Herbicide compatibility improvement
A process for preparing an aqueous concentrate glyphosate salt composition comprises (i) neutralizing glyphosate acid with potassium hydroxide and a minor amount of a low molecular weight organic amine in presence of water to produce a glyphosate salt solution having a pH of about 4.8 to about 5.0, where the neutralizing operation comprises a first neutralization step in which a slurry or glyphosate salt solution having a pH of about 4.4 to about 4.7 is produced and a second neutralization step in which the pH is adjusted to about 4.8 to about 5.0; and (ii) after the first neutralization step and before, during or after the second neutralization step, adding further water if necessary and optionally at least one surfactant to produce a final composition having a total glyphosate a.e. concentration not less than about 360 g/l.
1. A process for preparing a tank-mix herbicidal composition, the process comprising admixing in a suitable vessel with agitation (i) water in an amount suitable for application to a plant and/or soil surface by spraying; (ii) a herbicidally effective amount of an aqueous concentrate glyphosate salt composition; and (iii) an aqueous solution of one to a plurality of salts of a phenoxy-type herbicide, selected from the group consisting of phenoxyacetic acids, phenoxypropanoic acids, phenoxybutanoic acids, benzoic acids, picolinic acids, pyridinyloxyacetic acids, and enantiomers and racemates thereof, in an amount providing a glyphosate to phenoxy-type herbicide a.e. ratio of about 1:5 to about 20:1; wherein the aqueous concentrate glyphosate salt composition comprises glyphosate, at a total a.e. concentration not less than about 360 g/l, in anionic form accompanied by low molecular weight non-amphiphilic cations in a total molar amount greater than 110% to a maximum of about 120% of the molar amount of said glyphosate, said cations comprising potassium cations and less than 50% of low molecular weight organic ammonium cations by molar amount of all low molecular weight non-amphiphilic cations present.
2. The process of claim 1 , wherein the phenoxy-type herbicide is selected from the group consisting of 2,4-D, dicamba and picloram.
3. The process of claim 1 , wherein the phenoxy-type herbicide salt is the dimethylammonium salt of 2,4-D.
4. A tank-mix herbicidal composition prepared by the process of claim 1 .
5. The process of claim 1 , wherein the aqueous concentrate glyphosate composition has a total glyphosate a.e. concentration of about 360 g/l to about 650 g/l.
6. The process of claim 1 , wherein the aqueous concentrate glyphosate composition has a total glyphosate a.e. concentration of about 400 g/1 to about 600 g/l.
7. The process of claim 1 , wherein the aqueous concentrate glyphosate composition has a mole ratio of potassium to low molecular weight organic ammonium cations of about 55:45 to about 99:1.
8. The process of claim 1 , wherein the aqueous concentrate glyphosate composition has a mole ratio of potassium to low molecular weight organic ammonium cations of about 70:30 to about 90:10.
9. The process of claim 1 , wherein the aqueous concentrate glyphosate composition has a mole ratio of potassium to low molecular weight organic ammonium cations of about 96:4 to about 98:2.
10. The process of claim 1 , wherein said low molecular weight organic ammonium cations comprise isopropylammonium cations.
11. The process of claim 1 , wherein the aqueous concentrate glyphosate composition further comprises at least one surfactant.
12. The process of claim 11 , wherein the weight ratio of glyphosate a.e. to total surfactant is not greater than about 10:1.
13. The process of claim 1 , wherein the phenoxy-type herbicide is in the form of a potassium, sodium, ammonium or organic ammonium salt.
14. The process of claim 1 , wherein the phenoxy-type herbicide is in the form of an organic ammonium salt selected from the group consisting of methylammonium, dimethylammonium, n-propylammonium, isopropylammonium, mono-, di- and triethanolammonium salts.
15. The process of claim 1 , wherein the phenoxy-type herbicide is selected from the group consisting of 4-CPA, 2,4-D, 3,4-DA, MCPA, 2,4,5-T, cloprop, 4-CPP, dichlorprop, 3,4-DP, fenoprop, mecoprop, 4-CPB, 2,4-DB, 3,4-DB, MCPB, 2,4,5-TB, chloramben, dicamba, 2,3,6-TBA, tricamba, aminopyralid, clopyralid, picloram, triclopyr, and enantiomers and racemates thereof.