Method for producing cellulose-fiber flat structure
The present invention relates to a method of producing a cellulose-fiber flat structure, the method including obtaining a cellulose-fiber flat structure by filtering a fine cellulose-fiber dispersion containing fine cellulose fibers having an average fiber diameter of 4 to 100 nm, using a filter material having a water permeability of not more than 100 ml/m 2 ·s and an initial tensile modulus of 20 MPa or greater. The present invention is able to produce a cellulose-fiber flat structure by efficiently recovering fine cellulose fibers from a dispersion containing fine cellulose fibers having an average fiber diameter at the nano level. The method of producing a cellulose-fiber flat structure can also be applied to a continuous process.
1. A method of producing a cellulose-fiber flat structure, the method comprising obtaining a cellulose-fiber flat structure by filtering a very fine cellulose-fiber dispersion containing very fine cellulose fibers having an average fiber diameter of 4 to 100 nm, using a filter material having a water permeability of not more than 100 ml/m 2 ·s and an initial tensile modulus of 20 MPa or greater, wherein the filter material is obtained by subjecting a fabric formed using a fiber having an average thread thickness of 1 to 5 d/f to a heat and pressure treatment.
2. The method of producing a cellulose-fiber flat structure according to claim 1 , wherein the filter material is formed from at least one type of fiber selected from the group consisting of synthetic resin fibers, regenerated fibers and natural fibers.
3. The method of producing a cellulose-fiber flat structure according to claim 2 , wherein the fiber used to form the filter material is a splittable composite fiber.
4. The method of producing a cellulose-fiber flat structure according to claim 1 , wherein a thickness of the fabric is 100 μm or greater.
5. The method of producing a cellulose-fiber flat structure according to claim 1 , wherein the fabric is a woven fabric, a knitted fabric or a nonwoven fabric.
6. The method of producing a cellulose-fiber flat structure according to claim 1 further comprising, prior to obtaining the cellulose-fiber flat structure by performing filtering using the filter material, performing a microfibrillation treatment on a raw material dispersion comprising a dispersed cellulose, thereby obtaining the very fine cellulose-fiber dispersion.
7. A method of producing a cellulose-fiber composite, the method comprising, in addition to obtaining a cellulose-fiber flat structure by performing filtering using the filter material defined in the method of producing a cellulose-fiber flat structure according to claim 1 , complexing the cellulose-fiber flat structure and a matrix material.
8. The method of producing a cellulose-fiber flat structure according to claim 1 , further comprising, prior to obtaining the cellulose-fiber flat structure by performing filtering using the filter material, performing a microfibrillation treatment on a raw material dispersion comprising a dispersed cellulose, thereby obtaining the very fine cellulose-fiber dispersion,
wherein the filter material is obtained by subjecting a fabric formed using a fiber having an average thread thickness of 1 to 5 d/f to a heat and pressure treatment,
a thickness of the fabric is 100 μm or greater, and
the fiber is a splittable composite fiber.
9. A method of producing a cellulose-fiber flat structure, the method comprising obtaining a cellulose-fiber flat structure by filtering a very fine cellulose-fiber dispersion containing very fine cellulose fibers having an average fiber diameter of 4 to 100 nm using a filter material having a water permeability of not more than 100 ml/m 2 ·s and an initial tensile modulus of 20 MPa eater, wherein the filter material is formed from a paper base material.
10. The method of producing a cellulose-fiber flat structure according to claim 9 , wherein the paper base material has a thickness of 90 μm or greater.
11. The method of producing a cellulose-fiber flat structure according to claim 9 , further comprising, prior to obtaining the cellulose-fiber flat structure by performing filtering using the filter material, performing a microfibrillation treatment on a raw material dispersion comprising a dispersed cellulose, thereby obtaining the very fine cellulose-fiber dispersion,
wherein the filter material is formed from a paper base material, and
the paper base material has a thickness of 90 μm or greater.
12. The method of producing a cellulose-fiber flat structure according to claim 9 , wherein the method comprises, prior to obtaining the cellulose-fiber flat structure by performing filtering using the filter material, performing a microfibrillation treatment on a raw material dispersion comprising a dispersed cellulose, thereby obtaining the very fine cellulose-fiber dispersion.
13. A method of producing a cellulose-fiber composite, the method comprising, in addition to obtaining a cellulose-fiber flat structure by performing filtering using the filter material defined in the method of producing a cellulose-fiber flat structure according to claim 9 , complexing the cellulose-fiber flat structure and a matrix material.
14. A filter material having a water permeability of not more than 100 ml/m 2 ·s and an initial tensile modulus of 20 MPa or greater, which is used for filtering a very fine cellulose-fiber dispersion comprising very fine cellulose fibers having an average fiber diameter of 4 to 100 nm, wherein said filter material is obtained by subjecting a fabric formed using a fiber having an average thread thickness of 1 to 5 d/f to a heat and pressure treatment.
15. A method of filtering a cellulose-fiber dispersion, the method comprising obtaining a cellulose-fiber flat structure by filtering a very fine cellulose-fiber dispersion comprising very fine cellulose fibers having an average fiber diameter of 4 to 100 nm, using a filter material having a water permeability of not more than 100 ml/m 2 ·s and an initial tensile modulus of 20 MPa or greater, wherein the filter material is obtained by subjecting a fabric formed using a fiber having an average thread thickness of 1 to 5 d/f to a heat and pressure treatment, wherein the filtering is selected from the group consisting of reduced-pressure filtering methods, normal pressure filtering methods and pressurized filtering methods.
16. A filter material having a water permeability of not more than 100 ml/m 2 ·s and an initial tensile modulus of 20 MPa or greater, which is used for filtering a very fine cellulose-fiber dispersion comprising very fine cellulose fibers having an average fiber diameter of 4 to 100 nm, wherein the filter material is formed from a paper base material.
17. A method of filtering a cellulose-fiber dispersion, the method comprising obtaining a cellulose-fiber flat structure by filtering a very fine cellulose-fiber dispersion comprising very fine cellulose fibers having an average fiber diameter of 4 to 100 nm, using a filter material having a water permeability of not more than 100 ml/m 2 ·s and an initial tensile modulus of 20 MPa or greater, wherein the filter material is formed from a paper base material having a thickness of 90 μm or greater.