High-temperature open-cell porous ceramic
A high-temperature open-cell porous body, the body comprises crystalline inorganic particles and 0.5 to 3-weight percent glass. The crystalline inorganic particles are bonded together by the glass to form a matrix with interconnected pores having a porosity of greater than 20-percent. The crystalline inorganic particles may further include interconnected micro pores, the latter combination providing a matrix with both macro porosity and micro porosity.
1. A body, comprising:
a) crystalline inorganic particles;
b) 0.5 to 3-weight percent glass; and
c) wherein said crystalline inorganic particles are bonded together by said glass to form a matrix with interconnected pores having a porosity of greater than 20-percent by volume, wherein said matrix is annealed above 1550° C.
2. A body as recited in claim 1 , wherein said glass has silica content greater than 50-percent by weight.
3. A body as recited in claim 2 , wherein the body is an acid resistant body.
4. A body as recited in claim 1 , wherein said glass has a glass working point temperature above 900° C.
5. A body as recited in claim 1 , wherein said glass has a glass working point temperature above 1000° C.
6. A body as recited in claim 1 , wherein said glass is a wetted layer connecting said crystalline inorganic particles.
7. A body as recited in claim 1 , wherein said glass is completely amorphous.
8. A body as recited in claim 1 , wherein said crystalline inorganic particles comprise more than 97-percent by weight of said body.
9. A body as recited in claim 1 , wherein said crystalline inorganic particles are ceramic particles.
10. A body as recited in claim 1 , wherein said crystalline inorganic particles are an oxide.
11. A body as recited in claim 1 , wherein said crystalline inorganic particles are a carbide.
12. A body as recited in claim 1 , wherein said crystalline inorganic particles are a nitride.
13. A body as recited in claim 1 , wherein said crystalline inorganic particles are a boride.
14. A body as recited in claim 1 , wherein said crystalline inorganic particles are metal.
15. A body as recited in claim 1 , wherein said crystalline inorganic particles have a diameter of 44-microns to 250-microns.
16. A body as recited in claim 1 , wherein said crystalline inorganic particles have a diameter greater than 250-microns.
17. A body as recited in claim 1 , wherein said interconnected pores have an average pore size of 0.05-microns to 1-micron.
18. A body as recited in claim 1 , wherein said interconnected pores have an average pore size of 1-micron to 130-microns.
19. A body as recited in claim 1 , wherein said matrix is stable above 1200° C.
20. A body as recited in claim 1 , wherein said matrix has a modulus of rupture greater than 1 kpsi.
21. A body as recited in claim 1 , wherein said crystalline inorganic particles have a micro porous open-cell structure with micro pores.
22. A body as recited in claim 21 , wherein said micro pores have a micro pore surface and a catalyst bonded to said micro pore surface.
23. A body as recited in claim 1 , further comprising a liquid filling-material solidified to fill said interconnected pores.
24. A body as recited in claim 23 , wherein said filling-material is a metal.
25. A body as recited in claim 24 , wherein said metal is at least one selected from the group consisting of aluminum, nickel and cobalt.
26. A body as recited in claim 1 , wherein said inorganic crystalline particles have a size distribution and wherein said matrix is formed from initial glass particles having an average particle size distribution that is more than 10 times and up to 20-times smaller than the average particle size distribution of said inorganic particles.
27. A body, comprising:
a) Al 2 O 3 particles;
b) 0.5 to 3-weight percent glass; and
c) wherein said Al 2 O 3 particles are bonded together by said glass to form a matrix with interconnected pores having a porosity of greater than 20-percent by volume; wherein said matrix has a modulus of rupture of at least 4-kpsi.
28. A body as recited in claim 27 , wherein the body is an acid resistant body.
29. A body as recited in claim 27 , wherein said matrix is annealed above 1550° C.
30. A body as recited in claim 27 , wherein said Al 2 O 3 particles have a size distribution, wherein said matrix is formed from initial glass particles having an average particle size distribution that is more than 10 times and up to 20 times smaller than the average particle size distribution of said Al 2 O 3 particles.
31. A body as recited in claim 27 , wherein said interconnected pores have an average size of 0.05 to 1.0-microns.
32. A body, comprising:
a) 0.5 to 3-weight percent glass as a first glass:
b) crystalline inorganic particles having a micro porous open-cell structure, said micro porous open-cell structure formed from individual crystallites bonded together by micro porous bonding glass having a higher melting temperature than said first glass; and
c) wherein said crystalline inorganic particles having said micro porous open-cell structure are bonded together by said first glass to form a matrix with interconnected pores having a macro porosity of greater than 20-percent by volume.
33. A body, comprising:
a) crystalline inorganic particles;
b) 0.5 to 3-weight percent glass; and
c) wherein said crystalline inorganic particles are bonded together by said glass to form a matrix with interconnected pores having a porosity of greater than 20-percent by volume, wherein said inorganic crystalline particles have a size distribution and wherein said matrix is formed from initial glass particles having an average particle size distribution that is more than 10-times smaller than the average particle size distribution of said inorganic particles.
34. A body as recited in claim 33 , wherein said initial glass particles have an average size distribution that is 10-to-20 times smaller than the average particle size distribution of said inorganic particles.
35. A body as recited in claim 33 , wherein said matrix has a modulus of rupture of at least 4-kpsi.