IP Library Granted Patent US 9,080,020
Granted Patent B2
US 9,080,020 · App. 13/515,330 · Granted Jul 14, 2015

Water-dispersible silicone resins

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Quick Facts
Patent No.
US 9,080,020
App. No.
13/515,330
Granted
Jul 14, 2015
Kind
B2
Abstract

A process for preparing an aqueous dispersion of a silicone resin is disclosed by reacting a mixture containing an alkylalkoxysilane and a cationic alkoxysilane to form a self dispersing silicone resin and subsequently combining the silicone resin with water to form the dispersion. The resulting dispersions are useful for forming coatings on various substrates that are essentially free of co-surfactants or volatile organic solvents.

Claims (51)

1. A process for preparing an aqueous dispersion of a silicone resin comprising:

I) reacting a mixture containing:

a) 80 to 99.9% by weight of an alkylalkoxysilane of the formula

R 1 a Si(OR 2 ) 4-a

b) 0.1 to 20% by weight of a cationic alkoxysilane of the formula

R 3 b R 4 Si(OR 5 ) 3-b

where:

R 1 is an alkyl group containing 1 to 30 carbon atoms,

R 2 and R 5 are independently selected from the group consisting of hydrogen, alkyl groups containing 1 to 4 carbon atoms, CH 3 C(O)—, CH 3 CH 2 C(O)—, HOCH 2 CH 2 —, CH 3 OCH 2 CH 2 —, and C 2 H 5 OCH 2 CH 2 —,

R 3 is an alkyl group containing 1 to 4 carbons,

R 4 is a monovalent hydrocarbon having at least one quaternary ammonium group substituent,

a is 1 or 2,

b is 0, 1 or 2,

under an inert atmosphere at reflux temperature, and then subsequently to a temperature ranging from 120-140° C. to form a reaction product comprising a silicone resin; and

II) combining 5 to 95 wt % of the reaction product of step I) with 5 to 95 wt % of water to form an aqueous dispersion,

wherein the aqueous dispersion does not contain further surfactants and co-surfactants.

2. The process of claim 1 wherein aqueous hydrochloric acid is used to effect the reaction.

3. The process of claim 1 wherein the reaction product of step I) comprises an organopolysiloxane resin having an empirical formula of:

R

c

4

R

d

6

Si

(

OZ

)

e

(

O

)

4

-

c

-

d

-

e

2

where

R 4 is as defined above,

R 6 is R 3 or R 1 as defined above,

Z is a hydrogen atom, R 2 or R 5

c=0.0012 to 0.25,

d=0.4988 to 1.8

with the proviso that c+d may range from 0.5 to 1.8 and, e may range from 0.0 to 3.0.

Assignments (1)
CHANGE OF NAME Recorded Feb 27, 2018
From: DOW CORNING CORPORATION
To: DOW SILICONES CORPORATION
Reel/Frame 045460/0278 →