Battery control system
A battery control system includes a lithium ion secondary battery and a control device and further includes a voltage storage unit, a resistance storage unit, a current storage unit, a difference obtaining unit for obtaining a difference resistance ΔR(T ja ) between a normal internal resistance R j (T ja ) at a predetermined battery temperature T ja in a normal temperature range AT j and an initial internal resistance R 0 (T ja ) at the predetermined battery temperature, and a maximum voltage calculation unit for giving a maximum inter-terminal voltage V m (T), when at least a battery temperature T is within a low-temperature range AT l , as a value obtained by adding a product of the difference resistance ΔR(T ja ) and the allowable charging current I m (T) to the initial maximum inter-terminal voltage V m0 (T).
1. A battery control system including a lithium-ion secondary battery having a positive electrode plate and a negative electrode plate, and a control device for setting an allowable maximum inter-terminal voltage and an allowable charging current at the time of charging of the secondary battery and controlling the charging from a power supply to the secondary battery,
wherein when a normal temperature range AT j of a battery temperature T is set to 20 to 45° C. and a low-temperature range AT l of a battery temperature T is set to −30 to 0° C.,
the negative electrode plate has a characteristic such that
when characteristics of the negative electrode plate are compared in cases where the battery temperature T is within the normal temperature range AT j and within the low-temperature range AT l ,
reaction resistance R r (T) caused in the negative electrode plate is higher in the low-temperature range AT l , and
a ratio of the reaction resistance R r (T) of the negative electrode plate in internal resistance R(T) of the secondary battery is larger in the low-temperature range AT l ,
wherein the battery control system includes:
a voltage storage unit for storing an initial maximum inter-terminal voltage V m0 (T) allowed at an early use of the secondary battery in the maximum inter-terminal voltage V m (T) for each battery temperature T;
a resistance storage unit for storing initial internal resistance R 0 (T) caused at the early use of the secondary battery at least at a predetermined battery temperature T ja within the normal temperature range AT j ;
an electric current storage unit for storing the allowable charging current I m (T) for each battery temperature T;
a difference obtaining unit for obtaining difference resistance ΔR(T ja ) as a difference between normal internal resistance R j (T ja ) at the predetermined battery temperature T ja within the normal temperature range At j in the internal resistance of the secondary battery at timing when the battery temperature T of the secondary battery becomes the predetermined battery temperature T ja and the corresponding initial internal resistance R 0 (T ja ) at the predetermined battery temperature T ja stored in the resistance storage unit; and
a maximum voltage calculating unit for, at least when the battery temperature T is within the low-temperature range AT l , setting the maximum inter-terminal voltage V m (T) corresponding to the battery temperature T to a value obtained by adding a product of the difference resistance ΔR(T ja ) and the allowable charging current I m (T) stored in the electric current storage unit to the initial maximum inter-terminal voltage V m0 (T) stored in the voltage storage unit.
2. The battery control system according to claim 1 , wherein
the negative electrode plate has a characteristic such that,
as to the reaction resistance R r (T), the low-temperature reaction resistance R rl (T l ) at the temperature T l within the low-temperature range AT l obtains a value that is 7 or more times as large as the normal reaction resistance R rj (T j ) at the temperature T j within the normal temperature range AT j ,
a ratio R rj (T j )/R j (T j ) of the normal reaction resistance R rj (T j ) in the normal internal resistance R j (T j ) that is the internal resistance R(T) at the temperature T j is 10% or less, and
a ratio R rl (T l )/R l (T l ) of the low-temperature reaction resistance R rl (T l ) in the low-temperature internal resistance R l (T l ) that is the internal resistance R(T) at the temperature T l is 20% or more.
3. The battery control system according to claim 2 , wherein
when the battery temperature T is higher than the low-temperature range AT l , the maximum voltage calculating unit sets the initial maximum inter-terminal voltage V m0 (T) to be a value of the maximum inter-terminal voltage V m (T).
4. The battery control system according to claim 3 , comprising a normal internal resistance storage unit for storing the normal internal resistance R j (T ja ) of the secondary battery at the input time, which is externally input.
5. The battery control system according to claim 2 , comprising a resistance obtaining unit for obtaining the normal internal resistance R j (T ja ) of the secondary battery when the battery temperature T of the secondary battery is the predetermined battery temperature T ja .
6. The battery control system according to claim 5 , comprising:
a charging state detecting unit for detecting a charging state of the secondary battery;
an open inter-terminal voltage storage unit for storing an open inter-terminal voltage at each charging state of the secondary battery in advance; and
an open inter-terminal voltage obtaining unit for obtaining the open inter-terminal voltage based on the charging states detected by the charging state detecting unit,
wherein the resistance obtaining unit is a means for, when the same level of charging currents are detected until a second time after a predetermined time passes from a first time just after an operation of the secondary battery is changed from discharging to charging in a charging period of the secondary battery, obtaining the normal internal resistance R j (T ja ) by using a difference between the open inter-terminal voltage corresponding to the charging state of the secondary battery at the first time and the inter-terminal voltage of the secondary battery at the second time, and a current value of the charging current, and
the predetermined time is 1.0 second or less.
7. The battery control system according to claim 6 , wherein the predetermined time in the resistance obtaining unit is 0.1 seconds or less.
8. The battery control system according to claim 2 , comprising a normal internal resistance storage unit for storing the normal internal resistance R j (T ja ) of the secondary battery at the input time, which is externally input.
9. The battery control system according to claim 1 , wherein
when the battery temperature T is higher than the low-temperature range AT l , the maximum voltage calculating unit sets the initial maximum inter-terminal voltage V m0 (T) to be a value of the maximum inter-terminal voltage V m (T).
10. The battery control system according to claim 9 , comprising a resistance obtaining unit for obtaining the normal internal resistance R j (T ja ) of the secondary battery when the battery temperature T of the secondary battery is the predetermined battery temperature T ja .
11. The battery control system according to claim 10 , comprising:
a charging state detecting unit for detecting a charging state of the secondary battery;
an open inter-terminal voltage storage unit for storing an open inter-terminal voltage at each charging state of the secondary battery in advance; and
an open inter-terminal voltage obtaining unit for obtaining the open inter-terminal voltage based on the charging states detected by the charging state detecting unit,
wherein the resistance obtaining unit is a means for, when the same level of charging currents are detected until a second time after a predetermined time passes from a first time just after an operation of the secondary battery is changed from discharging to charging in a charging period of the secondary battery, obtaining the normal internal resistance R j (T ja ) by using a difference between the open inter-terminal voltage corresponding to the charging state of the secondary battery at the first time and the inter-terminal voltage of the secondary battery at the second time, and a current value of the charging current, and
the predetermined time is 1.0 second or less.
12. The battery control system according to claim 11 , wherein the predetermined time in the resistance obtaining unit is 0.1 seconds or less.
13. The battery control system according to claim 9 , comprising a normal internal resistance storage unit for storing the normal internal resistance R j (T ja ) of the secondary battery at the input time, which is externally input.
14. The battery control system according to claim 1 , comprising a resistance obtaining unit for obtaining the normal internal resistance R j (T ja ) of the secondary battery when the battery temperature T of the secondary battery is the predetermined battery temperature T ja .
15. The battery control system according to claim 14 , comprising:
a charging state detecting unit for detecting a charging state of the secondary battery;
an open inter-terminal voltage storage unit for storing an open inter-terminal voltage at each charging state of the secondary battery in advance; and
an open inter-terminal voltage obtaining unit for obtaining the open inter-terminal voltage based on the charging states detected by the charging state detecting unit,
wherein the resistance obtaining unit is a means for, when the same level of charging currents are detected until a second time after a predetermined time passes from a first time just after an operation of the secondary battery is changed from discharging to charging in a charging period of the secondary battery, obtaining the normal internal resistance R j (T ja ) by using a difference between the open inter-terminal voltage corresponding to the charging state of the secondary battery at the first time and the inter-terminal voltage of the secondary battery at the second time, and a current value of the charging current, and
the predetermined time is 1.0 second or less.
16. The battery control system according to claim 15 , wherein the predetermined time in the resistance obtaining unit is 0.1 seconds or less.
17. The battery control system according to claim 14 , comprising a resistance obtaining unit for obtaining the normal internal resistance R j (T ja ) of the secondary battery when the battery temperature T of the secondary battery is the predetermined battery temperature T ja .
18. The battery control system according to claim 17 , comprising:
a charging state detecting unit for detecting a charging state of the secondary battery;
an open inter-terminal voltage storage unit for storing an open inter-terminal voltage at each charging state of the secondary battery in advance; and
an open inter-terminal voltage obtaining unit for obtaining the open inter-terminal voltage based on the charging states detected by the charging state detecting unit,
wherein the resistance obtaining unit is a means for, when the same level of charging currents are detected until a second time after a predetermined time passes from a first time just after an operation of the secondary battery is changed from discharging to charging in a charging period of the secondary battery, obtaining the normal internal resistance R j (T ja ) by using a difference between the open inter-terminal voltage corresponding to the charging state of the secondary battery at the first time and the inter-terminal voltage of the secondary battery at the second time, and a current value of the charging current, and
the predetermined time is 1.0 second or less.
19. The battery control system according to claim 18 , wherein the predetermined time in the resistance obtaining unit is 0.1 seconds or less.
20. The battery control system according to claim 1 , comprising a normal internal resistance storage unit for storing the normal internal resistance R j (T ja ) of the secondary battery at the input time, which is externally input.