disposed in or on the transition element and/or the outer ring.
3. The absorber tube according to claim 1 , further comprising an expansion bellows that equilibrates expansion differences between the sheath tube and the metal tube.
4. The absorber tube according to claim 1 , wherein the membrane comprises a material selected from the group consisting of iron, palladium, and niobium.
5. The absorber tube according to claim 3 , wherein the expansion bellows and/or the wall comprise(s) a doped region that increases permeability for the free hydrogen.
6. The absorber tube according to claim 2 , wherein the getter material is in a container that is fastened to the outer ring and/or to the transition element.
7. The absorber tube according to claim 6 , wherein the container comprises a fabric sock.
8. The absorber tube according to claim 2 , wherein the outer ring has an opening that points towards the getter material and that is sealed by the membrane.
9. The absorber tube according to claim 2 , wherein the outer ring and/or the transition element has a section that at least partially encloses the getter material.
10. The absorber tube according to claim 9 , wherein the membrane is disposed in the section.
11. The absorber tube according to claim 9 , wherein the temperature changing device is adjacent to the section.
12. The absorber tube according to claim 3 , wherein the temperature changing device runs at least partially in folds of the expansion bellows.
13. The absorber tube according to claim 1 , wherein the temperature changing device comprises a heating device.
14. The absorber tube according to claim 13 , wherein the heating device comprises a heating filament.
15. A method for changing the temperature of a membrane of an absorber tube, the absorber tube comprising:
a collector mirror that reflects solar irradiation and directs the reflected solar irradiation onto the absorber tube;
a metal tube that conducts and heats a heat transfer medium;
a sheath tube surrounding the metal tube, the sheath tube forming an annular space that can be evacuated;
a wall running between the sheath tube and the metal tube to seal the annular space;
a getter material configured to bind free hydrogen that is present in the annular space;
a membrane in the wall that is permeable to the free hydrogen, and purges free hydrogen from the annular space; and
a temperature changing device that changes a temperature of the getter material, the wall, and the membrane,
the method comprising the steps of:
reflecting solar irradiation and directing the reflected solar irradiation onto the absorber tube with a collector mirror;
changing the temperature of a getter material by a temperature changing device; and
changing the temperature of the membrane by the getter material.
16. A method for the reversible loading and unloading of a getter material with free hydrogen in an absorber tube, comprising the following steps:
reflecting solar irradiation and directing the reflected solar irradiation onto the absorber tube with a collector mirror;
loading the getter material at a first temperature (T 1 );
changing the temperature of the getter material to a second temperature (T 2 );
unloading the getter material at the second temperature (T 2 ); and
changing the temperature of getter material to the first temperature (T 1 ).
17. A device for discharging free hydrogen from an annular space of an absorber tube, comprising:
a collector mirror that reflects solar irradiation and directs the reflected solar irradiation onto the absorber tube;
a metal tube that conducts and heats a heat transfer medium;
a sheath tube surrounding the metal tube, the sheath tube forming an annular space that can be evacuated;
a wall running between the sheath tube and the metal tube to seal the annular space;
a getter material configured to bind free hydrogen that is present in the annular space;
a membrane in the wall that is permeable to the free hydrogen, and purges free hydrogen from the annular space; and
a temperature changing device that changes a temperature of the getter material, the wall, and the membrane;
a temperature measuring unit that determines a temperature value of the sheath tube; and
a comparison unit that compares the temperature value of the sheath tube to a selectable critical temperature value.
18. A method for discharging free hydrogen from an annular space of an absorber tube, comprising the following steps:
reflecting solar irradiation and directing the reflected solar irradiation onto the absorber tube with a collector mirror;
determining a temperature value of a sheath tube of the absorber tube by a temperature measuring unit;
comparing the temperature value with a selectable critical temperature value by a comparison unit; and
changing the temperature of a getter material, a wall, and/or a membrane of the absorber tube with a temperature changing device so that hydrogen that is bound to the getter material is released and is discharged from the annular space.