Nanoparticles with multiple attached polymer assemblies and use thereof in polymer composites
Methods of synthesizing a binary polymer functionalized nanoparticle are generally provided. In one embodiment, a first anchoring compound is attached to a nanoparticle, and a first plurality of first monomers are polymerized on the first anchoring compound to form a first polymeric chain covalently bonded to the nanoparticle via the first anchoring compound. In another embodiment, a first polymeric chain can be attached to the nanoparticle, where the first polymeric chain has been polymerized prior to attachment to the nanoparticle. Thereafter, a second anchoring compound is attached to the nanoparticle, and a second plurality of second monomers are polymerized on the second anchoring compound to form a second polymeric chain covalently bonded to the nanoparticle via the second anchoring compound. Nanoparticles are also generally provided having multiple polymeric assemblies.
1. A method of synthesizing a binary polymer functionalized nanoparticle, the method comprising:
attaching a first anchoring compound to a nanoparticle;
polymerizing a first plurality of first monomers on the first anchoring compound to form a first polymeric chain covalently bonded to the nanoparticle via the first anchoring compound;
thereafter, attaching a second anchoring compound to the nanoparticle;
polymerizing a second plurality of second monomers on the second anchoring compound to form a second polymeric chain covalently bonded to the nanoparticle via the second anchoring compound.
2. The method as in claim 1 , further comprising:
deactivating the first polymeric chain prior to attaching the second anchoring compound to the nanoparticle.
3. The method as in claim 1 , further comprising:
deactivating the second polymeric chain.
4. The method as in claim 1 , wherein the first polymeric chain is different than the second polymeric chain.
5. The method as in claim 4 , wherein the first polymeric chain has a molecular weight up to about 50,000, and wherein the second polymeric chain has a molecular weight of about 50,000 or more.
6. The method as in claim 4 , wherein the polymeric first polymeric chain has a different polydispersity index than the second polymeric chain.
7. The method as in claim 1 , wherein the first plurality of first monomers comprises a single type of monomer.
8. The method as in claim 1 , wherein the first plurality of first monomers comprises a mixture of different types of monomers.
9. The method as in claim 1 , wherein the second plurality of second monomers comprises a single type of monomer.
10. The method as in claim 1 , wherein the second plurality of second monomers comprises a mixture of different types of monomers.
11. The method as in claim 1 , further comprising:
after polymerizing a second plurality of second monomers, attaching a third anchoring compound to the nanoparticle; and
polymerizing a third plurality of third monomers on the third anchoring compound to form a third polymeric chain covalently bonded to the nanoparticle via the third anchoring compound.
12. The method as in claim 11 , further comprising:
deactivating the third polymeric chain.
13. The method as in claim 11 , further comprising:
after polymerizing the third plurality of third monomers, attaching a fourth anchoring compound to the nanoparticle; and
polymerizing a fourth plurality of fourth monomers on the fourth anchoring compound to form a fourth polymeric chain covalently bonded to the nanoparticle via the fourth anchoring compound.