Process for producing thermoplastic elastomer composition
Disclosed is a process for producing a thermoplastic elastomer composition having a matrix phase comprising a polyamide and an ethylene/vinyl alcohol copolymer and a disperse phase comprising a rubber composition, by which gelation by a reaction between a polyamide and an ethylene/vinyl alcohol copolymer can be inhibited and the dispersion of the rubber composition can be good. In the process, the polyamide resin and the rubber composition are melt-blended to the extent necessary for the rubber composition to form a disperse phase, and then the ethylene/vinyl alcohol copolymer is added and further melt-blended together.
1. A process for producing a thermoplastic elastomer composition having a matrix phase comprising a polyamide resin and an ethylene/vinyl alcohol copolymer and a disperse phase comprising a rubber composition, wherein, using a twin screw kneader having at least two supply ports, the polyamide resin and the rubber composition are supplied to an upstream supply port of the twin screw kneader, and the polyamide resin and the rubber composition are melt-blended to prepare a blend of the polyamide resin and the rubber composition having a sea-island structure, in which the polyamide resin constitutes a matrix phase and the rubber composition constitutes disperse phases, and, by supplying the ethylene/vinyl alcohol copolymer to a downstream supply port of the twin kneader, the ethylene/vinyl alcohol copolymer is added to the blend and melt-blended to prepare a thermoplastic elastomer composition having sea-island structure, in which the polyamide resin and the ethylene/vinyl alcohol copolymer constitute a matrix phase, and the rubber composition constitutes a disperse phase.
2. The process according to claim 1 , wherein the melt viscosity η d at 250° C. and 243 s −1 of the blend prepared by melt-blending the polyamide resin and the rubber composition is higher than a melt viscosity η c at 250° C. and 243 s −1 of the ethylene/vinyl alcohol copolymer to be added.
3. The process according to claim 2 , wherein the thermoplastic elastomer composition comprises 0.1 to 7.3% by weight of the ethylene/vinyl alcohol copolymer based on the total weight of the thermoplastic elastomer composition.
4. The process according to claim 2 , wherein the thermoplastic elastomer composition comprises 0.1 to 7.3% by weight of the ethylene/vinyl alcohol copolymer based on the total weight of the thermoplastic elastomer composition.
5. The process according to claim 1 , wherein the thermoplastic elastomer composition comprises 0.1 to 7.3% by weight of the ethylene/vinyl alcohol copolymer based on the total weight of the thermoplastic elastomer composition.
6. The process according to claim 1 , wherein the polyamide resin is at least one selected from the group consisting of nylon 11, nylon 12, nylon 6, nylon 66, a nylon 6/66 copolymer, nylon 612, nylon MXD6, a nylon 6/66/12 copolymer, nylon 46, nylon 9T, nylon 6T, and nylon 610.
7. The process according to claim 1 , wherein the ethylene/vinyl alcohol copolymer has an ethylene content of 32 to 48% by mol and a degree of saponification of not less than 90%.
8. The process according to claim 1 , wherein the rubber composition comprises at least one selected from the group consisting of a halogenated isoolefin/p-alkylstyrene copolymer, a maleic anhydride-modified ethylene/α-olefin copolymer, and a maleic anhydride-modified ethylene/ethyl acrylate copolymer.