Ceramic composition, porous ceramic heat insulating material using same, and preparation method thereof
The present invention relates to a ceramic composition and a porous ceramic insulating material comprising the same, which is widely used as a core material in sandwich panels or fire doors. The ceramic composition comprises 44-60 wt % of glass powder, 8-15 wt % of fly ash, 4-8 wt % of surface treatment agent, and 23-29 wt % of water glass. The porous ceramic insulating material manufactured from the composition is lightweight and is an environmentally friendly material which generates no toxic gas when it catches fire. The ceramic insulating material can be produced at a low temperature of 800˜900° C., and thus has low production cost. In addition, it can be continuously manufactured in a sheet form.
1. A ceramic composition comprising:
44.00-60.00 wt % of glass powder;
8.00-15.00 wt % of fly ash;
4.00-8.00 wt % of a surface treatment agent as a mixture comprising 62.40 wt % of silicon dioxide (SiO 2 ), 22.50 wt % of calcium oxide (CaO), 7.70 wt % of sodium oxide (Na 2 O) and 7.40 wt % of other; and
23.00-29.00 wt % of water glass.
2. The ceramic powder of claim 1 , wherein the glass powder comprises:
62.50-72.50 wt % of silicon dioxide (SiO 2 );
9.75-22.30 wt % of calcium oxide (CaO); and
8.00-13.70 wt % of sodium oxide (Na 2 O).
3. The ceramic composition of claim 2 , wherein the fly ash comprises:
54.5 wt % of silicon dioxide (SiO 2 );
21.1 wt % of alumina (Al 2 O 3 ); and
3.49 wt % of iron trioxide (Fe 2 O 3 ).
4. The ceramic composition of claim 1 , wherein the glass powder is waste glass powder.
5. A porous ceramic insulating material, which comprises the ceramic composition of claim 1 and has a specific gravity of 0.3-0.5 g/cm 3 , a flexural strength of 40 Kgf/cm 2 or less, a thermal conductivity of 0.1-0.14 W/mK, and a flame retardance of grade 1.
6. A method for manufacturing a porous ceramic insulating material comprising the ceramic composition set forth in claim 1 , the method comprising the steps of:
mixing components of said composition to obtain a mixture;
drying and powdering the mixture to obtain a powdered material;
heat-treating the powdered material so as to be calcined and foamed;
molding the heat-treated material into a predetermined shape;
cooling the molded material; and
cutting and finishing the cooled material.
7. The method of claim 6 , wherein the heat-treating step is carried out at 800˜900° C. for 20 minutes to 3 hours.
8. The method of claim 6 , wherein, in the step of mixing the components of the composition, germanium (Ge) is further added in addition to said glass powder, fly ash, surface treatment agent and water glass.
9. A method for manufacturing a porous ceramic insulating material comprising the ceramic composition set forth in claim 2 , the method comprising the steps of:
mixing components of said composition to obtain a mixture;
drying and powdering the mixture to obtain a powdered material;
heat-treating the powdered material so as to be calcined and foamed;
molding the heat-treated material into a predetermined shape;
cooling the molded material; and
cutting and finishing the cooled material.
10. A method for manufacturing a porous ceramic insulating material comprising the ceramic composition set forth in claim 3 , the method comprising the steps of:
mixing components of said composition to obtain a mixture;
drying and powdering the mixture to obtain a powdered material;
heat-treating the powdered material so as to be calcined and foamed;
molding the heat-treated material into a predetermined shape;
cooling the molded material; and
cutting and finishing the cooled material.
11. A method for manufacturing a porous ceramic insulating material comprising the ceramic composition set forth in claim 4 , the method comprising the steps of:
mixing components of said composition to obtain a mixture;
drying and powdering the mixture to obtain a powdered material;
heat-treating the powdered material so as to be calcined and foamed;
molding the heat-treated material into a predetermined shape;
cooling the molded material; and
cutting and finishing the cooled material.