Resistive RAM devices and methods
View Patent ↗The present disclosure includes a high density resistive random access memory (RRAM) device, as well as methods of fabricating a high density RRAM device. One method of forming an RRAM device includes forming a resistive element having a metal-metal oxide interface. Forming the resistive element includes forming an insulative material over the first electrode, and forming a via in the insulative material. The via is conformally filled with a metal material, and the metal material is planarized to within the via. A portion of the metal material within the via is selectively treated to create a metal-metal oxide interface within the via. A second electrode is formed over the resistive element.
1. A resistive random access memory (RRAM) device formed by the method comprising:
forming a first oxide material over a substrate;
forming a silicon nitride material over the first oxide material;
forming a second oxide material over a portion of the silicon nitride material;
forming a first electrode over a different portion of the silicon nitride material;
forming a resistive element over the first electrode, where forming the resistive element includes:
forming an insulative material over the second oxide material and the first electrode;
forming a via in the insulative material over the first electrode;
filling the via with a metal material; and
selectively treating a portion of the metal material within the via to create a metal-metal oxide interface within the via; and
forming a second electrode over the resistive element and the insulative material.
2. A resistive random access memory (RRAM) device, comprising:
a first electrode;
a second electrode separated from the first electrode by a semiconductor insulating material; and
a resistive element contained within a via formed in the semiconductor insulating material, the via extending between the first and the second electrode, the resistive element including a first portion and a second portion, the first portion being a material including a metal and the second portion being an oxide of the material including the metal formed by selectively oxidizing the material including the metal within the via to form a metal-metal oxide interface at a location that enables the resistive element to be switched between more than one resistance state that are different from one another by at least two orders of magnitude.
3. The RRAM device of claim 2 , wherein the first portion is a noble metal.
4. The RRAM device of claim 2 , wherein the first portion is palladium.
5. The RRAM device of claim 2 , wherein the first portion is platinum.
6. The RRAM device of claim 2 , wherein the first portion is ruthenium.
7. The RRAM device of claim 2 , wherein the first portion is Cu and the second portion is CuOx.
8. The RRAM device of claim 2 , wherein the first portion is TiN and the second portion is TiON.
9. The RRAM device of claim 2 , wherein the first and second portions of the resistive element are configured to provide a resistance ratio on the order of about 1000 using 3V programming pulses drawing approximately 1 mA and −2V erase pulses drawing less than 1.5 mA.
10. The RRAM device of claim 2 , wherein the first and second portions of the resistive element are configured to provide a resistance ratio on the order of about 100 using 3V programming pulses drawing approximately 0.01 mA and −2V erase pulses drawing less than 0.03 mA.
11. The RRAM device of claim 2 , wherein the first and second portions of the resistive element are configured to provide at least about 1000 ohms of resistance.
12. The RRAM device of claim 2 , wherein the second portion is less than about forty percent (40%) of the volume of the via.
13. The RRAM device of claim 2 , wherein the second portion occupies less than about twenty-five percent (25%) of the distance between the first and second electrodes.
14. The RRAM device of claim 2 , wherein the second portion is in the range of from about 10 Angstroms to about 100 Angstroms along the dimension of the via extending between the first and second electrodes.
15. The RRAM device of claim 14 , wherein the second portion is in the range of from about 20 Angstroms to about 80 Angstroms along the dimension of the via extending between the first and second electrodes.
16. The RRAM device of claim 2 , wherein the first electrode includes a tungsten deposited over a buried digit line, the first electrode arranged such the tungsten is in contact with the first portion of the resistive element.
17. The RRAM device of claim 2 , wherein the second electrode includes a volume of tungsten deposited over a volume of TiN, the second electrode arranged such the TiN is in contact with the second portion of the resistive element.
18. The RRAM device of claim 2 , wherein the semiconductor insulating material is SiN.
19. The RRAM device of claim 2 , wherein the semiconductor insulating material is an oxide.
20. A resistive random access memory (RRAM) device, comprising:
a first electrode;
a second electrode separated from the first electrode by a semiconductor insulating material having a via therein, the via extending between the first and the second electrode; and
a resistive element formed at least within the via, and including a first portion and a second portion, the first portion being a material including a metal material the second portion being an oxide of the material including the metal formed by selectively oxidizing the material including the metal within the via to form a metal-metal oxide interface at a location that enables the resistive element to be switched between more than one resistance state that are different from one another by at least two orders of magnitude.
21. The RRAM device of claim 20 , wherein the first and second portions of the resistive element are configured such that they do not occupy the entire volume of the via, where at least one of the first and second electrodes extends into the via in contact with the resistive element.
22. The RRAM device of claim 21 , wherein the at least one of the first and second electrodes extends into the via in the range of from about 10 Angstroms to about 50 Angstroms.
23. The RRAM device of claim 20 , wherein the first and second portions of the resistive element are configured such that they occupy at least the entire volume of the via, where at least one of the first and second portions extends outside the via in contact with one of the first or second electrodes.
24. The RRAM device of claim 23 , wherein the at least one of the first and second portions extends outside the via by a distance in the range of from about 10 Angstroms to about 50 Angstroms.
25. The RRAM device of claim 20 , wherein the resistive element is arranged to have the second portion formed over the first portion within the via.
26. The RRAM device of claim 20 , wherein the resistive element is arranged to have the first portion formed over the second portion within the via.