Production and separation of glycerol-related products using various feed stocks
View Patent ↗Disclosed are processes for producing glycerol-related products. One process for producing glycerol-related products comprises introducing glycerol and an alkylation reagent to a substantially oxygen free environment. Another process for producing glycerol-related products comprises introducing a glycerol and tetramethylammonium hydroxide to a substantially oxygen free environment.
1. A process for producing glycerol-related products comprising:
introducing a feedstock and an alkylation reagent to a substantially oxygen free environment;
hydrolyzing at a temperature at or above 200° C. one or more lipid glycerides in the feedstock;
methylating one or more fatty acids in the feedstock with methyl groups from the alkylation reagent, wherein the hydrolyzing and methylating occur contemporaneously;
separating a lower phase from an upper phase of a resulting condensate, the lower phase comprised of biodiesel;
acidifying the upper phase;
separating the acidified upper phase into biodiesel dissolved in methanol and methoxylated glycerols dissolved in methanol;
removing the methanol from both the biodiesel and the methoxylated glycerols; and
separating the biodiesel from the methoxylated glycerols.
2. The process of claim 1 , wherein the alkylation reagent is tetramethylammonium hydroxide.
3. The process of claim 2 , wherein the methlylated glycerol-related products are one or more of 1,2,3-trimethoxy-propane (TMP), 1,3-dimethoxy-2-propanol (DMP), 1,2-dimethoxy-3-propanol (2DMP) and 3-methoxy-1,2-dihydroxypropane (MDP).
4. The process of claim 1 , wherein the temperature is between about 250° C. and about 500° C. and the pressure is atmospheric.
5. The process of claim 1 , wherein the feedstock is an algal biomass.
6. The process of claim 1 , wherein the feedstock is one or more of glyceride based oils from plants, glyceride based oils from animal fat and used cooking oil.
7. The process of claim 1 , wherein at least one by-product of the processed alkylation reagent is converted and recycled as the alkylation reagent.
8. The process of claim 2 , wherein a trimethylamine by-product of the processed tetramethylammonium hydroxide is converted and recycled as the alkylation reagent.
9. The process of claim 1 , wherein the alkylation reagent is selected from one or more of tetramethylammonium hydroxide, tetrabutylammonium hydroxide, trimethylphenylammonium hydroxide, tetraethyammonium hydroxide, and (m-trifluoro-methylphenyl)trimethylammonium hydroxide.
10. The process of claim 1 , wherein the substantially oxygen free environment comprises less than or equal to one percent oxygen.
11. The process of claim 1 , wherein the methanol is removed with distillation.
12. A process for producing glycerol-related products comprising:
hydrolyzing and methylating glycerol with an alkylation reagent in a substantially oxygen free environment without a catalyst, wherein the glycerol is methoxylated glycerols produced from one or more of an algal biomass and glyceride based oils.
13. The process of claim 12 , wherein the glyceride based oils are glyceride based oils from plants, glyceride based oils from animal fat and used cooking oil.
14. The process of claim 12 , wherein the alkylation reagent is tetramethylammonium hydroxide.
15. The process of claim 14 , wherein the glycerol-related products are one or more of 1,2,3-trimethoxy-propane (TMP), 1,3-dimethoxy-2-propanol (DMP), and 1,2-dihydroxy-3-methoxy propane (MDP).
16. The process of claim 14 , wherein a trimethylamine by-product of the processed tetramethylammonium hydroxide is converted and recycled as the alkylation reagent.
17. The process of claim 12 , wherein the temperature is between about 250° C. and about 500° C. and the pressure is atmospheric.
18. The process of claim 12 , wherein at least one by-product of the processed alkylation reagent is converted and recycled as the alkylation reagent.
19. The process of claim 12 , wherein the alkylation reagent is selected from one or more of tetramethylammonium hydroxide, tetrabutylammonium hydroxide, trimethylphenylammonium hydroxide, tetraethyammonium hydroxide, and (m-trifluoro-methylphenyl)trimethylammonium hydroxide.
20. Glycerol-related products produced from the process of claim 12 .
21. A process for producing glycerol-related products comprising:
hydrolyzing and methylating glycerol with an alkylation reagent in a substantially oxygen free environment without a catalyst, wherein the glycerol is crude glycerin produced from a biodiesel production facility.