Polyamide composition with low thermal conductivity
A polyamide composition that can be used in different transformation methods and, in particular, for the production of an extrusion profile having a low thermal conductivity, is described. One such composition includes, in particular, glass beads. Also described is a composition, preferably a molding composition, e.g., in the form of granules or powder, that can be used to produce items by means of injection molding.
1. A thermoplastic composition comprising:
Compound A: a thermoplastic polyamide, wherein the composition comprises from 30 wt. % to 95 wt. % of polyamide relative to the total weight of the composition,
Compound B: a thermoplastic polymer having a lower thermal conductivity than polyamide A, wherein compound B is a styrene (co)polymer, wherein the composition comprises from 0.1 wt. % to 30 wt. % of compound B relative to the total weight of the composition,
Compound C: one or more compatibilizers between compound A and compound B, at least one of which comprises functional groups for compatibilization with compound A,
Compound D: hollow glass beads in an amount of, based on the total weight of the composition, from 10 wt. % to 20 wt. %, and
Compound E: reinforcing fillers or extenders in an amount of, based on the total weight of the composition, from 1 wt. % to 60 wt. %;
wherein the thermoplastic polyamide is a blend of polyamide 6.6 and polyamide 6 and the proportion by weight of polyamide 6 relative to the total weight of polyamide is between 1% and 30%.
2. The composition as defined in claim 1 , wherein the composition has a thermal conductivity below 0.272X 2 +0.088X+CtM, wherein:
X is a proportion by weight of reinforcing fillers or extenders E) present in the composition, and
CtM is a thermal conductivity of a matrix M comprising polyamide A, polymer B and compound C, in the absence of any fillers.
3. The composition as defined by claim 1 , wherein compound B is a styrene (co)polymer comprising a rubber on which acrylonitrile and a styrene compound are grafted.
4. The composition as defined by claim 3 , wherein the styrene compound is selected from styrene or a-methylstyrene.
5. The composition as defined by claim 3 , wherein the rubber of compound B is selected from the group consisting of: polybutadiene, butadiene-styrene rubber, butadiene-acrylate rubber, butadiene-acrylonitrile rubber, ethylene-propylene rubber, ethylene-propylene-diene rubber and mixtures of two or more of these rubbers.
6. The composition as defined by claim 1 , wherein compound B is an acrylonitrile-butadiene-styrene copolymer, optionally comprising functions for compatibilization with the polyamide.
7. The composition as defined by claim 1 , wherein compound C is selected from the group consisting of a styrene-maleimide copolymer comprising functional groups for compatibilization with the polyamide, and a styrene-ethylene-butadiene-styrene or styrene-butadiene-styrene block copolymer optionally fully or partially hydrogenated, having functional groups for compatibilization with the polyamide.
8. The composition as defined by claim 7 , wherein the functional groups for compatibilization with the polyamide are selected from the group consisting of maleic anhydride, carboxylic acid, and an ester group.
9. The composition as defined by claim 1 , wherein the hollow glass beads have an average diameter from 1 μm to 2 mm.
10. The composition as defined by claim 1 , wherein the hollow glass beads endow said composition with a density reduction of at least 0.4% for each 1 wt. % of glass beads added to said composition.
11. The composition as defined by claim 1 , wherein the glass beads provide a decrease of at least 5% of the total weight of the composition.
12. A method of manufacturing a composition as claimed in claim 1 wherein the method comprises mixing the compounds hot or cold.
13. An article obtained by forming the composition as defined in claim 1 .
14. The article as defined in claim 13 , wherein the article is a microcellular article.
15. The article as defined in claim 13 having an extruded profile.
16. A window or door having a frame comprising the article as defined in claim 15 having an extruded profile.
17. A thermoplastic composition comprising:
Compound A: a thermoplastic polyamide, wherein the composition comprises 40 wt. % to 80 wt. % of polyamide relative to the total weight of the composition;
Compound B: a thermoplastic polymer having a lower thermal conductivity than polyamide A, wherein compound B is a styrene (co)polymer and wherein the composition comprises from 1 wt. % to 20 wt. % relative to the total weight of the composition;
Compound C: one or more compatibilizers between compound A and compound B, at least one of which comprises functional groups for compatibilization with compound A, wherein the composition comprises 0.5 wt. % to 5 wt. % of compatibilizer relative to the total weight of the composition
Compound D: hollow glass beads in an amount of, based on the total weight of the composition, from 10 wt. % to 20 wt. %, and
Compound E: reinforcing fillers or extenders in an amount of, based on the total weight of the composition, from 15 wt. % to 50 wt. %;
wherein the thermoplastic polyamide is a blend of polyamide 6.6 and polyamide 6 and the proportion by weight of polyamide 6 relative to the total weight of polyamide is between 1% and 30%.
18. The composition according to claim 17 , wherein compound C is a styrene-maleimide copolymer comprising functional groups for compatibilization with the polyamide.