Noise-reducing extrusion coating compositions
Methods for extrusion coating a substrate are provided. The methods comprise applying an extrusion coating composition to a surface of a substrate by extrusion coating. In these methods, the extrusion coating composition includes a polyolefin and an inorganic particulate material having an average particle size of no greater than 2 μm and a particle loading of at least 20 weight percent, based on the total weight of polyolefin and the inorganic particulate material.
1. A method for extrusion coating a substrate, the method comprising applying an extrusion coating composition to a surface of the substrate by extrusion coating, whereby the extrusion coating composition contacts a chill roll surface, the extrusion coating composition consisting essentially of:
(a) one or more ethylene-based polymers selected from the group consisting of polyethylene homopolymers and polyethylene copolymers prepared from only two different monomers, the ethylene-based polymers having a density no greater than 0.940 g/cc; and
(b) an inorganic particulate material having an average particle size of no greater than 1.5 μm and a particle loading of at least 25 weight percent, based on the total weight of the polyolefin and inorganic particulate material in the coating composition,
wherein the extrusion coating composition is characterized in that it reduces the extrusion coating noise level at the chill roll release point by at least 3 dB relative to an identical extrusion coating process conducted with the same extrusion coating composition absent the inorganic particulate material, wherein the noise level at the chill release point is measured using a chrome-plated gloss chill roll with a surface roughness of 0.5 μm at an extrudate temperature of 320° C. and an air gap of 250 mm for an extrusion coating of 25 g/m 2 applied at a line speed of 300 mpm or an extrusion coating of 12 g/m 2 applied at a line speed of 500 mpm.
2. The method of claim 1 , wherein the extrusion coating composition is characterized in that it reduces the extrusion coating noise level at the chill roll release point by at least 5 dB relative to an identical extrusion coating process conducted with the same extrusion coating composition absent the inorganic particulate material, wherein the noise level at the chill roll release point is measured using a chrome-plated glossy chill roll with a surface roughness of 0.5 μm, at an extrudate temperature of 320° C. and an air gap of 250 mm for an extrusion coating of 25 g/m 2 applied at a line speed of 300 mpm or an extrusion coating of 12 g/m 2 applied at a line speed of 500 mpm.
3. The method of claim 2 , wherein the extrusion coating composition is characterized in that it reduces the extrusion coating noise level at the chill roll release point by at least 10 dB.
4. The method of claim 1 , wherein the inorganic particulate material has a particle loading of at least 30 weight percent, based on the total weight of the polyolefin and the inorganic particulate material in the coating composition.
5. The method of claim 1 , wherein the inorganic particulate material is calcium carbonate.
6. The method of claim 1 , further comprising extruding one or more additional extrusion coating layers between the substrate and the extrusion coating composition to provide a multilayered, extrusion coated substrate, in which the extrusion coating composition is in contact with the chill roll.
7. The method of claim 1 , wherein at least one of the ethylene-based polymers has a density of less than 0.916 g/cc.
8. The method of claim 1 , wherein at least one of the ethylene-based polymers has a density of from about 0.860 g/cc to about 0.905 g/cc.
9. The method of claim 1 , wherein at least one of the ethylene-based polymers has a density of from 0.860 g/cc to less than 0.890 g/cc.
10. The method of claim 1 , wherein the ethylene-based polymers are selected from the group consisting of low density polyethylene (LDPE), high density polyethylene (HDPE), enhanced polyethylene (EPE), ultra low linear density polyethylene (VLDPE), ethylene acrylic acid (EAA) copolymers, ionomers, ethylene methyl acrylic acid (EMAA) copolymers, ethylene ethyl acrylate (EEA) copolymers, ethylene methyl acrylate (EMA) copolymers, ethylene butyl acrylate (EBA) copolymers, ethylene vinyl acetate (EVA) copolymers, and combinations thereof.
11. The method of claim 1 , wherein the ethylene-based polymers are selected from the group consisting of LDPE, EPE and combinations thereof.